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41.
Himadri Kumar Mukerjee 《Topology and its Applications》2006,153(18):3467-3495
Complete PL and topological classification and partial smooth classification of manifolds homotopy equivalent to a Wall's manifold (defined as a mapping torus of a Dold manifold), introduced by Wall in his 1960 Annals paper on cobordism, have been done by determining: (1) the normal invariants of Wall's manifolds, (2) the surgery obstruction of a normal invariant and (3) the action of the Wall surgery obstruction groups on the smooth, PL and homeomorphism classes of homotopy Wall's manifolds (to be made precise in the body of the paper). Consequently classification results of automorphisms (self homeomorphisms, and self PL-homeomorphisms) of Dold manifolds follow. 相似文献
42.
Salicylidene-o-aminobenzothiol and its 5-chloro and 5-bromo derivatives, dibasic tridentate Schiff bases, dervied from the condensation of o-aminothiol and Salicylaldehyde, 5-chloro salicylaldehyde and 5-bromo salicylaldehyde, were used for coordination with Zr(IV), Th(IV) and UO2(VI) metal inos. The I:I (metal-ligand) stoichiometry of these complexes is shown by elemental analysis and conductometric titrations. Molecular structure of these complexes are proved by Infra-red spectroscopy and thermogravimetric analysis. Magnetic susceptibility measurements of Zr(IV), Th(IV) and UO2(VI) complexes show their diamagnetic and octahedral geometry. Results show that all the complexes have solvent molecules in coordination with metal ion. 相似文献
43.
This paper reports conduction mechanism in a-Sb2Se3 over a wide range of temperature (238 to 338 K) and frequency (5 Hz to 100 kHz). The d.c. conductivity measured as a function
of temperature shows semiconducting behaviour with activation energy ΔE=0.42 eV. Thermally induced changes in the electrical and dielectric properties of a-Sb2Se3 have been examined. The a.c. conductivity in the material has been explained using modified CBH model. The band conduction
and single polaron hopping is dominant above room temperature. However, in the lower temperature range the bipolaron hopping
dominates. 相似文献
44.
Sanjeev Kumar Raghuwanshi 《Indian Journal of Physics》2010,84(7):831-846
In this paper we have studied the asymmetric versus symmetric planar waveguide in terms of their usefulness in optical fiber communication systems. We have explored the thin
waveguide versus thick waveguide first. Later on usefulness of asymmetric versus symmetric waveguide is carried out to target for WDM optical network application. All kinds of optical network components
are fabricated on Si substrate with the point of view of their application. Here asymmetric planar structure may be more useful
compared to symmetric waveguide in terms of their non-uniform power confinement properties. However, the symmetric waveguide
structure may be more useful for their high power confinement properties. It is well known that the thin symmetric waveguide
supports at least one mode. However the thick waveguide may support many even as well as odd modes. We study the power confinement
properties for symmetric as well as asymmetric waveguide structure. We conclude that higher order modes show the nonlinear
power variations. Mode field profile for various cases is discussed as well. Comparative study between asymmetric versus symmetric waveguide has a lot of significance in optical network area. It has been shown through analysis that in asymmetric
waveguide, the power flows more through film region in the case of fundamental mode. Power confinement properties for asymmetric
waveguide versus symmetric waveguide have been studied. 相似文献
45.
Sachin S. Pathak R. D. Bhanushali I. C. Pius S. K. Mukerjee 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):1641-1648
Titania–silica microspheres have been prepared by sol–gel process. Internal gelation route, which use hexamethylenetetramine as the source of ammonia was used for the preparation spherical gel particles. A cationic surfactant, cetrimide was added in the feed broth for introducing meso-porosity in the gel network. Further paraffin oil emulsion was incorporated in the feed broth before gelation for the formation of larger pores in the gel network. The spherical gel particles thus obtained were washed and heat treated under controlled conditions to remove the entrapped surfactant, paraffin oil and other organic compounds resulting in highly porous intact titania–silica microspheres. The material was characterized by surface area, porosity and by SEM photomicrographs. The ion exchange property of this material was studied using the sorption of plutonium on this material from carbonate medium by distribution coefficient studies and ion exchange column loading and elution experiments. 相似文献
46.
V. V. Vinogradov A. V. Agafonov A. V. Vinogradov K. T. Pillai Rajesh V. Pai S. K. Mukerjee S. K. Aggarwal 《Journal of Sol-Gel Science and Technology》2011,60(1):6-10
Mesoporous γ-Al2O3 materials with high surface area and a narrow pore size distribution were synthesized by facile sol–gel procedure with application
of the polymer–colloid complex as a template. 相似文献
47.
P. S. Suresh Sanjeev Giri Raghib Husain Ramesh Mullangi 《Biomedical chromatography : BMC》2010,24(10):1052-1058
A highly sensitive, rapid assay method has been developed and validated for the estimation of S‐citalopram (S‐CPM) in rat plasma with liquid chromatography coupled to tandem mass spectrometry with electrospray ionization in the positive‐ion mode. The assay procedure involves a simple liquid–liquid extraction of S‐CPM and phenacetin (internal standard, IS) from rat plasma with t‐butyl methyl ether. Chromatographic separation was operated with 0.2% formic acid:acetonitrile (20:80, v/v) at a flow rate of 0.50 mL/min on a Symmetry Shield RP18 column with a total run time of 3.0 min. The MS/MS ion transitions monitored were 325.26 → 109.10 for S‐CPM and 180.10 → 110.10 for IS. Method validation and pre‐clinical sample analysis were performed as per FDA guidelines and the results met the acceptance criteria. The lower limit of quantitation achieved was 0.5 ng/mL and the linearity was observed from 0.5 to 5000 ng/mL. The intra‐ and inter‐day precisions were in the range of 1.14–5.56 and 0.25–12.3%, respectively. This novel method has been applied to a pharmacokinetic study and to estimate brain‐to‐plasma ratio of S‐CPM in rats. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
48.
Rajendra A. Kalgaonkar Somnath Nandi Sanjeev S. Tambe Jyoti P. Jog 《Journal of Polymer Science.Polymer Physics》2004,42(14):2657-2666
The solid‐state viscoelastic properties are examined for intercalated nanocomposites based on a copolyester and (2‐ethyl‐hexyl)dimethyl hydrogenated‐tallow ammonium montmorillonite. The nanocomposites are prepared via the direct melt intercalation technique using a conventional twin‐screw extruder. Dynamic mechanical thermal analysis of the nanocomposites is conducted using two different test setups. The dynamic mechanical relaxation spectra show an increase in the storage modulus of the nanocomposite over the entire temperature range under study as compared to the pristine polymer (except in the transition region from 70 to 80 °C). These results are analyzed using the empirical Havriliak–Negami (HN) equation. The four temperature independent HN parameters (α, β, E0, and E∞) and one temperature dependent parameter (τ, the relaxation time) are determined by solving the HN equation for each temperature over the range of temperatures. The calculated moduli results fit well with the experimental values of the relaxation spectra for the nanocomposites. This study shows that the HN model can be applied to polymer layered silicate nanocomposites, and it can be used to predict their dynamic mechanical properties over a wide range of temperatures and frequencies a priori. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2657–2666, 2004 相似文献
49.
Summary The present paper obtains necessary and sufficient conditions for factorial orthogonality in the presence of covariates. In
particular, when interactions are absent, combinatorial characterizations of the conditions, as natural generalizations of
the well-known equal and proportional frequency criteria, have been derived. 相似文献
50.
K.?Sanjeev RaoEmail author Rajeswari?Seshadri Rama?Govindarajan 《Theoretical and Computational Fluid Dynamics》2004,17(4):233-248
A new minimal composite theory that extends the approach of Govindarajan and Narasimha [1] is proposed here for 2D non-parallel compressible boundary-layer stability subject to 3D disturbances. The mean profiles are obtained from Hortons analysis, which provides a good approximation for a large range of Prandtl numbers at non-zero pressure gradients. In the lowest order, all effects of order lower than O(R-2/3) anywhere in the boundary-layer are included, R being the local boundary-layer Reynolds number; the resulting non-parallel formulation yields a set of four ordinary differential equations, as compared to the five coupled equations of classical parallel flow theory of Mack [2]. The largest effect on stability of flow non-parallelism is found to be due to the wall-normal advection of velocity and temperature disturbance quantities by the mean flow. The present theory shows that the bulk viscosity, invariably included in compressible stability theories, is irrelevant at the lowest order. In comparison with the full [O(R-1)] non-parallel theory, the present theory is marginally better than the parallel flow theory. PACS 03.50.De, 04.20-q, 42.65-k 相似文献