全文获取类型
收费全文 | 203866篇 |
免费 | 1962篇 |
国内免费 | 591篇 |
专业分类
化学 | 102316篇 |
晶体学 | 3340篇 |
力学 | 9287篇 |
综合类 | 5篇 |
数学 | 22471篇 |
物理学 | 69000篇 |
出版年
2021年 | 1656篇 |
2020年 | 1798篇 |
2019年 | 2000篇 |
2018年 | 2699篇 |
2017年 | 2601篇 |
2016年 | 3765篇 |
2015年 | 2305篇 |
2014年 | 3613篇 |
2013年 | 9084篇 |
2012年 | 7240篇 |
2011年 | 8733篇 |
2010年 | 6040篇 |
2009年 | 5908篇 |
2008年 | 7913篇 |
2007年 | 8082篇 |
2006年 | 7722篇 |
2005年 | 6892篇 |
2004年 | 6424篇 |
2003年 | 5650篇 |
2002年 | 5491篇 |
2001年 | 6424篇 |
2000年 | 4931篇 |
1999年 | 3794篇 |
1998年 | 3038篇 |
1997年 | 3045篇 |
1996年 | 2791篇 |
1995年 | 2613篇 |
1994年 | 2462篇 |
1993年 | 2337篇 |
1992年 | 2691篇 |
1991年 | 2671篇 |
1990年 | 2600篇 |
1989年 | 2396篇 |
1988年 | 2449篇 |
1987年 | 2448篇 |
1986年 | 2279篇 |
1985年 | 2960篇 |
1984年 | 3215篇 |
1983年 | 2631篇 |
1982年 | 2801篇 |
1981年 | 2771篇 |
1980年 | 2637篇 |
1979年 | 2727篇 |
1978年 | 2821篇 |
1977年 | 2819篇 |
1976年 | 2886篇 |
1975年 | 2670篇 |
1974年 | 2644篇 |
1973年 | 2776篇 |
1972年 | 1763篇 |
排序方式: 共有10000条查询结果,搜索用时 140 毫秒
791.
Al2O3 incorporated HfO2 films grown by atomic layer deposition (ALD) were investigated by high-resolution X-ray photoelectron spectroscopy (HRXPS). The core level energy state of a 15 Å thick film showed a shift to higher binding energy, as the result of a silicate formation and Al2O3 incorporation. The incorporation of Al2O3 into the HfO2 film had no effect on silicate formation at the interface between the film and Si, while the ionic bonding characteristics and hybridization effects were enhanced compared to a pure HfO2 film. The dissociation of the film in an ultrahigh vacuum (UHV) is effectively suppressed compared to a pure HfO2 film, indicating an enhanced thermal stability of Hf-Al-O. Any dissociated Al2O3 on the film surface was completely removed into the vacuum by vacuum annealing treatment over 850 °C, while HfO2 contributed to Hf silicide formation on the film surface. 相似文献
792.
R W Milne R L Nation G D Reynolds A A Somogyi J T Van Crugten 《Journal of chromatography. A》1991,565(1-2):457-464
Improvements to previously reported methods for the determination of morphine, morphine-3-glucuronide (M3G) and morphine-6-glucuronide (M6G) in human plasma are described. The improved methods involve the use of a solid-phase extraction cartridge and a chromatographic system which uses paired-ion reversed-phase high-performance liquid chromatography with a radially compressed column. Only one cartridge is used to prepare each sample for chromatography and each cartridge may be used for at least fourteen 1-ml plasma samples. The recovery is greater than 85%. The improvements to the method of sample pretreatment and in the chromatographic conditions have allowed determination of morphine, M3G and M6G in human plasma down to 13.3 nmol/l (coefficient of variation = 9.3%), 108 nmol/l (6.6%) and 41 nmol/l (6.7%), respectively, using ultraviolet detection alone. It was shown that all three compounds were stable in plasma for up to 101 weeks when stored at -20 degrees C. 相似文献
793.
794.
795.
E. D. Aluker A. G. Krechetov A. Yu. Mitrofanov A. S. Pashpekin 《Russian Journal of Physical Chemistry B, Focus on Physics》2007,1(6):570-572
A new method for studying the kinetics of the expansion of explosion products based on measuring the time elapsed from explosion initiation to the short-circuiting of the discharge gap by the products was proposed. It was revealed that, at the initial stage of expansion of the silver azide explosion products, they move with uniform acceleration, a behavior suggestive that, during this period, the exothermic reaction 2N3 → 3N2 occurs. 相似文献
796.
797.
D. A. Davydov S. Z. Nazarova A. A. Valeeva A. A. Rempel 《Bulletin of the Russian Academy of Sciences: Physics》2007,71(5):677-680
The order-disorder phase transition in vanadium monoxide of substoichiometric compositions VOy has been studied for the first time in situ by the Faraday method with a pendulum magnetic balance of the Domenically type. A minimum is found on the temperature dependence of the magnetic susceptibility of vanadium monoxide of different compositions at a temperature of about 700 K. X-ray diffraction analysis performed before and after measuring the magnetic susceptibility confirmed the change in the structure of vanadium monoxide and the possibility of atom-vacancy processes upon cooling and heating of the samples. 相似文献
798.
Márcio D. Lima Mônica J. de Andrade Viera Skákalová Felipe Nobre Carlos P. Bergmann Siegmar Roth 《固体物理学:研究快报》2007,1(4):165-167
A method for the production of transparent carbon nanotube networks (CNTNs) over transparent substrates was developed. In this method, CNTNs were grown directly in the target surface by applying the catalyst in specific zones of the substrate through lithographic techniques. The networks can be also transferred from the original substrate to other surfaces. The newly grown carbon nanotubes have a very high aspect ratio (>50000). Thus far, networks with an optical transmittance of 94% at 550 nm and a surface resistivity of 3.6 kΩ/sq have been produced. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
799.
P. Thomsen-Schmidt K. Hasche G. Ulm K. Herrmann M. Krumrey G. Ade J. Stümpel I. Busch S. Schädlich A. Schindler W. Frank D. Hirsch M. Procop U. Beck 《Applied Physics A: Materials Science & Processing》2004,78(5):645-649
High-accuracy film thickness measurements in the range below 100 nm can be made by various complex methods like spectral ellipsometry (SE), scanning force microscopy (SFM), grazing incidence X-ray reflectometry (GIXR), or X-ray fluorescence analysis (XRF). The measurement results achieved with these methods are based on different interactions between the film and the probe. A key question in nanotechnology is how to achieve consistent results on a level of uncertainty below one nanometre with different techniques.Two different types of thickness standards are realised. Metal film standards for X-ray techniques in the thickness range 10 to 50 nm are calibrated by GIXR with monochromatised synchrotron radiation of 8048 eV. The results obtained at four different facilities show excellent agreement. SiO2 on Si standards for SE and SFM in the thickness range 6 to 1000 nm are calibrated by GIXR with monochromatised synchrotron radiation of 1841 eV and with a metrological SFM. Consistent results within the combined uncertainties are obtained with the two methods. Surfaces and interfaces of both types of standards are additionally investigated by transmission electron microscopy (TEM). PACS 61.10.Kw; 68.55.Jk; 06.20.Fn; 06.60.Mr; 07.79.Lh 相似文献
800.
Manufacturing cell formation using similarity coefficients and a parallel genetic TSP algorithm: Formulation and comparison 总被引:2,自引:0,他引:2
J. BalakrishnanP. D. Jog 《Mathematical and Computer Modelling》1995,21(12):61-73
Many algorithms have been proposed to form manufacturing cells from component routings. However, many of these do not have the capability of solving large problems. We propose a procedure using similarity coefficients and a parallel genetic implementation of a TSP algorithm that is capable of solving large problems of up to 1000 parts and 1000 machines. In addition, we also compare our procedure with many existing procedures using nine well-known problems from the literature.
The results show that the proposed procedure compares well with the existing procedures and should be useful to practitioners and researchers. 相似文献