全文获取类型
收费全文 | 2868篇 |
免费 | 103篇 |
国内免费 | 7篇 |
专业分类
化学 | 2212篇 |
晶体学 | 46篇 |
力学 | 21篇 |
数学 | 145篇 |
物理学 | 554篇 |
出版年
2023年 | 18篇 |
2022年 | 24篇 |
2021年 | 35篇 |
2020年 | 65篇 |
2019年 | 45篇 |
2018年 | 45篇 |
2017年 | 30篇 |
2016年 | 77篇 |
2015年 | 58篇 |
2014年 | 93篇 |
2013年 | 137篇 |
2012年 | 198篇 |
2011年 | 254篇 |
2010年 | 123篇 |
2009年 | 116篇 |
2008年 | 208篇 |
2007年 | 198篇 |
2006年 | 200篇 |
2005年 | 188篇 |
2004年 | 165篇 |
2003年 | 135篇 |
2002年 | 135篇 |
2001年 | 42篇 |
2000年 | 33篇 |
1999年 | 20篇 |
1998年 | 28篇 |
1997年 | 23篇 |
1996年 | 29篇 |
1995年 | 19篇 |
1994年 | 17篇 |
1993年 | 11篇 |
1992年 | 16篇 |
1991年 | 9篇 |
1990年 | 12篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 5篇 |
1985年 | 14篇 |
1984年 | 15篇 |
1983年 | 16篇 |
1982年 | 19篇 |
1981年 | 9篇 |
1980年 | 18篇 |
1979年 | 11篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 4篇 |
1975年 | 8篇 |
1974年 | 4篇 |
1973年 | 4篇 |
排序方式: 共有2978条查询结果,搜索用时 15 毫秒
231.
232.
Ken-ichi Fujita Satoshi UmekiManabu Yamazaki Taku AinoyaTeruhisa Tsuchimoto Hiroyuki Yasuda 《Tetrahedron letters》2011,52(24):3137-3140
We prepared magnetically recoverable osmium catalysts by use of magnetite, quaternary ammonium salts, and potassium osmate(VI), and applied them to the dihydroxylation of olefins. By employing 2 mol% of the magnetic osmium catalyst, the dihydroxylation reaction proceeded smoothly to provide the corresponding vicinal diol in a good chemical yield. The osmium catalyst was readily recovered by use of an external magnet, and was reused repeatedly. 相似文献
233.
234.
Pumping dye-doped organic polymer by interference pattern of a frequency-doubled Nd:YAG 532 nm laser to induce a periodic gain-structure and confining it within a stable optical resonator, the oscillation output can be effectively enhanced in comparison with either that of uniform irradiation, i.e., pumping, or of distributed feedback (DFB) operation, and the oscillation wavelength becomes tunable by adjusting the period of the interference pattern. Using Rhodamine-B as a dopant over the range from 200 to 1000 ppm, the oscillation output was enhanced by - 10 dB, which was larger than the output of the uniform irradiation and was - 30% greater than the DFB scheme. Moreover, changing the period of the interference pattern by adjusting the setting angle of the Koster prism enables us to vary the oscillation wavelength around 600 nm. 相似文献
235.
Akira Kasahara Taeko Izumi Satoshi Murakami Kazuhiro Miyamoto Toshimi Hino 《Journal of heterocyclic chemistry》1989,26(5):1405-1413
The palladium-catalyzed cross-coupling reaction of 2-bromonitrobenzenes or 2-bromoacetanilides with ethylene has been used to produce a variety of substituted indoles. The mild reaction conditions and selectivity inherent in the coupling reaction have been utilized to produce regiochemically pure 4-, 5-, 6-, and 7-substituted indoles. 相似文献
236.
237.
We propose a perturbation method for determining the (largest) group of invariance of a toric ideal defined in [S. Aoki, A. Takemura, The largest group of invariance for Markov bases and toric ideals, J. Symbolic Comput. 43 (5) (2008) 342–358]. In the perturbation method, we investigate how a generic element in the row space of the configuration defining a toric ideal is mapped by a permutation of the indeterminates. Compared to the proof by Aoki and Takemura which was based on stabilizers of a subset of indeterminates, the perturbation method gives a much simpler proof of the group of invariance. In particular, we determine the group of invariance for a general hierarchical model of contingency tables in statistics, under the assumption that the numbers of the levels of the factors are generic. We prove that it is a wreath product indexed by a poset related to the intersection poset of the maximal interaction effects of the model. 相似文献
238.
239.
Atsuhiro Fujimori Hiroko Hoshizawa Satoshi Kobayashi Kaname Kanai Yukio Ouchi Kazuhiko Seki 《Journal of Polymer Science.Polymer Physics》2008,46(5):534-546
Comb copolymers containing both hydrogenated and fluorinated side‐chains were prepared by copolymerization using acrylic or methacrylic monomers in several ratios. The crystal structures of these copolymers and layer structures of their organized molecular films were investigated by wide‐angle X‐ray diffraction (WAXD), small‐angle X‐ray scattering (SAXS), and out‐of plane X‐ray diffraction. Further, to selectively estimate the regularity of shorter fluorocarbon side‐chains, organized molecular films of copolymers were investigated by polarized near‐edge X‐ray adsorption fine structure (NEXAFS) spectroscopy. From the results of these measurements, it was inferred that these copolymers formed highly ordered layer structures, and a long spacing was predominantly determined by the arrangement of hydrogenated side‐chains, except in copolymers having extremely high fluorocarbon contents. In the case of the organized molecular films, the fluorinated side‐chains of methacrylate copolymers cannot form a highly ordered arrangement, whereas those of acrylate copolymers were oriented on monolayers. However, in both cases, the hydrogenated side‐chains predominantly formed layer structures in the organized films, and the fluorinated side‐chains did not contribute to the formation of the layer structures. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 534–546, 2008 相似文献
240.