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61.
A novel intercalating phenazine derivative (Pzn) was covalently linked to the 3-end of decathymidylate via a ribose residue of the dye. A fluorescence technique was used to study double helix formation by this conjugate with poly(rA) in aqueous solutions of neutral pH, at the presence of 0.1 and 1 M sodium ions. Proportionality between thermally induced changes in the fluorescence intensity of the free conjugate and bound one was revealed, that made it possible to calculate the helix-to-coil transition from fluorescence melting data using a simple equation. The transition curves were found to be in well conformity with those constructed from absorption measurements. It was shown that the attachment of Pzn significantly enhanced the stability of poly(rA) · (dT)10 duplex due to intercalation of the dye chromophore into the adenine strand. The temperature of half-dissociation was increased by 12°C, and the stabilizing increment of standard free energy was 3.2–3.6 kcal/mol at 37°C. 相似文献
62.
M. K. Pandey R. K. Dubey D. N. Tripathi 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,41(2):275-279
The Classical Trajectory Monte Carlo (CTMC) Method has
been used to calculate the differential, partial and total single electron
capture cross sections for the collision of H+/D+ with Ca and Mg
atoms in the energy range of 1–100 keV. The differential cross sections
at angles near the diffraction limit (<0.1○) in both systems
show a forward peak followed by an asymptotic fall at higher angles. Total
and partial capture cross sections are found to be in good agreement with
the experimental observations. Oscillations in the partial capture cross sections have been explained due to the swapping
of the field electron.
Isotope effect in the electron transfer is reported to be negligible. 相似文献
63.
Shruti A. Dubey 《Journal of Mathematical Analysis and Applications》2011,376(1):275-281
This paper discusses nonlinear functional differential equation in a real reflexive Banach space with nonlocal history condition. By using the method of lines, the existence and uniqueness of a strong solution are established. Finally, some applications of the abstract results are presented. 相似文献
64.
Reduction of ketone 3 derived from (R)-2,3-cyclohexylideneglyceraldehyde 1 with some common hydrides took place with syn-selectivity. The resulting major product 4a has been exploited as a common chiral template to prepare both enantiomers Ia,b of disparlure. 相似文献
65.
66.
Nathan W. Polaske Ramin Dubey Gary S. Nichol Bogdan Olenyuk 《Tetrahedron: Asymmetry》2009,20(23):2742-2750
The asymmetric organocatalytic α-sulfenylation of substituted piperazine-2,5-diones is reported, with cinchona alkaloids as chiral Lewis bases and electrophilic sulfur transfer reagents. Catalyst loadings, the type of sulfur transfer reagent, temperature, and solvent were investigated in order to optimize the reaction conditions. The effects of ring substitution and the type of catalyst on the yield and enantioselectivity of the reaction are reported. 相似文献
67.
68.
Vinay K. Singh Rahul Dubey Abhishek Upadhyay Laxmi Kant Sharma Rana Krishna Pal Singh 《Tetrahedron letters》2017,58(45):4227-4231
An efficient and economical method was developed for synthesis of 3-substituted indole by using electrochemically induced condensation of various aldehyde, indole and malononitrile. 相似文献
69.
In this paper, multilayer structures of porous silicon were fabricated by using electrochemical etching and characterized for its optical properties and surface morphology. Samples of monolayer of porous silicon were grown to study the characteristics of porous layer formation with respect to applied current density, etching time and hydrofluoric acid concentrations. Photoluminescence peaks of red emission at wavelength 695 and 650 nm were observed from multilayer porous silicon structures. By atomic force microscopy measurement, hillocks like surface were clearly observed within the host material, which confirmed the formation of pores. 相似文献
70.