Noncovalent assembly of ferrocene on modified gold surfaces mediated by uracil–adenine base pairs

Redox-active ferrocene was assembled on gold surfaces through the hydrogen bonding interactions between adenine-substituted ferrocene and a uracil-terminated organothiol monolayer. The surface coverage of ferrocene Γ could be varied from ca. 4 × 10^? 11 to 2.0 × 10^? 10 mol cm^? 2 by diluting the thiol-modified uracil derivative with inert 1-octanethiol. A decrease in the apparent electron transfer rate constant for ferrocene, k_app, from ca. 50 to 10 s^? 1 was observed upon increasing Γ.     

Characterization of a sucrose/starch matrix through positron annihilation lifetime spectroscopy: unravelling the decomposition and glass transition processes

The triplet state of positronium, o-Ps, is used as a probe to characterize a starch-20% w/w sucrose matrix as a function of temperature (T). A two-step decomposition (of sucrose, and then starch) starts at 440 K as shown by a decrease in the o-Ps intensity (I(3)) and lifetime (τ(3)), the latter also disclosing the occurrence of a glass transition. Upon sucrose decomposition, the matrix acquires properties (reduced size and density of nanoholes) that are different from those of pure starch. A model is successfully established, describing the variations of both I(3) and τ(3) with T and yields a glass transition temperature, T(g) = (446 ± 2) K, in spite of the concomitant sucrose decomposition. Unexpectedly, the starch volume fraction (as probed through thermal gravimetry) decreases with T at a higher rate than the free volume fraction (as probed through PALS).     

Arylbenzo[<Emphasis Type="Italic">h</Emphasis>][1, 6]naphthyridine Derivatives: Synthesis and Photophysical Properties

Suzuki-Miyaura cross coupling was successfully used for C5-arylation in 4-amino-2-chloroquinoline-3-carbaldehyde using arylbornic acid and tetrakistriphenylphosphine palladium catalyst in water. Friedländer condensation reaction on 4-amino-2-chloro/2-arylquinoline-3-carbaldehyde and aromatic ketones gave novel aryl and diarylbenzo[h] [1, 6]naphthyridines in good yields. Fluorescence quantum yields were increased by introducing C2 and C5 π donor aryl benzo[h][1, 6]naphthyridines derivatives.

Open image in new window

Figure Synthesis of Fluorescent Arylbenzo[h][1, 6]naphthyridine

     

Superconductivity in Supersymmetric Theory in Restricted Chromodynamics

The study of superconductivity, dual superconductivity and color superconductivity has been undertaken through the breaking of super symmetric gauge theory in restricted chromo dynamics (RCD) which automatically incorporates the condensation of monopoles and dyons leading to confining and superconducting phases. Dyonic supermultiplets in N=1 super symmetry have been obtained quantum mechanically in RCD and it has been shown that dyon appears in RCD theory only through restricted part of the generalized potential and it is only this part of this potential which is responsible for quark confinement and the resulting superconductivity through the mechanism of dyonic condensation.     

Optimal credit period and lot size for deteriorating items with expiration dates under two-level trade credit financing

In a supplier-retailer-buyer supply chain, the supplier frequently offers the retailer a trade credit of S periods, and the retailer in turn provides a trade credit of R periods to her/his buyer to stimulate sales and reduce inventory. From the seller’s perspective, granting trade credit increases sales and revenue but also increases opportunity cost (i.e., the capital opportunity loss during credit period) and default risk (i.e., the percentage that the buyer will not be able to pay off her/his debt obligations). Hence, how to determine credit period is increasingly recognized as an important strategy to increase seller’s profitability. Also, many products such as fruits, vegetables, high-tech products, pharmaceuticals, and volatile liquids not only deteriorate continuously due to evaporation, obsolescence and spoilage but also have their expiration dates. However, only a few researchers take the expiration date of a deteriorating item into consideration. This paper proposes an economic order quantity model for the retailer where: (a) the supplier provides an up-stream trade credit and the retailer also offers a down-stream trade credit, (b) the retailer’s down-stream trade credit to the buyer not only increases sales and revenue but also opportunity cost and default risk, and (c) deteriorating items not only deteriorate continuously but also have their expiration dates. We then show that the retailer’s optimal credit period and cycle time not only exist but also are unique. Furthermore, we discuss several special cases including for non-deteriorating items. Finally, we run some numerical examples to illustrate the problem and provide managerial insights.     

A comprehensive note on: An inventory model under two levels of trade credit and limited storage space derived without derivatives

In 2006, Huang proposed an inventory model with two warehouses when the supplier offers the retailer a permissible delay of M periods, and the retailer also provides its customers a permissible delay of N periods. He then solved it without derivatives. In this note, we extend his model to complement the shortcomings of his model. In contrast to the complicated and tedious quadratic–algebraic method suggested by Huang, we propose a simple arithmetic–geometric method to solve the inventory problem. Finally, we run computer programs for several numerical examples to illustrate the proposed model and obtain some managerial implications.