全文获取类型
收费全文 | 109篇 |
免费 | 16篇 |
国内免费 | 20篇 |
专业分类
化学 | 82篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 10篇 |
物理学 | 51篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2013年 | 5篇 |
2012年 | 5篇 |
2011年 | 2篇 |
2010年 | 6篇 |
2009年 | 7篇 |
2008年 | 7篇 |
2007年 | 4篇 |
2006年 | 3篇 |
2005年 | 8篇 |
2004年 | 8篇 |
2003年 | 10篇 |
2002年 | 16篇 |
2001年 | 11篇 |
2000年 | 11篇 |
1999年 | 5篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1982年 | 3篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1909年 | 2篇 |
1904年 | 1篇 |
排序方式: 共有145条查询结果,搜索用时 46 毫秒
91.
Mixed-metal carbonyl clusters of W2Ir2(CO)10(η^5-C5H4Me)2 1 and W2Ir2(μ-L)(CO)8(η^5-C5H4Me)2 (L = dppe 2, dppf 3) have been studied by TDDFT method focusing on their electronic and nonlinear optical properties. These three clusters exhibit the first static hyperpolarizabilities of medium magnitude (βtot-10×10^-30 esu). The origin of β is discussed by the new proposed orbital-pair decomposition scheme by Barandes et al. The result suggests that the β values of the two clusters are mainly originated from d-d electron transition within the metal skeleton, and d-p (π*) electron transition from metals to carbonyls and phenyl. The additional coordination by the electron donor group, ferrocene, makes cluster 3 own much larger β values, and the relatively longer range charge transfer from d orbitals of ferrocene to d orbirals of Ir and W is responsible for the enhanced β values. 相似文献
92.
Richard D. Chambers Takashi Nakano Graham Sandford 《Journal of fluorine chemistry》2009,130(9):792-1498
Attempts to develop a direct enantioselective fluorination protocol using elemental fluorine and an appropriate Lewis acid and chiral ligand system are described. 相似文献
93.
J. F. Farnum M. D. Glascock M. K. Sandford S. Gerritsen 《Journal of Radioanalytical and Nuclear Chemistry》1995,196(2):267-274
The elemental composition of 44 human bone samples and 56 soil samples from the Pre-Colombian Tutu site, St. Thomas, Virgin Islands were determined by neutron activation analysis and atomic absorption spectroscopy. Soils from the site were analyzed for the purpose of assessing diagenetic change in the bone samples after deposition. Twenty two elements were observed in the Tutu bones. The compositional data will be considered for use, along with other archaeological information, to aid in dietary reconstruction at the Tutu site. 相似文献
94.
A hadron and string cascade model, JPCIAE, together with the corresponding Monte Carlo event generator, has been employed in this paper to investigate further the charge fluctuations in Au+Au collisions at Snn = 130 GeV. The default JPCIAE calculations are in good agreement with PHENIX and STAR data. We found that the thermal predictions for the π gas, the resonance π gas and quark matter deviate, respectively, from the corresponding dynamical simulations from the JPCIAE model. The discrepancies were also found between the π charge fluctuations and the charge fluctuations of all species of hadrons. However the charge fluctuations for "π from ρ and ω decay" and for all the hadrons from resonance decay are close to each other, indicating the correlation between positively and negatively charged hadrons is not sensitive to the species of hadrons. This work shows further that it is questionable to use the charge fluctuations as a signature of QGP. 相似文献
95.
Sandford G 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(7):1464-1469
Perhalogenated heteroaromatic systems, such as trichloro-s-triazine and pentafluoropyridine, are multifunctional "building blocks" that react with a number of appropriate difunctional nucleophiles to provide access to a variety of macrocyclic and even cage-like molecular architectures. Unusual structural and complexation characteristics of the systems reported so far, such as the recognition of anions, provide a further stimulus for the development of this area. 相似文献
96.
Chambers RD Cooper JA Copin E Sandford G 《Chemical communications (Cambridge, England)》2001,(23):2428-2429
A general, efficient approach for the synthesis of fluorocarbon iodides and di-iodides bearing hydrocarbon groups is described and the synthetic utility of these new systems is demonstrated in reactions with thiols. 相似文献
97.
采用含时密度泛函理论方法(TDDFT)计算了IB族过渡金属及第5周期的金属杂化偶氮苯生色团的二阶非线性光学极化率。研究了金属杂化偶氮苯生色团的电子激发跃迁。结果表明, 与金属离子络合后的杂化偶氮苯生色团, 二阶非线性光学极化率明显改变, 是金属的推拉电子效应的结果。IB族金属的在原有机偶氮苯共轭体系的电荷转移方向的强拉电子效应, 增大了电荷转移范围, 使二阶非线性光学极化率增大。与Nb络合的杂化生色团, 沿原电荷转移相反的方向拉动电荷, 电荷转移跃迁局限于金属离子附近, 未能产生大的激发跃迁偶极矩, 体系的二阶非线性光学响应因而降低。激发跃迁能量是另一个主要影响因素, 同一类跃迁中, 金属杂化生色团的跃迁能量越低, 其二阶非线性光学响应就越大。络合Rh的生色团与Nb杂化生色团类似, 电荷转移跃迁范围都比较小, 同时由于Rh与羧基结合时几乎垂直羧基平面, 电荷同时沿X, Y方向转移跃迁, 属于二维电荷转移类型。 相似文献
98.
Baron A Sandford G Slater R Yufit DS Howard JA Vong A 《The Journal of organic chemistry》2005,70(23):9377-9381
[Reaction: see text]. Polyfunctional tetrahydropyrido[2,3-b]pyrazine scaffolds can be synthesized by sequential reaction of pentafluoropyridine with sodium phenylsulfinate and an appropriate diamine. The polyfunctionality possessed by the difluorinated tetrahydropyrido[2,3-b]pyrazine scaffolds was demonstrated in selected model reactions with nucleophiles to give access to various polysubstituted [6,6]-ring fused systems. 相似文献
99.
Hadjar Benmansour Graham Sandford Andrei S. Batsanov 《Journal of fluorine chemistry》2007,128(7):718-722
Palladium catalysed Suzuki cross-coupling reactions between 2,4,6-tribromo-3,5-difluoropyridine and a short series of aromatic boronic acid derivatives gave 4-bromo-3,5-difluoro-2,6-diphenylpyridine derivatives arising from displacement of bromine atoms attached to positions ortho to ring nitrogen or the corresponding triaryl systems depending on the reaction conditions. Consequently, the use of polybromofluoropyridine scaffolds for the synthesis of polyfunctional heteroaromatic derivatives is expanded further. 相似文献
100.
Tianhua Tang Christopher Sandford Shelley D. Minteer Matthew S. Sigman 《Chemical science》2021,12(13):4771
Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. Despite the benefits brought by redox catalysis, establishing the precise nature of substrate activation remains challenging. Herein, we determine that a Co(i) complex bearing two N,N,N-tridentate ligands acts as a competent redox catalyst for the reduction of benzyl bromide substrates. Kinetic studies combining electroanalytical techniques with multivariable linear-regression analysis were conducted, disclosing an outer-sphere electron-transfer mechanism, which occurs in concert with C–Br bond cleavage. Furthermore, we apply a pattern recognition platform to distinguish between mechanisms in the activation of benzyl bromides, found to be dependent on the ligation state of the cobalt(i) center and ligand used.Through kinetic studies combining electroanalytical techniques with multivariable linear-regression (MLR) analysis, a pattern recognition platform is established to determine the electron-transfer mechanism (inner-sphere or outer-sphere) of an electrochemical reduction of benzyl bromides, mediated by different cobalt complexes. 相似文献