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51.
Bisphenol-A polycarbonate films were irradiated with 86 MeV swift heavy nickel ions at varying fluences, ranging from 1 × 1011 to 1 × 1013 ions cm?2, under vacuum at room temperature, to analyze the induced electrical and thermal modifications. AC conductivity measurements and UV-visible spectroscopy, Fourier transform infra-red (FTIR) spectroscopy, thermo-gravimetric analysis (TGA), differential scanning calorimetry (DSC), and X-ray diffraction (XRD) techniques were applied to analyze the changes. A significant, exponential increase in conductivity at higher frequency was observed with the increase of nickel ion fluence. UV-visible analysis corroborated the results of the AC conductivity measurement, revealing the increase in size of the carbon clusters embedded in the polymer network, with the increase of heavy ion fluence. FTIR analysis revealed the formation of alkene and alkyne end groups at higher doses, which further supported the suggestion that the variation in electrical properties induced by the ion irradiation of the polymer was due to development of a carbonaceous phase inside the polymer due to the irradiation. Thermal analysis, i.e., TGA and DSC patterns, showed that chain-scission was the leading phenomena in the heavy ion-irradiated polycarbonate samples, resulting in degradation of their thermal stability. 相似文献
52.
Benzofuroxanes react with dienamines to give a novel class of quinoxaline NN'-dioxide enamines in good yields. 相似文献
53.
Two uncoupled two-level atoms cannot be jointly excited by classical light under general circumstances, due to destructive interference of excitation pathways in two-photon absorption. However, with temporally entangled light, two-atom excitation is shown possible. Photons arising from three-level cascade decay are intrinsically ordered in time of emission. This field correlation induces a joint resonance in the two-atom excitation probability via suppression of one of the time-ordered excitation pathways. The relative gain in two-photon absorption increases with the time-frequency entanglement. 相似文献
54.
A modified combustion process, namely a mixed fuel process making use of a mixture of two fuels, such as citric acid and glycine
has been developed to prepare nanocrystalline ceria powders. The effect of the mixed fuel and the different fuel to oxidant
ratios on the decomposition characteristics of the gels were investigated by simultaneous thermal analysis experiments. It
was established from various characterization techniques that the ceria powder prepared through the mixed fuel process has
got the optimum powder characteristics, namely, a surface area of 33.33 m2/g and a crystallite size of 14 nm compared to the powders produced through the combustion process using a single fuel like
glycine or citric acid. Such powders when sintered at 1250°C resulted in pellets with densities in the range of 94–96% of
theoretical density. In this paper, we have carried out systematic studies on the sintering of ceria powders prepared by different
approaches. The sintered ceramic from mixed fuel batch, exhibited and retained relative density more than 95% up to 1250°C
and this data clearly underscores the ability of this process in developing ceria ceramics with increased stability against
reduction. 相似文献
55.
The Rayleigh–Taylor instability (RTI) of a ferrofluid has been the subject of recent research, because of its implications on the stability of stellar and planetary interiors. This paper analyzes the effects of rotation and magnetic field on nonlinear RTI of two superposed ferrofluids. It is considered that the system is subjected to uniform parallel rotation and normal magnetic field. Surface tension acts at the interface. The method of multiple scales is utilized to obtain the solutions and dispersion relations are obtained for the nonlinear problem of RTI of magnetic fluids. Finally the stability of the problem is discussed. 相似文献
56.
Stable, high-power, second-harmonic-generation (SHG) of a compact CW Ytterbium (Yb) fiber laser at 1064 nm into the green
and its use as a pump source for CW singly-resonant optical parametric oscillator (SRO) is demonstrated. Using a simple single-pass
SHG configuration in MgO:sPPLT, as much as 9.6 W of single-frequency green radiation at 532 nm is generated from 30 W of fundamental
power at a conversion efficiency of 32.7% in a Gaussian spatial profile with a beam quality factor of M
2 < 1.3. Thermal effects have been investigated at different fundamental power levels and various thermal management schemes
are employed to maximize the second-harmonic power. The green source is successfully deployed to pump a CW SRO tunable over
855–1408 nm, generating up to 2.1 W of idler at 1168 nm. The peak-to-peak idler power stability is better than 10.7% over
40 min, with beam quality factor M
2 < 1.26 for the idler and M
2 < 1.52 for the signal. 相似文献
57.
Dr. Srivari Chandrasekhar Kakita Veera Mohana Rao Mallikanti Seenaiah Police Naresh Ambure Sharada Devi Dr. Bharatam Jagadeesh 《化学:亚洲杂志》2014,9(2):457-461
Hybrid peptidic oligomers comprising natural and unnatural amino acid residues that can exhibit biomolecular folding and hydrogen‐bonding mimicry have attracted considerable interest in recent years. While a variety of hybrid peptidic helices have been reported in the literature, other secondary structural patterns such as γ‐turns and ribbons have not been well explored so far. The present work reports the design of novel periodic γ‐turns in the oligomers of 1:1 natural‐α/unnatural trans‐β‐norborenene (TNAA) amino acid residues. Through DFT, NMR, and MD studies, it is convincingly shown that, in the mixed conformational pool, the heterogeneous backbone of the hybrid peptides preferentially adopt periodic 8‐membered (pseudo γ‐turn)/7‐membered (inverse γ‐turn) hydrogen bonds in both polar and non‐polar solvent media. It is observed that the stereochemistry and local conformational preference of the β‐amino acid building blocks have a profound influence on accessing the specific secondary fold. These findings may be of significant relevance for the development of molecular scaffolds that facilitate desired positioning of functional side‐chains. 相似文献
58.
A mild, efficient, and high-yielding method for the synthesis of 2-aryl-2,3-dihydroquinolin-4(1H)-ones from their corresponding 2-amino chalcones using silica chloride (SiO2Cl) under solvent-free conditions is described. A series of 2-aryl-2,3-dihydroquinolin-4(1H)-ones containing both electron-donating and electron-withdrawing substituents were synthesized. 相似文献
59.
Chandu Venugopal M. J. Kurian E. Savithri Devi P. J. Jessy C. P. Anilkumar G. Renuka 《Indian Journal of Physics》2010,84(3):319-324
The dispersion characteristics of low-frequency electromagnetic waves are studied in a plasma containing hydrogen ions and
positively and negatively charged oxygen ions and electrons. This composition of the plasma approximates very well the coma
of comet Halley where many heavy ions have been observed in appreciable numbers. The excitation of these waves results from
the relative motion between the protons and the heavy ions, which are considered unmagnetised and, therefore, may act like
a beam. We find that the wave growth increases with increasing heavy ion densities, beam velocities and propagation angles. 相似文献
60.
P. Lakshmi Reddy D. Ashok Kumar M. Lakshmi Devi T. Veera Reddy B.V. Subba Reddy R. Narender 《Tetrahedron letters》2014
A three-component, four center Ugi reaction of 3-(1-(2-aminophenyl)-5-phenyl-1H-pyrrol-2-yl)propanoic acid with aromatic aldehyde and t-butyl isocyanide has been achieved to produce a novel class of N-tert-butyl-2-(6-oxo-11-phenyl-7,8-dihydrobenzo[b]pyrrolo[1,2-d][1,4]diazacine-5(6H)-yl)-2-phenylacetamides in moderate to good yields. 相似文献