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991.
Jones RM Van De Water RW Lindsey CC Hoarau C Ung T Pettus TR 《The Journal of organic chemistry》2001,66(10):3435-3441
A low-temperature method for generating o-quinone methides is described which permits facile introduction of assorted R substituents onto the aryl ring system at low temperature. The method is useful for the efficient preparation of ortho-ring-alkylated phenols. 相似文献
992.
Loss S Magistrato A Cataldo L Hoffmann S Geoffroy M Röthlisberger U Grützmacher H 《Angewandte Chemie (International ed. in English)》2001,40(7):1143
The cover picture shows the metalloporphyrin heterodimer [(tpp)Mo$\rm{\mathop{-}^{4}}$Re(oep)](+) with the novel [Mo$\rm{\mathop{-}^{4}}$Re](5+) core. The core represents the first example of a quadruple bond between elements of different triads, thus proving that heterometallic quadruple bonds are not limited to the Group 6 metals. From the space-filling model it is clear that there is no interaction between the stabilizing porphyrin ligands. The ORTEP plot in a projection along the Re-Mo axis emphasizes the perfectly eclipsed geometry of the porphyrins, which is unambiguous proof of the existence of the quadruple bond in the solid state. The diamagnetism and large magnetic anisotropy of the cation, as determined by (1)H NMR spectroscopy, indicate that the quadruple bond is retained in solution. A logical and well-defined synthetic route was used to synthesize the dimer, and can be extended to other metalloporphyrins to generate further novel quadruple bonds (the picture was generated by Marina Boulan, St. Petersburg, Russia), full details are reported by J. P. Collman et al. on p. 1271 ff. 相似文献
993.
994.
995.
A. N. Andreyev D. Ackermann F. P. Heßberger S. Hofmann M. Huyse I. Kojouharov B. Kindler B. Lommel G. Münzenberg R. D. Page K. Van de Vel P. Van Duppen K. Heyde 《The European Physical Journal A - Hadrons and Nuclei》2003,18(1):55-64
Alpha-decay of the new nuclide 184Bi has been studied in the complete-fusion reaction 93Nb(94Mo, 3n)184Bi at the velocity filter SHIP. The evaporation residues were separated in-flight and subsequently identified on the basis of recoil-
, recoil-
-
analysis and excitation functions measurements. Two
-decaying isomeric states in 184Bi with half-life values of 13(2) ms and 6.6(1.5) ms were identified. The
-branching ratio of 180Tl was deduced for the first time as
. Improved data on the fine-structure
-decay of 186Bi were obtained in the 93Nb(95Mo, 2n)186Bi reaction. A similarity of the decay energies and half-life values of 184,186Bi is pointed out and a possible explanation for this effect is suggested.Received: 14 March 2003, Revised: 29 April 2003, Published online: 2 September 2003PACS:
23.60.+e
decay - 27.70.+q
- 27.80.+w
K. Heyde: Present address: EP-ISOLDE, CERN, CH-1211, Geneva 23, Switzerland. 相似文献
996.
E. Galichet F. Gulminelli D. C. R. Guinet M. F. Rivet J. F. Lecolley R. Bougault G. Auger B. Borderie B. Bouriquet A. Buta J. L. Charvet A. Chbihi J. Colin D. Cussol R. Dayras D. Durand J. D. Frankland B. Guiot S. Hudan P. Lautesse F. Lavaud N. Le Neindre O. Lopez L. Manduci J. Marie L. Nalpas J. Normand M. Pârlog P. Paw lowski E. Plagnol E. Rosato J. C. Steckmeyer B. Tamain A. Van Lauwe E. Vient C. Volant J. P. Wieleczko INDRA Collaboration 《The European Physical Journal A - Hadrons and Nuclei》2003,18(1):75-86
The transport properties of the 36Ar +58Ni system at
measured with the INDRA array, are studied within the BNV kinetic equation. A general protocol of comparison between the N-body experimental fragment information and the one-body distribution function is developed using global variables, with a special focus on charge density. This procedure avoids any definition of sources and any use of an afterburner in the simulation. We shall discuss the feasibility of such an approach and the distortions induced by the finite detection efficiency and the completeness requirements of the data selection. The sensitivity of the different global observables to the macroscopic parameters of the effective nuclear interaction will be studied in detail.Received: 21 January 2003, Published online: 5 August 2003PACS:
25.70.-z Low and intermediate energy heavy-ion reactions - 24.10.-i Nuclear reaction models and methodsN. Le Neindre: Permanent address: Institut de Physique Nuclaire, IN2P3-CNRS, F-91406 Orsay cedex, France. 相似文献
997.
J.W.?Van OrdenEmail author S.?Jeschonnek 《The European Physical Journal A - Hadrons and Nuclei》2003,17(3):391-395
The phenomena of scaling and Bloom-Gilman duality are examined in the context of simple nonrelativistic and relativistic quantum-mechanical models. These models are shown to scale and to show the qualitative features of Bloom-Gilman duality. This suggests that these phenomena do not necessarily require the properties of QCD.Received: 1 November 2002, Published online: 15 July 2003PACS:
12.40.Nn Regge theory, duality, absorptive/optical models - 12.39.Ki Relativistic quark model - 13.60.Hb Total and inclusive cross-sections (including deep-inelastic processes) 相似文献
998.
Regina Sandra Burachik B. F. Svaiter 《Proceedings of the American Mathematical Society》2003,131(8):2379-2383
Recently, the authors studied the connection between each maximal monotone operator and a family of convex functions. Each member of this family characterizes the operator and satisfies two particular inequalities.
The aim of this paper is to establish the converse of the latter fact. Namely, that every convex function satisfying those two particular inequalities is associated to a unique maximal monotone operator.
999.
The aim of this paper is to study necessary conditions for existence of weak solutions of the inequality
1000.
Many graphs arising in various information networks exhibit the "power law" behavior -the number of vertices of degree k is proportional to k-# for some positive #. We show that if # > 2.5, the largest eigenvalue of a random power law graph is almost surely(1+ o(1))?m (1+ o(1))\sqrt{m} where m is the maximum degree. Moreover, the klargest eigenvalues of a random power law graph with exponent # have power law distribution with exponent 2# if the maximum degree is sufficiently large, where k is a function depending on #, mand d, the average degree. When 2<#< 2.5, the largest eigenvalue is heavily concentrated at cm3-# for some constant c depending on # and the average degree. This result follows from a more general theorem which shows that the largest eigenvalue of a random graph with a given expected degree sequence is determined by m, the maximum degree, and [(d)\tilde] \tilde{d} , the weighted average of the squares of the expected degrees. We show that the k-th largest eigenvalue is almost surely (1+ o(1))?{mk} (1+ o(1))\sqrt{m_k} where mk is the k-th largest expected degree provided mk is large enough. These results have implications on the usage of spectral techniques in many areas related to pattern detection and information retrieval. 相似文献