全文获取类型
收费全文 | 39598篇 |
免费 | 2801篇 |
国内免费 | 2132篇 |
专业分类
化学 | 28273篇 |
晶体学 | 519篇 |
力学 | 1397篇 |
综合类 | 156篇 |
数学 | 3740篇 |
物理学 | 10446篇 |
出版年
2023年 | 311篇 |
2022年 | 804篇 |
2021年 | 891篇 |
2020年 | 864篇 |
2019年 | 939篇 |
2018年 | 711篇 |
2017年 | 750篇 |
2016年 | 1287篇 |
2015年 | 1256篇 |
2014年 | 1591篇 |
2013年 | 2449篇 |
2012年 | 3046篇 |
2011年 | 3288篇 |
2010年 | 2198篇 |
2009年 | 2018篇 |
2008年 | 2753篇 |
2007年 | 2463篇 |
2006年 | 2353篇 |
2005年 | 2100篇 |
2004年 | 1816篇 |
2003年 | 1423篇 |
2002年 | 1483篇 |
2001年 | 1037篇 |
2000年 | 840篇 |
1999年 | 555篇 |
1998年 | 421篇 |
1997年 | 407篇 |
1996年 | 444篇 |
1995年 | 337篇 |
1994年 | 340篇 |
1993年 | 348篇 |
1992年 | 308篇 |
1991年 | 268篇 |
1990年 | 187篇 |
1989年 | 179篇 |
1988年 | 158篇 |
1987年 | 147篇 |
1986年 | 113篇 |
1985年 | 194篇 |
1984年 | 130篇 |
1983年 | 113篇 |
1982年 | 128篇 |
1981年 | 96篇 |
1980年 | 88篇 |
1978年 | 86篇 |
1977年 | 89篇 |
1976年 | 100篇 |
1975年 | 103篇 |
1974年 | 79篇 |
1973年 | 103篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
91.
92.
Sang Hyun Kwon Yoshio Okamoto Chiyo Yamamoto Wonjo Cheong Myeonghee Moon Jung Hag Park 《Analytical sciences》2006,22(12):1525-1529
Porous zirconia particles are very robust material and have received considerable attention as a stationary phase support for HPLC. We prepared cellulose dimethylphenylcarbamate-bonded carbon-clad zirconia (CDMPCCZ) as a chiral stationary phase (CSP) for separation of enantiomers of a set of 14 racemic compounds in normal phase (NP) and reversed-phase (RP) liquid chromatography. Retention and enantioselectivity on CDMPCCZ were compared to those on CDMPC-coated zirconia (CDMPCZ) to see how the change in immobilization method of the chiral selector affects the retention and chiral selectivity. In NPLC, retention was longer and the number of resolved racemates was smaller on CDMPCCZ than on CDMPCZ. However, chiral selectivity factors for some resolved racemates were better on CDMPCCZ than on CDMPCZ. The longer retention on CDMPCCZ is likely due to strong, non-chiral discriminating interactions with the carbon layer on CDMPCZ. In RPLC only two racemates were resolved on CDMPCCZ, but retention times were shorter than, and resolutions were comparable to, those in NPLC, indicating a potential for improving chromatographic performance of the CDMPCCZ column in RPLC with optimized column preparation and separation conditions. 相似文献
93.
We apply a Bayesian approach to the problem of prediction in an unbalanced growth curve model using noninformative priors. Due to the complexity of the model, no analytic forms of the predictive densities are available. We propose both approximations and a prediction-oriented Metropolis-Hastings sampling algorithm for two types of prediction, namely the prediction of future observations for a new subject and the prediction of future values for a partially observed subject. They are illustrated and compared through real data and simulation studies. Two of the approximations compare favorably with the approximation in Fearn (1975, Biometrika, 62, 89–100) and are very comparable to the more accurate Rao-Blackwellization from Metropolis-Hastings sampling algorithm. 相似文献
94.
N.-K. Lee T.A. Vilgis 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(4):451-465
We study the elastic properties of single A/B random copolymer chains, with a specific sequence and use them as theoretical
model for so called HP proteins. HP proteins carry hydrophilic (P) and hydrophobic (H) monomers. We predict a rich structure
in the force-extension relations which can be attributed to the information in the sequence. The variational method is used
to probe local minima on the path of stretching and releasing for the chain molecules. At a given force, we find multiple
configurations which are separated by energy barriers. A collapsed globular configuration consists of several domains which
unravel cooperatively. Upon stretching, the unfolding path shows a stepwise pattern corresponding to the unfolding of each
domain. While releasing, several cores can be created simultaneously in the middle of the chain, resulting in a different
path of collapse. The long-range interactions and stiffness of the chain simplify the potential landscape given by the disorder
in sequence.
Received 5 March 2002 / Received in final form 16 May 2002 Published online 13 August 2002 相似文献
95.
我国医疗费用增长与医疗设备投入的相关性研究 总被引:3,自引:0,他引:3
近年来我国卫生总费用占GDP的比例增长很快,而在卫生费用结构上则发生政府投入下降和个人支出的上升。本文采集了大量的统计数据,采用统计相关性研究的方法,论证了医疗设备规模的不断扩大是导致医疗费用上升的主要因素之一;医疗设备的快速增长与医院维修费用投入的增长直接相关,而引起医疗设备维修大量投入的主要原因则是故障期内医疗设备的非正常闲置。本文通过对个人卫生费用的上升、医疗设备规模的扩大及其医疗设备维修投入费用增加相关性的分析,说明了在这种关系下,十分有必要研究医院医疗设备维修体系,以在卫生投入和患者权益上达到平衡。 相似文献
96.
Myung-Soon Lee 《Applied Surface Science》2006,252(14):5019-5025
We prepared high quality Au(1 1 1) film on Si wafer through the spin coating and thermal decomposition of a gold ink, spin-coated-and-fired (SCAF) Au film. The X-ray measurements, XRD and pole-figure analysis, showed that the SCAF Au film has a (1 1 1) out-of-plane orientation with a random in-plane orientation. In order to confirm the chemical activity of the SCAF Au film, we demonstrate the formation of patterned structures with the film by using soft lithography technique. The chemical activities of this physically stable SCAF Au film to the alkanethiols were at least equivalent those of physically deposited the Au films. The possibility of the mass production of micro patterned structure with the SCAF Au film was also demonstrated over the wide region on Si wafer by the microcontact lithography. These suggest that the Au film will help the easy fabrication of various nanosized devices on Si wafer and other substrates. 相似文献
97.
Young Hee Geum Young Ik Kim Kang Sup Lee 《Journal of Applied Mathematics and Computing》2007,25(1-2):109-118
A parametric boundary equation is established for the principal period-2 bulb in the cubic Mandelbrot set. Using its geometry, an efficient escape-time algorithm which reduces the construction time for the period-2 bulbs in the cubic Mandelbrot set is introduced and the implementation graphic results display the fascinating fractal beauty 相似文献
98.
A high-performance liquid chromatographic procedure was developed for the quantitation of homoharringtonine in plasma. Harringtonine was used as an internal standard, and 1 ml of sample was required. The single-step extraction with dichloromethane resulted in almost 100% recovery for homoharringtonine and harringtonine. Analysis was performed on a reversed-phase CN column with amperometric detection. Chromatography was completed in 12 min. At an oxidation potential of +1.0 V, the detection limit was 1 ng/ml at a signal-to-noise ratio of 2. The mean analytical recovery for homoharringtonine was 99.5%. The within-run precision and between-run precision were both less than 11%. The method is equally applicable for plasma or serum, and it has been demonstrated to be applicable for study of the pharmacokinetics of homoharringtonine in patients suffering from acute non-lymphocytic leukaemia. 相似文献
99.
100.
Improving Construction for Connected Dominating Set with Steiner Tree in Wireless Sensor Networks 总被引:2,自引:0,他引:2
Manki Min Hongwei Du Xiaohua Jia Christina Xiao Huang Scott C.-H. Huang Weili Wu 《Journal of Global Optimization》2006,35(1):111-119
The connected dominating set plays an important role in ad hoc wireless networking. Many constructions for approximating the minimum connected dominating set have been proposed in the
literature. In this paper, we propose a new one with Steiner tree, which produces approximation solution within a factor of
6.8 from optimal. This approximation algorithm can also be implemented distributedly. 相似文献