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41.
Chiappe C Detert H Lenoir D Pomelli CS Ruasse MF 《Journal of the American Chemical Society》2003,125(10):2864-2865
Weakly bound molecular complexes play an important role in chemistry, physics, and biodisciplines. The preequilibrium pi-complexes of various alkenes with bromine have been examined quantitatively, and a direct relationship between association constants (KF) of these pi-complexes and polarizability of the olefins was found. The stability of the Br2-olefin pi complexes is affected by both the donor ionization potential and the polarizability of the olefin, and an equation able to take into account both effects is proposed. 相似文献
42.
A new three-component domino reaction catalyzed by palladium was devised, producing polysubstituted bicyclic molecules in good yields from readily available substrates. The reaction conditions and the scope of the process were examined, and a possible mechanism is proposed. [reaction: see text] 相似文献
43.
László Erdős Sandrine Péché José A. Ramírez Benjamin Schlein Horng‐Tzer Yau 《纯数学与应用数学通讯》2010,63(7):895-925
We consider N × N Hermitian Wigner random matrices H where the probability density for each matrix element is given by the density ν(x) = e?U(x). We prove that the eigenvalue statistics in the bulk are given by the Dyson sine kernel provided that U ∈ C6( \input amssym $\Bbb R$ ) with at most polynomially growing derivatives and ν(x) ≥ Ce?C|x| for x large. The proof is based upon an approximate time reversal of the Dyson Brownian motion combined with the convergence of the eigenvalue density to the Wigner semicircle law on short scales. © 2010 Wiley Periodicals, Inc. 相似文献
44.
An efficient route to a 5,6-dihydropyrano[3,4-b]pyridin-8-one core in two steps from enaminolactones
Cheikh Sall Sandrine Paquelet Jean Michel Chezal Yves Blache 《Tetrahedron letters》2008,49(8):1301-1304
A convenient two step conversion of heterocyclic enaminolactones to heterocyclic fused 2-pyran-1-ones is reported. The use of this method can be applied to a wide variety of aromatic and heteroaromatic amines to give potentially biologically active compounds in good yields. 相似文献
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Efficient reaction conditions have been developed to prepare highly functionalized chiral pyranosido-pyrimidine by regioselective alkylation of the pyranoside ring and palladium-catalyzed cross-coupling reaction on the pyrimidine ring under microwave activation. Such scaffold contains three different functions suitable for selective derivatization and could find applications in the design of peptidomimetics. 相似文献
48.
Aline Bonami Sandrine Grellier Mohammad Kacim 《Transactions of the American Mathematical Society》2008,360(3):1377-1390
We extend to multilinear Hankel operators the fact that some truncations of bounded Hankel operators are still bounded. We prove and use a continuity property of bilinear Hilbert transforms on products of Lipschitz spaces and Hardy spaces.
49.
Hannah DC Dunn NJ Ithurria S Talapin DV Chen LX Pelton M Schatz GC Schaller RD 《Physical review letters》2011,107(17):177403
We report heat dissipation times in semiconductor nanocrystals of CdSe. Specifically, a previously unresolved, subnanosecond decay component in the low-temperature photoluminescence decay dynamics exhibits longer decay lifetimes (tens to hundreds of picoseconds) for larger nanocrystals as well as a size-independent, ~25-meV spectral shift. We attribute the fast relaxation to transient phonon-mediated relaxation arising from nonequilibrium acoustic phonons. Following acoustic phonon dissipation, the dark exciton state recombines more slowly via LO-phonon assistance resulting in the observed spectral shift. The measured relaxation time scales agree with classical calculations of thermal diffusion, indicating that interfacial thermal conductivity does not limit thermal transport in these semiconductor nanocrystal dispersions. 相似文献
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