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81.
    
A 2D coordination compound {[Cu2(HL)(N3)]?ClO4} ( 1 ; H3L=2,6‐bis(hydroxyethyliminoethyl)‐4‐methyl phenol) was synthesized and characterized by single‐crystal X‐ray diffraction to be a polymer in the crystalline state. Each [Cu2(HL)(N3)]+ species is connected to its adjacent unit by a bridging alkoxide oxygen atom of the ligand to form a helical propagation along the crystallographic a axis. The adjacent helical frameworks are connected by a ligand alcoholic oxygen atom along the crystallographic b axis to produce pleated 2D sheets. In solution, 1 dissociates into [Cu2(HL)2(H3L)]?2H2O ( 2 ); the monomer displays high selectivity for Zn2+ and can be used in HEPES buffer (pH 7.4) as a zinc ion selective luminescent probe for biological application. The system shows a nearly 19‐fold Zn2+‐selective chelation‐enhanced fluorescence response in the working buffer. Application of 2 to cultured living cells (B16F10 mouse melanoma and A375 human melanoma) and rat hippocampal slices was also studied by fluorescence microscopy.  相似文献   
82.
83.
    
This investigation reports the atom transfer radical copolymerization (ATRcP) of glycidyl methacrylate (GMA) and 2‐ethylhexyl acrylate (EHA). Poly(glycidyl methacrylate) (PGMA) has easily transformable pendant oxirane group and poly(2‐ethylhexyl acrylate) (PEHA) has very low Tg. They are the important components of coating and adhesive materials. Copolymerization of GMA and EHA was carried out in bulk and in toluene at 70 °C at different molar feed ratios using CuCl as catalyst in combination with 2,2′‐bypyridine (bpy) as well as N,N,N′,N″,N″‐pentamethyl diethylenetriamine (PMDETA) as ligand. The molecular weight (Mn) and the polydispersity index (PDI) of the polymers were determined by GPC analysis. The molar composition of the copolymers was determined by 1H NMR analysis. The reactivity ratios of GMA (r1) and EHA (r2) were determined using Finemann‐Ross and Kelen‐Tudos linearization methods and those had been compared with the literature values for conventional free radical copolymerization. The thermal properties of the copolymers were studied by DSC and TGA analysis. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6526–6533, 2009  相似文献   
84.
Sign-pattern IPs are a generalization of packing IPs, where for a given column all coefficients are either non-negative or non-positive. We show that the aggregation closure for such sign-pattern IPs can be 2-approximated by the original 1-row closure. This generalizes a result for packing IPs. On the other hand, unlike in the case of packing IPs, we show that the multi-row aggregation closure cannot be well approximated by the original multi-row closure.  相似文献   
85.
One-dimensional infinite group problems have been extensively studied and have yielded strong cutting planes for mixed integer programs. Although numerical and theoretical studies suggest that group cuts can be significantly improved by considering higher-dimensional groups, there are no known facets for infinite group problems whose dimension is larger than two. In this paper, we introduce an operation that we call sequential-merge. We prove that the sequential-merge operator creates a very large family of facet-defining inequalities for high-dimensional infinite group problems using facet-defining inequalities of lower-dimensional group problems. Further, they exhibit two properties that reflect the benefits of using facets of high-dimensional group problems: they have continuous variables’ coefficients that are not dominated by those of the constituent low-dimensional cuts and they can produce cutting planes that do not belong to the first split closure of MIPs. Further, we introduce a general scheme for generating valid inequalities for lower-dimensional group problems using valid inequalities of higher-dimensional group problems. We present conditions under which this construction generates facet-defining inequalities when applied to sequential-merge inequalities. We show that this procedure yields some two-step MIR inequalities of Dash and Günlük.  相似文献   
86.
In this paper we present an entanglement concentration protocol for enhancement of the amount of entanglement maximally in a three qubit non-maximally entangled state. We use a Bell state for this purpose. Here the speciality is that no non-local measurement involving more than one parties is involved in the protocol. It is shown that for obtaining best probability of success a maximally entangled Bell state must be used. The probability of success in our protocol increases with an increase in the amount of entanglement in the assisting Bell state, and is zero when the entanglement vanishes.  相似文献   
87.
We investigate the conformation-dependent electron transfer in a biphenyl molecule within a simple tight-binding framework. The overall junction current and circular currents in two benzene rings driven by applied bias voltage are calculated by using Green’s function formalism. Our analysis may provide the possibilities of using organic molecules with loop substructures to design molecular spintronic devices, indicating the emergence of molecular spintronics.  相似文献   
88.
    
1‐longitudinal optical (LO) phonons in free‐standing mixed Cd1−xZnxS nanocrystals, synthesized using chemical precipitation, are investigated using Raman spectroscopy. As expected for the nanocrystals, the 1‐LO modes are found to appear at slightly lower wavenumbers than those in the bulk mixed crystals and exhibit one‐mode behavior. On the other hand, the line broadening is found to be much more than that can be accounted on the basis of phonon confinement. From the detailed line‐shape analysis it turns out that the substitutional disorder in the mixed crystals contributes much more to the line broadening than the phonon confinement. The linewidth arising from these mechanisms are also extracted from the analysis. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
89.
    
Heteroaryl boronic acids and esters are extremely important and valuable intermediates because of their wide application in the synthesis of marketed drugs and bioactive compounds. Over the last couple of decades, the construction of highly important heteroaryl carbon-boron bonds has created huge attention. The transition-metal-free protocols are more green, less sensitive to air and moisture, and also economically advantageous over the transition-metal-based protocols. The transition-metal-free C−H borylation of heteroarenes and C−X (X=halogen) borylation of heteroaryl halides represents an excellent approach for their synthesis. Also, various cyclization and alkyne activation protocols have been recently established for their synthesis. The goal of this review article is to summarize the existing literature and the current state of the art for transition-metal-free synthesis of heteroaryl boronic acid and esters.  相似文献   
90.
    
Solid porous and crystalline covalent organic frameworks (COFs) are characterized by their higher specific BET surface areas and functional pore walls, which allow the adsorption of various bioactive molecules inside the porous lattices. We have introduced a perylene-based COF, PER@PDA-COF-1, which acts as an effective porous volumetric reservoir for an anticancer drug, mitoxantrone (MXT). The drug-loaded COF (MXT–PER@PDA-COF-1) exhibited zero cellular release of MXT towards cancer cells, which can be attributed to the strong intercalation between the anthracene-dione motif of the drug and the perylene-based COF backbone. Here, we have introduced a strategy involving the serum-albumin-triggered intracellular release of mitoxantrone from MXT–PER@PDA-COF-1. The serum albumin acts as an exfoliating agent and as a colloidal stabilizer in PBS medium (pH = 7.4), rapidly forming a protein corona around the exfoliated COF crystallites and inducing the sustained release of MXT from the COF into tumorigenic cells.

Solid porous and crystalline covalent organic frameworks (COFs) are characterized by their higher specific BET surface areas and functional pore walls, which allow the adsorption of various bioactive molecules inside the porous lattices.  相似文献   
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