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61.
Saibal Ray P. C. Ray M. Khlopov P. P. Ghosh U. Mukhopadhyay P. Chowdhury 《International Journal of Theoretical Physics》2009,48(9):2499-2510
Choosing the three phenomenological models of the dynamical cosmological term Λ, viz.,
,
and Λ∼ρ where a is the cosmic scale factor, it has been shown by the method of numerical analysis for the considered non-linear differential
equations that the three models are equivalent for the flat Universe k=0 and for arbitrary non-linear equation of state. The evolution plots for dynamical cosmological term Λ vs. time t and also the cosmic scale factor a vs. t are drawn here for k=0,+1. A qualitative analysis has been made from the plots which supports the idea of inflation and hence expanding Universe. 相似文献
62.
H. Watanabe G. J. Lane G. D. Dracoulis A. P. Byrne P. Nieminen F. G. Kondev K. Ogawa M. P. Carpenter R. V. F. Janssens T. Lauritsen D. Seweryniak S. Zhu P. Chowdhury 《The European Physical Journal A - Hadrons and Nuclei》2009,42(2):163-169
The nucleus $\ensuremath {\rm ^{127}Sb}$ , which is on the neutron-rich periphery of the $\ensuremath \beta$ -stability region, has been populated in complex nuclear reactions involving deep-inelastic and fusion-fission processes with $\ensuremath {\rm {}^{136}Xe}$ beams incident on thick targets. The previously known isomer at 2325 keV in $\ensuremath {\rm {}^{127}Sb}$ has been assigned spin and parity $\ensuremath 23/2^+$ , based on the measured $\ensuremath \gamma$ - $\ensuremath \gamma$ angular correlations and total internal conversion coefficients. The half-life has been determined to be 234(12) ns, somewhat longer than the value reported previously. The 2194 keV state has been assigned $\ensuremath J^{\pi} = 19/2^+$ and identified as an isomer with $\ensuremath T_{1/2} = 14(1) {\rm ns}$ , decaying by two $\ensuremath E2$ branches. The observed level energies and transition strengths are compared with the predictions of a shell model calculation. Two $\ensuremath 15/2^+$ states have been identified close in energy, and their properties are discussed in terms of mixing between vibrational and three-quasiparticle configurations. 相似文献
63.
Satyajit Banerjee Atish Datta Chowdhury Subhas Kumar Ghosh 《Mathematics in Computer Science》2008,1(4):673-688
Obtaining a matching in a graph satisfying a certain objective is an important class of graph problems. Matching algorithms
have received attention for several decades. However, while there are efficient algorithms to obtain a maximum weight matching,
not much is known about the maximum weight maximum cardinality, and maximum cardinality maximum weight matching problems for
general graphs. Our contribution in this work is to show that for bounded weight input graphs one can obtain an algorithm
for both maximum weight maximum cardinality (for real weights), and maximum cardinality maximum weight matching (for integer
weights) by modifying the input and running the existing maximum weight matching algorithm. Also, given the current state
of the art in maximum weight matching algorithms, we show that, for bounded weight input graphs, both maximum weight maximum
cardinality, and maximum cardinality maximum weight matching have algorithms of similar complexities to that of maximum weight
matching. Subsequently, we also obtain approximation algorithms for maximum weight maximum cardinality, and maximum cardinality
maximum weight matching.
相似文献
64.
J. Chowdhury S. Sil S. N. Karmakar B. Bhattacharyya 《The European Physical Journal B - Condensed Matter and Complex Systems》2010,76(3):435-444
We have presented the role of the Coulomb interaction (U) and the magnetic
field [(B)\vec]\vec{B} on the ground state properties of the quasi-one dimensional
graphite ribbon structures at half-filling. Mean field Hartree-Fock
Approximation is used to study the systems. To understand the boundary effects
in graphite structures, we have compared the results of these systems
with those of the square lattice ribbon structures. Studying the density of
states, the Drude weight and the charge gap, we have drawn the U – B phase
diagrams for the zigzag and the armchair graphite ribbons. 相似文献
65.
Shubhamoy Chowdhury Arnab Bhattacharya Pinki Saha Smita Majumder E. Suresh 《Journal of Coordination Chemistry》2016,69(24):3664-3676
Employing 1-(2-methoxybenzyl)-2-(2-methoxyphenyl)-1H-benzimidazole (bpb) as a monodentate ligand, a new greenish-blue copper(II) complex, [Cu(bpb)2(NO3)2] (1a), has been synthesized. 1a has been characterized analytically and spectroscopically. The X-ray crystal structure of 1a reveals that it adopts a cis disposition with respect to the ligands. The solid state structure of 1a is stabilized by intramolecular offset face-to-face π–π stacking. Non-covalent supramolecular edge-to-face C–H?π interactions with neighboring molecules give 1-D supramolecular chains that further lead to the formation of an assembled 3-D supramolecular metal-organic framework via hydrogen bonding interactions. 1a shows blue fluorescence most likely due to intramolecular offset face-to-face π–π stacking. At room temperature, 1a is one-electron paramagnetic. It shows a rhombic EPR spectrum with g1 = 2.12, g2 = 2.42, and g3 = 2.52 in the solid state at liquid nitrogen temperature. In cyclic voltammetry, 1a displays a one-electron oxidative Cu(II)/Cu(III) couple. Our DFT calculations, corroborate the observed experimental results of 1a. 相似文献
66.
J.S. Yadav B.V. Subba Reddy Swapan Kumar Biswas Sandip Sengupta P. Vishnumurthy 《Tetrahedron letters》2008,49(6):1034-1036
Phenacyl bromides undergo smooth vic-diallylation and dipropargylation with allyl and propargyl indium reagents generated in situ from metallic indium and allyl or propargyl bromide to produce 4-arylocta-1,7-dien-4-ol derivatives in good yields. Phenacyl chloride and azide also participated effectively in bis-allylation. Similar results are also obtained from in situ generated allyl or propargyl zinc bromide. 相似文献
67.
The exchange part of the usual Hartree-Fock potential in the unrestricted Hartree-Fock (UHF) theory is suitablyaveraged to construct an, average one-electron model Hamiltonian which generates a set of spin-restricted one-electron orbitals in
a self-consistent manner. These orbitals are then used to calculate the electronic energy of the open-shell system by using
the proper functional form for the energy which handles the exchange terms correctly. The eigenvalues ofF
av can be used for calculating either the spin-polarised or spin-averaged ionisation potentials of different orbitals at theKoopmans’ theorem level of approximation. Comparison ofE
ac with the UHF-energy shows thatE
UHF<E
ac in each case revealing some kind of an upper bound nature ofE
ac. An approximate variational argument is given. Relationship of our model with the hyper-Hartree-Fock theory of slater is
explored and the general problem of eliminating ‘self-interaction’ terms in average Fock-operator based theories is discussed. 相似文献
68.
Membrane Disruption and Enhanced Inhibition of Cell‐Wall Biosynthesis: A Synergistic Approach to Tackle Vancomycin‐Resistant Bacteria 下载免费PDF全文
Venkateswarlu Yarlagadda Dr. Sandip Samaddar Dr. Krishnamoorthy Paramanandham Dr. Bibek R. Shome Dr. Jayanta Haldar 《Angewandte Chemie (International ed. in English)》2015,54(46):13644-13649
Resistance to glycopeptide antibiotics, the drugs of choice for life‐threatening bacterial infections, is on the rise. In order to counter the threat of glycopeptide‐resistant bacteria, we report development of a new class of semi‐synthetic glycopeptide antibiotics, which not only target the bacterial membrane but also display enhanced inhibition of cell‐wall biosynthesis through increased binding affinity to their target peptides. The combined effect of these two mechanisms resulted in improved in vitro activity of two to three orders of magnitude over vancomycin and no propensity to trigger drug resistance in bacteria. In murine model of kidney infection, the optimized compound was able to bring bacterial burden down by about 6 logs at 12 mg kg?1 with no observed toxicity. The results furnished in this report emphasize the potential of this class of compounds as future antibiotics for drug‐resistant Gram‐positive infections. 相似文献
69.
Andrzej Rajca Prof. Velavan Kathirvelu Dr. Sandip K. Roy Dr. Maren Pink Dr. Suchada Rajca Dr. Santanu Sarkar Sandra S. Eaton Prof. Gareth R. Eaton Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(19):5778-5782
Site‐directed spin labeling and EPR spectroscopy offer accurate, sensitive tools for the characterization of structure and function of macromolecules and their assemblies. A new rigid spin label, spirocyclohexyl nitroxide α‐amino acid and its N‐(9‐fluorenylmethoxycarbonyl) derivative, have been synthesized, which exhibit slow enough spin‐echo dephasing to permit accurate distance measurements by pulsed EPR spectroscopy at temperatures up to 125 K in 1:1 water/glycerol and at higher temperatures in matrices with higher glass transition temperatures. Distance measurements in the liquid nitrogen temperature range are less expensive than those that require liquid helium, which will greatly facilitate applications of pulsed EPR spectroscopy to the study of structure and conformation of peptides and proteins. 相似文献
70.
Amal Halder Sandip K. Nayak Subrata Chattopadhyay Sumanta Bhattacharya 《Journal of solution chemistry》2012,41(2):223-240
The present article reports the host-guest complexation of a calix[4]arene derivative, namely 4-iso-propyl-calix[4]arene (1), with fullerenes (both C60 and C70) in toluene and benzonitrile solutions. It is observed that the charge-transfer (CT) absorption bands are located in the
ground state for the C60 and C70 complexes of 1. By utilizing the CT absorption bands, various important physicochemical parameters like the oscillator strength, resonance
energy, transition dipole moment, electronic coupling element and solvent reorganization energies have been estimated for
the C60-1 and C70-1 complexes. The CT transition energy is very helpful for determining the vertical ionization potential of 1 in solution. Jobs method of continuous variation was used to establish 1:1 stoichiometry for the fullerene complexes of 1. The most fascinating feature of the present study is that 1 binds C70 preferentially compared to C60 as obtained from binding constant (K) data. The effect of solvent on the complexation of fullerenes (C60 and C70) with 1 is clearly observed from the trend in the K values: in toluene and whereas in benzonitrile, and . Molecular mechanics force field (MMMF) calculations reveal fascinating features regarding the binding pattern of fullerenes
towards 1 in vacuo in terms of enthalpy of formation. MMMF calculations establish that during C70-1 complexation, C70 is directed in an end-on manner rather than the traditional side-on pattern. 相似文献