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11.
Sanjib Kumar Saha Ajit Kumar Chaudhuri 《Journal of polymer science. Part A, Polymer chemistry》1987,25(2):519-532
The polymerization of methyl methacrylate was studied in carbon tetrachloride medium with ferric laurate, a metal soap, in combination with n-hexyl amine as the initiator system at 60°C. The rate of polymerization was found to be linear with the monomer concentration and proportional to the square root of both ferric ion and amine concentration. A reaction scheme involving initial complex formation between ferric ion and amine and subsequent reaction of the complex with the solvent molecule to produce free radicals responsible for initiation of polymerization has been postulated to account for the observed results. 相似文献
12.
Ajay K. Bose Subhendu N. Ganguly Maghar S. Manhas Vaidyanathan Srirajan Ashoke Bhattacharjee Sochanchingwung Rumthao Anju H. Sharma 《Tetrahedron letters》2004,45(6):1179-1181
A novel dinitro secondary metabolite, 2-nitro-4-(2′-nitroethenyl)phenol from a marine source, has been prepared via highly accelerated, microwave assisted, nitration reactions using mild reagents. ipso-Substitution of a carboxy group by a nitro group is discussed. 相似文献
13.
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15.
Ajay K. Bose Maghar S. Manhas Suhas Pednekar Subhendu N. Ganguly Hoang Dang William He Arun Mandadi 《Tetrahedron letters》2005,46(11):1901-1903
An important stage in process development is kilo scale preparation of the target compound. For this reason, a procedure involving water-based biphasic reaction media has been developed for conducting some exothermic reactions on a large scale. This protocol is illustrated by the energy-efficient and rapid preparation of dihydropyrimidinones by a solvent-free, green chemistry procedure applied to the Biginelli reaction using p-toluenesulfonic acid as catalyst. 相似文献
16.
Misra T Maiti M Ganguly T 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(8):1631-1641
By using steady state and time-resolved (laser flash photolysis and single photon counting) spectroscopic techniques the quenching of the lowest excited singlet (S1) state of 9-cyanoanthracene (9CNA) by the donors (quenchers) 2-methylindole (2MI) and 2-methylindoline (2MIN) in solvents of different polarity has been studied. Both the transient absorption, by laser flash photolysis technique, and photobleaching measurements were made at the ambient temperature both in non-polar n-heptane (NH) and highly polar acetonitrile (ACN) solvents. The photobleaching efficiency (alpha) was found to depend significantly on the polarity of surrounding solvents and also on the molecular structures of the quenchers. In NH the values of alpha are found to be larger than the corresponding values observed in ACN for both 2MI and 2MIN which possess highly reactive H atom bound to the heterocyclic N atom. Following the results obtained from the transient absorption spectra of the present donor-acceptor molecules in the different polarity solvents, a scheme describing the overall reaction mechanisms of the different photoreactions involved has been proposed. The probable causes for the changes observed in the mechanisms of the photoreactions involved in the cases of 2MI and 2MIN donors have been discussed in the light of their canonical structures. 相似文献
17.
1,5-Diaza-cis-decalin populates two conformations in which the nitrogen atoms are either gauche (N-in) or anti (N-out) to one another. The equilibrium mixture of the two conformers depends on the substituents at the nitrogen atom, as well as the reaction conditions. Ab initio (HF/6-31G, B3LYP/6-31+G) and molecular mechanics (Amber) calculations have been performed to examine the possible role of stereoelectronics and steric effects in controlling the equilibrium of substituted 1,5-diaza-cis-decalins. In the present study, N,N'-diethyl- and N,N'-bistrifluoroethyl-1,5-diaza-cis-decalins have been synthesized, and the equilibrium mixtures have been measured using 1H and 13C NMR experiments. Steric effects appear to control the equilibria between the two conformational isomers of 1,5-diaza-cis-decalin while torsional effects appear to dominate the equilibria for the N,N'-dialkyl derivatives. 相似文献
18.
Efficient and simple colorimetric fluoride ion sensor based on receptors having urea and thiourea binding sites 总被引:6,自引:0,他引:6
[structure: see text] Novel colorimetric receptors for selective fluoride ion sensing containing anthraquinone as chromogenic signaling subunit and urea (N,N' '-(9,10-dihydro-9,10-dioxo-1,2-anthracenediyl)bis[N'-phenyl])/thiourea (N,N' '-(9,10-dihydro-9,10-dihydro-9,10-dioxo-1,2-antrhacenediyl)bis[N-phenyl]) binding sites have been reported. These receptors have shown no affinity for other halide ions (Cl-, Br-, and I- ions). Well-defined color change in the visible region of the spectrum was observed upon addition of fluoride ion in DMSO/CH3CN solution of the receptors 1 and 2. 相似文献
19.
Roland Prewo Jost H. Bieri Subhendu Narayan Ganguly Max Viscontini 《Helvetica chimica acta》1982,65(3):1094-1099
The Configuration at C(6) of Natural 5,6,7,8-Tetrahydro-L-biopterin and of its Pentaacetate The structure of (6.R)-pentaacetyl-5,6,7,8-tetrahydro-L-biopterin, one of two diastereoisomers obtained by catalytic hydrogenation and subsequent acetylation of L-biopterin, has been determined by X-ray diffraction analysis. The space group is P212121, a=8,053(l), b=14,955(3), c= 21,502 (4) Å. The asymmetric unit contains one molecule of the biopterin derivative and one of ethyl acetate. The R-configuration can be assigned to C(6) by reference to the known configurations of the other asymmetric C-atoms. As hydrolysis of this diastereoisomer yields the natural 5, 6,7,8-tetrahydro-L-biopterin, the latter also possesses the (6 R)-configuration. 相似文献
20.
Ru(P)2(TaiMe)Cl2 [P = PPh3; TaiMe = 1-methyl-2-(p-tolylazo)imidazole] possesses a cis-RuCl2 configuration. Dechlorination was carried out in acetone solution by Ag+ and the solvated species reacted with N,O-[oxinate (ox), -picolinate (pic)], O,O-[salicylate (sa), 3-formylsalicylate (3-fsa), 5-formylsalicylate (5-fsa)] and S,S-[xanthate (xan), dithiocarbamate (dtc)] chelators to yield [Ru(P)2(TaiMe)(N,O/O,O/S,S)] (ClO4)
n
(n = 1 for N,O- and S,S-chelators; n = 0 for O,O-chelators). The complexes were characterised by microanalysis, molar conductance, i.r., u.v.–vis. and 1H-n.m.r. data. Isomeric structures in some complexes were identified by 1H-n.m.r. spectra. The electronic spectra show a high intensity ( 104) m.l.c.t. transition in the visible region together with a weak shoulder ( 103) at longer wavelength. Redox studies exhibit a RuIII/RuII couple and quasireversible azo reduction. 相似文献