全文获取类型
收费全文 | 4385篇 |
免费 | 275篇 |
国内免费 | 67篇 |
专业分类
化学 | 3088篇 |
晶体学 | 34篇 |
力学 | 98篇 |
综合类 | 3篇 |
数学 | 501篇 |
物理学 | 1003篇 |
出版年
2023年 | 41篇 |
2022年 | 32篇 |
2021年 | 83篇 |
2020年 | 90篇 |
2019年 | 109篇 |
2018年 | 60篇 |
2017年 | 75篇 |
2016年 | 134篇 |
2015年 | 121篇 |
2014年 | 157篇 |
2013年 | 227篇 |
2012年 | 285篇 |
2011年 | 328篇 |
2010年 | 207篇 |
2009年 | 191篇 |
2008年 | 267篇 |
2007年 | 212篇 |
2006年 | 231篇 |
2005年 | 208篇 |
2004年 | 165篇 |
2003年 | 114篇 |
2002年 | 126篇 |
2001年 | 79篇 |
2000年 | 65篇 |
1999年 | 51篇 |
1998年 | 39篇 |
1997年 | 47篇 |
1996年 | 33篇 |
1995年 | 32篇 |
1994年 | 28篇 |
1993年 | 30篇 |
1992年 | 28篇 |
1991年 | 22篇 |
1990年 | 16篇 |
1988年 | 19篇 |
1987年 | 25篇 |
1985年 | 28篇 |
1984年 | 21篇 |
1983年 | 22篇 |
1980年 | 22篇 |
1979年 | 16篇 |
1934年 | 26篇 |
1933年 | 15篇 |
1932年 | 29篇 |
1931年 | 24篇 |
1930年 | 21篇 |
1928年 | 16篇 |
1926年 | 23篇 |
1923年 | 19篇 |
1922年 | 16篇 |
排序方式: 共有4727条查询结果,搜索用时 265 毫秒
21.
A new chemiluminescence method for the determination of carbamazepine (CBZ) has been developed. The method is based on the chemiluminescence produced in the reaction of tris(2,2'-bipyridine)ruthenium(III) and CBZ in an acidic medium. The chemiluminescence intensity was enhanced by organic solvents in the reaction system. Under the optimum experimental conditions, the calibration curve was linear over the range 4.0 x 10(-3)-8.6 x 10(-7) mol/L for CBZ. The detection limit (S/N = 3) was 2.5 x 10(-7) mol/L and the relative standard deviation of six replicate measurements was 2.6% for 4.0 x 10(-4) mol/L of CBZ. The possible reaction mechanism were also discussed. The chemiluminescence method was successfully applied to assay the CBZ contents in pharmaceutical tablets. 相似文献
22.
23.
24.
An algorithm for a time accurate incompressible Navier–Stokes solver on an unstructured grid is presented. The algorithm uses a second order, three‐point, backward difference formula for the physical time marching. For each time step, a divergence free flow field is obtained based on an artificial compressibility method. An implicit method with a local time step is used to accelerate the convergence for the pseudotime iteration. To validate the code, an unsteady laminar flow over a circular cylinder at a Reynolds number of 200 is calculated. The results are compared with available experimental and numerical data and good agreements are achieved. Using the developed unsteady code, an interaction of a Karman vortex street with an elliptical leading edge is simulated. The incident Karman vortex street is generated by a circular cylinder located upstream. A clustering to the path of the vortices is achieved easily due to flexibility of an unstructured grid. Details of the interaction mechanism are analysed by investigating evolutions of vortices. Characteristics of the interactions are compared for large‐ and small‐scale vortex streets. Different patterns of the interaction are observed for those two vortex streets and the observation is in agreement with experiment. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
25.
In this paper we introduce a new notion of infine nonsmooth functions and give several characterizations of infineness property. We prove alternative theorems with mixed constraints (i.e., inequality and equality constraints) being described by invex-infine nonsmooth functions. We establish a necessary and sufficient condition for a solution of a vector optimization problem involving mixed constraints to be a properly efficient solution. 相似文献
26.
27.
28.
LetX,X
1,X
2,... be i.i.d. random vectors in d. The limit laws that can arise by suitable affine normalizations of the partial sums,S
n=X
1+...+X
n, are calledoperator-stable laws. These laws are a natural extension to
d
of the stable laws on. Thegeneralized domain of attraction of [GDOA()] is comprised of all random vectorsX whose partial sums can be affinely normalized to converge to . If the linear part of the affine transformation is restricted to take the formn
–B for some exponent operatorB naturally associated to thenX is in thegeneralized domain of normal attraction of [GDONA()]. This paper extends the theory of operator-stable laws and their domains of attraction and normal attraction. 相似文献
29.
30.
N. Huppert Marion Würtele Hermann H. Hahn 《Analytical and bioanalytical chemistry》1998,362(6):529-536
A rapid, inexpensive and solvent-free method for the simultaneous determination of the polyamide plasticizer N-butylbenzenesulfonamide (NBBS) and the widely used pharmaceutical Ibuprofen by solid phase microextraction (SPME) combined with gas chromatography/mass spectrometry (GC/MSD) in wastewater samples was developed. Besides the optimized analytical conditions, results of investigations with varying analytical parameters are reported. Problems, which may occur during the analytical procedure (e.g. salt deposits, adsorption phenomena, carry-over), are discussed. For the determination of Ibuprofen, it is important to carry out the extraction under acidic conditions with sufficiently buffered samples; the GC/MSD system must be very clean and well maintained. SPME allows an extraction of Ibuprofen without derivatization of its carboxylic group. For quantification in complex matrices, the standard addition technique is necessary. Limit of detection and limit of determination are 0.1 μg/L for both analytes. NBBS and Ibuprofen were detected in several raw and treated wastewater samples from municipal wastewater treatment plants in the range from < 0.1 to 3.5 μg/L. 相似文献