Generalized derivations acting on multilinear polynomials in prime rings

Let R be a noncommutative prime ring of characteristic different from 2 with Utumi quotient ring U and extended centroid C, let F, G and H be three generalized derivations of R, I an ideal of R and f(x₁,..., x _n ) a multilinear polynomial over C which is not central valued on R. If

$$F(f(r))G(f(r)) = H(f(r)^2 )$$

for all r = (r₁,..., r _n ) ∈ I ⁿ , then one of the following conditions holds:

1. (1)
   there exist a ∈ C and b ∈ U such that F(x) = ax, G(x) = xb and H(x) = xab for all x ∈ R
    
2. (2)
   there exist a, b ∈ U such that F(x) = xa, G(x) = bx and H(x) = abx for all x ∈ R, with ab ∈ C
    
3. (3)
   there exist b ∈ C and a ∈ U such that F(x) = ax, G(x) = bx and H(x) = abx for all x ∈ R
    
4. (4)
   f(x₁,..., x _n )² is central valued on R and one of the following conditions holds

   1. (a)
      there exist a, b, p, p’ ∈ U such that F(x) = ax, G(x) = xb and H(x) = px + xp’ for all x ∈ R, with ab = p + p’
       
   2. (b)
      there exist a, b, p, p’ ∈ U such that F(x) = xa, G(x) = bx and H(x) = px + xp’ for all x ∈ R, with p + p’ = ab ∈ C.
       
    

     

The strength of multi-row aggregation cuts for sign-pattern integer programs

Sign-pattern IPs are a generalization of packing IPs, where for a given column all coefficients are either non-negative or non-positive. We show that the aggregation closure for such sign-pattern IPs can be 2-approximated by the original 1-row closure. This generalizes a result for packing IPs. On the other hand, unlike in the case of packing IPs, we show that the multi-row aggregation closure cannot be well approximated by the original multi-row closure.     

Controlling hydrogel properties by tuning non-covalent interactions in a charge complementary multicomponent system

Mixing small molecule gelators is a promising route to prepare useful and exciting materials that cannot be accessed from any of the individual components. Here, we describe pH-triggered hydrogelation by mixing of two non-gelling amphiphiles. The intermolecular interactions among the molecules can be tuned either by controlling the degree of ionization of the components or by a preparative pathway, which enables us to control material properties such as gel strength, gel stiffness, thermal stability, and an unusual shrinking/swelling behaviour.

The properties of a charge complementary multicomponent gel can be tuned either by pH change or by varying the preparative pathway.     

Relations between facets of low- and high-dimensional group problems

One-dimensional infinite group problems have been extensively studied and have yielded strong cutting planes for mixed integer programs. Although numerical and theoretical studies suggest that group cuts can be significantly improved by considering higher-dimensional groups, there are no known facets for infinite group problems whose dimension is larger than two. In this paper, we introduce an operation that we call sequential-merge. We prove that the sequential-merge operator creates a very large family of facet-defining inequalities for high-dimensional infinite group problems using facet-defining inequalities of lower-dimensional group problems. Further, they exhibit two properties that reflect the benefits of using facets of high-dimensional group problems: they have continuous variables’ coefficients that are not dominated by those of the constituent low-dimensional cuts and they can produce cutting planes that do not belong to the first split closure of MIPs. Further, we introduce a general scheme for generating valid inequalities for lower-dimensional group problems using valid inequalities of higher-dimensional group problems. We present conditions under which this construction generates facet-defining inequalities when applied to sequential-merge inequalities. We show that this procedure yields some two-step MIR inequalities of Dash and Günlük.     

A Three-Qubit State Entanglement Concentration Protocol Assisted by Two-Qubit Systems

In this paper we present an entanglement concentration protocol for enhancement of the amount of entanglement maximally in a three qubit non-maximally entangled state. We use a Bell state for this purpose. Here the speciality is that no non-local measurement involving more than one parties is involved in the protocol. It is shown that for obtaining best probability of success a maximally entangled Bell state must be used. The probability of success in our protocol increases with an increase in the amount of entanglement in the assisting Bell state, and is zero when the entanglement vanishes.     

Conformation-dependent electron transport through a biphenyl molecule: circular current and related issues

We investigate the conformation-dependent electron transfer in a biphenyl molecule within a simple tight-binding framework. The overall junction current and circular currents in two benzene rings driven by applied bias voltage are calculated by using Green’s function formalism. Our analysis may provide the possibilities of using organic molecules with loop substructures to design molecular spintronic devices, indicating the emergence of molecular spintronics.     

Possible Routes for Efficient Thermo-Electric Energy Conversion in a Molecular Junction

In the context of designing an efficient thermoelectric energy-conversion device at nanoscale level, we suggest several important tuning parameters to enhance the performance of thermoelectric converters. We consider a simple molecular junction, which is always helpful to understand the basic mechanisms in a deeper way, where a benzene molecule is coupled to two external baths having unequal temperatures. The key component responsible for achieving better performance is associated with the asymmetric nature of transmission function, and in the present work, we show that it can be implemented in different ways by regulating the physical parameters involving the system. Employing a tight-binding framework we calculate electrical and thermal conductances, thermopower, and figure of merit (FOM) by using Landauer integrals, and thoroughly examine the critical roles played by molecule-to-lead (ML) interface geometry, magnetic field, chemical substituent group, ML coupling, and the direct coupling between the two leads. Our results show that a reasonably large FOM (≫1) can be obtained and lead to a possibility of regulating the efficiency by selectively tuning the physical parameters. We believe that the present analysis will enhance the understanding of designing efficient thermoelectric devices, and can be verified in a laboratory.     

Experimental signature of entrance channel effect in heavy mass region via evaporation residue cross section and spin distribution measurements

Evaporation residue (ER) cross sections and gamma multiplicity distributions have been measured for ¹⁶O + ¹⁸⁴W and ¹⁹F + ¹⁸¹Ta systems in the excitation energy range of 50–90 MeV, leading to the same compound nucleus ²⁰⁰Pb^∗. Comparison of experimental results of both the systems shows that ER cross sections and moments of gamma multiplicity distribution of ¹⁶O + ¹⁸⁴W system are significantly higher than those of ¹⁹F + ¹⁸¹Ta system at higher excitation energies. Present measurements directly shows the experimental signature of entrance channel effect even with the systems which are not very different with respect to their entrance channel mass asymmetry. It is further demonstrated that the reduction in the ER cross section and moments of spin distribution for ¹⁹F + ¹⁸¹Ta system is mainly due to the suppression of fusion of higher l values.     

Phonon confinement and substitutional disorder in Cd1−xZnxS nanocrystals

1‐longitudinal optical (LO) phonons in free‐standing mixed Cd_1−xZn_xS nanocrystals, synthesized using chemical precipitation, are investigated using Raman spectroscopy. As expected for the nanocrystals, the 1‐LO modes are found to appear at slightly lower wavenumbers than those in the bulk mixed crystals and exhibit one‐mode behavior. On the other hand, the line broadening is found to be much more than that can be accounted on the basis of phonon confinement. From the detailed line‐shape analysis it turns out that the substitutional disorder in the mixed crystals contributes much more to the line broadening than the phonon confinement. The linewidth arising from these mechanisms are also extracted from the analysis. Copyright © 2009 John Wiley & Sons, Ltd.     

Concise synthesis of two trisaccharides related to the saponin isolated from Centratherum anthelminticum

Chemical synthesis of two trisaccharides related to the saponin isolated from Centratherum anthelminticum is reported. Stereoselective, high-yielding glycosylation strategies were developed using H₂SO₄ immobilized on silica for activation of trichloroacetimidate donors, or in conjunction with N-iodosuccinimide for activation of a thioglycoside. A late stage TEMPO-mediated oxidation was performed for the formation of the required uronic acid moiety.