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81.
This paper describes a flow-injection (FI) method for the simultaneous determination of aniline and cyclohexylamine impurities in cyclamate products. The method consists of the derivatization of amines with 1,2-naphthoquinone-4-sulfonate under selective and non-selective conditions. Here, the selectivity is achieved by working at 20 degree C, at which only aniline reacts, whilst higher temperatures (80 degree C) lead to a non-selective reaction of the two analytes. The FI manifold is composed of two flow cells for the spectrophotometric detection of derivatives at 480 nm. Experimental conditions have been optimized by factorial design and multicriteria making approach. Quantification is accomplished by differential analysis of the analyte contributions in the double peaks generated when the sample reaches cell 1 and cell 2. Results obtained with the proposed method are in satisfactory agreement with those provided by the standard method for the analysis of cyclamate samples. 相似文献
82.
A novel organic-inorganic hybrid based on a dinuclear copper complex supported on a keggin polyoxometalate 总被引:1,自引:0,他引:1
Reinoso S Vitoria P Lezama L Luque A Gutiérrez-Zorrilla JM 《Inorganic chemistry》2003,42(12):3709-3711
The autoassembly process of copper-oxalate dimers and Keggin type polyoxometalates leads to the first example of a new family of organic-inorganic hybrids, K(14)[(Cu(2)(bpy)(2)(mu-ox))(SiW(11)O(39)Cu(H(2)O))](2)[SiW(11)O(39)Cu(H(2)O)]. approximately 55H(2)O. This compound crystallizes in the monoclinic space group C2/m, a = 37.932(6) A, b = 21.303(3) A, c = 12.546(2) A, beta = 106.16(1) degrees, Z = 2. The crystal structure reveals the presence of a polymeric hybrid built up of alternating dimer and polyoxometalate entities. 相似文献
83.
84.
Jürgen?HerzogEmail author Zhongming?Tang Santiago?Zarzuela 《manuscripta mathematica》2003,112(4):489-509
In this paper we study the symmetric algebra S(E
i
) and Rees algebra R(E
i
) of the modules E
i
of i-cycles of the Koszul complex associated with the sequence of indeterminates
of a polynomial ring
. For i=2 and i=n–2 we show that
is a d-sequence on S(E
i
) and R(E
i
) and we determine Gröbner bases and Sagbi bases related to these algebras.
Mathematics Subject Classification (2000):13A30, 13D02, 13H10, 13P10The second author is grateful to the National Natural Science Foundation of China for support.Part of this work was made while the third author was visiting the Fachbereich Mathematik und Informatik der Universität Essen, to which he would like to thank for its hospitality. 相似文献
85.
The conformal class of a Hermitian metric g on a compact almost complex manifold (M2m, J) consists entirely of metrics that are Hermitian with respect to J. For each one of these metrics, we may define a J-twisted
version of the Ricci curvature, the J-Ricci curvature, and its corresponding trace, the J-scalar curvature sJ. We ask if the conformal class of g carries a metric with constant sJ, an almost Hermitian version of the usual Yamabe problem posed for the scalar curvature s. We answer our question in the
affirmative. In fact, we show that (2m−1)sJ−s=2(2m−1)W(ω, ω), where W is the Weyl tensor and ω is the fundamental form of g. Using techniques developed for the solution
of the problem for s, we construct an almost Hermitian Yamabe functional and its corresponding conformal invariant. This invariant
is bounded from above by a constant that only depends on the dimension of M, and when it is strictly less than the universal
bound, the problem has a solution that minimizes the almost complex Yamabe functional. By the relation above, we see that
when W (ω, ω) is negative at least one point, or identically zero, our problem has a solution that minimizes the almost Hermitian
Yamabe functional, and the universal bound is reached only in the case of the standard 6-sphere
equipped with a suitable almost complex structure. When W(ω, ω) is non-negative and not identically zero, we prove that the
conformal invariant is strictly less than the universal bound, thus solving the problem for this type of manifolds as well.
We discuss some applications. 相似文献
86.
The Einstein–Podolsky–Rosen–Bohm (EPRB) experiment performed with random variable and spatially separated analyzers is a milestone
test in the controversy between Objective Local Theories (OLT) and Quantum Mechanics (QM). Only a few OLT are still possible.
Some of the surviving OLT (specifically, the so called non-ergodic theories) would be undetectable in the averaged statistical
values, but they may leave their trace in the time dynamics. For, while QM predicts random processes, the OLT of this kind
predict the existence of regularities that may be revealed as a low dimensional object in the phase space. We perform a numerical
analysis of the time-resolved data recorded in that experiment to unveil any hypothetical low dimensional dynamics that may
be present. We find no consistent indication of such dynamics except for one data file, the longest of all in the real time.
The possible causes of these dynamics are discussed.
相似文献
87.
In this review, the synthesis, reactivity and properties of linear and cyclic oligophosphanides are described. Specifically the structures and versatile reactivity of the anionic ligands (P4R4)2? (R = But, Ph, Mes), (P4HR4)? (R = Ph and Mes) and cyclo-(P5But4)? towards main group and transition metal complexes is elucidated. In addition, potential application of metal oligophosphanides as precursors for the preparation of metal phosphides is also briefly discussed. 相似文献
88.
H. Isnard M. Granet C. Caussignac E. Ducarme A. Nonell B. Tran F. Chartier 《Spectrochimica Acta Part B: Atomic Spectroscopy》2009,64(11-12):1280-1286
In the nuclear domain, precise and accurate isotopic composition determination of elements in spent nuclear fuels is mandatory to validate neutron calculation codes and for nuclear waste disposal. The present study presents the results obtained on Cs isotope ratio by mass spectrometric measurements. Natural cesium is monoisotopic (133Cs) whereas cesium in spent fuels has 4 isotopes (133Cs, 134Cs, 135Cs, and 137Cs). As no standard reference material is available to evaluate the accuracy of Cs isotopic measurements, a comparison of cesium isotopic composition in spent nuclear fuels has been performed between Thermal Ionization Mass Spectrometry (TIMS) and a new method involving Multiple Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICPMS) measurements. For TIMS measurements, isotopic fractionation has been evaluated by studying the behavior of cesium isotope ratios (133Cs/137Cs and 135Cs/137Cs) during the analyses. For MC-ICPMS measurements, the mass bias effects have been corrected with an external mass bias correction using elements (Eu and Sb) close to cesium masses. The results obtained by the two techniques show good agreement: relative difference on 133Cs/137Cs and 135Cs/137Cs ratios for two nuclear samples, analyzed after chemical separation, ranges from 0.2% to 0.5% depending on the choice of reference value for mass bias correction by MC-ICPMS. Finally the quantification of the 135Cs/238U ratio by the isotope dilution technique is presented in the case of a MOx (mixed oxide) spent fuel sample. Evaluation of the global uncertainties shows that this ratio could be defined at an uncertainty of 0.5% (k = 2). The intercomparison between two independent mass spectrometric techniques is fundamental for the evaluation of uncertainty when no isotopic standard is available. 相似文献
89.
Belén Altava Dalgi S. Barbosa M. Isabel Burguete Jorge Escorihuela Santiago V. Luis 《Tetrahedron: Asymmetry》2009,20(9):999-1003
A family of new imidazolium salts derived from natural amino acids has been synthesized and tested for NMR enantiodiscrimination, as chiral shift reagents, of carboxylic acids. These imidazolium receptors contain different structural modifications and the splitting of the signals of the acids, after addition of the corresponding CSRs, depends on these structural variables. Compound 8b exhibited the strongest chiral solvating properties for racemic Mosher acid and was recognized as a suitable CSR for the determination of its enantiomeric composition. 相似文献
90.
Manuela Martín‐Zarco Santiago Toribio Joaquín C. García‐Martínez Julián Rodríguez‐López 《Journal of polymer science. Part A, Polymer chemistry》2009,47(23):6409-6419
A series of polyamido amine (PAMAM) dendrimers (Generations 2, 3, 4, and 6) fully functionalized at their periphery with first‐ and second‐generation poly (phenylenevinylene) (PPV) dendrons have been efficiently prepared. MALDI‐TOF mass spectrometry proved to be particularly useful for the characterization of the new hybrid dendrimers as well as for the estimation of the average number of PPV dendrons attached to the surface. The optical absorption and emission properties of these systems were studied. The materials display extremely high molar extinction coefficients and emit blue light with only slightly lower fluorescence quantum yields than the corresponding free dendrons. Self‐quenching interactions between PPV units were not observed in THF. However, the luminescence properties underwent a dramatic change when toluene was used as the solvent. The lower polarity of toluene caused shrinkage of the PAMAM structure and brought the PPV chromophores closer together, leading to self‐quenching interactions and excimer formation. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6409–6419, 2009 相似文献