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91.
Erika Vrkonyi-Schlovicsk Klmn Takcs Istvn Hermecz 《Journal of heterocyclic chemistry》1997,34(3):1065-1066
Diastereomeric timolol tartrates 4 are obtained in a one-pot synthesis from the racemic base 2 and optically active O,O-diacetyl- or O,O-dibenzoyltartaric anhydrides 3 , as only one of the diastereomers precipitates from acetone solution. Acidic hydrolysis as the corresponding 4 leads to timolol in high yield and optical purity. 相似文献
92.
P. I. H. Bastiaens S. G. Mayhew E. M. O'Naulláin A. van Hoek A. J. W. G. Visser 《Journal of fluorescence》1991,1(2):95-103
Both a mode-locked argon-ion laser and synchrotron radiation were used as excitation sources to obtain time-resolved polarized fluorescence of the two FAD cofactors in electron transferring flavoprotein fromMegasphaera elsdenii. Red-edge excited and blue-edge detected fluorescence anisotropy decay curves did not contain a fast relaxation process which was observed upon mainband excitation and detection. This relaxation was assigned to homo-energy transfer between the two FAD cofactors. Failure of energy transfer as observed with edge spectroscopy on this protein excludes restricted reorientational motion of the flavins as a possible mechanism of depolarization. From the global analysis of the fluorescence anisotropy decay surface obtained at multiple excitation and detection wavelengths, the distance between and the relative orientation of the flavins could be estimated. The methodology described has general applicability in other multichromophoric biopolymers and has the potential to acquire accurate geometrical parameters in these systems. 相似文献
93.
Robert Andreu Gerard Lligadas Joan Carles Ronda Marina Galià Virginia Cádiz 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4965-4973
A new oxazolidine derivative was obtained from phenol, 2‐amino‐2‐methylpropane‐1,3‐diol and paraformaldehyde. The reaction of this novel oxazolidine diol with phenylisocyanate lead to a urethane model compound which can be polymerized thermally by oxazolidine ring opening to give a Mannich bridge structure. Linear segmented polyurethanes were prepared by reaction of different ratios of oxazolidine diol and commercial polyethylenglycol (Mw ~ 400) with 4,4′‐methylenbis (cyclohexylisocyanate) (HMDI, 90% isomers mixture). The polyurethanes were thermally characterized and crosslinked by oxazolidine ring opening to obtain materials which showed improved thermal stability. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4965–4973, 2007 相似文献
94.
Brandau C. Bartsch T. Böhm S. Böhme C. Hoffknecht A. Kieslich S. Knopp H. Schippers S. Shi W. Müller A. Grün N. Scheid W. Steih T. Bosch F. Franzke B. Kozhuharov C. Krämer A. Mokler P. H. Nolden F. Steck M. Stöhlker T. Stachura Z. 《Hyperfine Interactions》2003,146(1-4):41-45
Hyperfine Interactions - An overview of measurements of dielectronic recombination (DR) with the heaviest lithiumlike ions is presented. The experiments have been carried out at the heavy ion... 相似文献
95.
To Professor Guillermo Torres on the occasion of his 70th birthday. 相似文献
96.
97.
M A Aguilar-Mendez E San Martin-Martinez J E Morales A Cruz-Orea M R Jaime-Fonseca 《Analytical sciences》2007,23(4):457-461
Water vapor diffusion coefficient (WVDC) and thermal diffusivity (alpha) were determined in gelatin-starch films through photothermal techniques. The effect of different variables in the elaboration of these films, such as starch and glycerol concentrations and pH, were evaluated through the response surface methodology. The results indicated that an increase in the glycerol concentration and pH favored the WVDC of the films. On the other hand, alpha was influenced principally by the starch content and pH of the film-forming solution. The minimum alpha value was 4.5 x 10(-4) cm2/s, which is compared with alpha values reported for commercial synthetic polymers. 相似文献
98.
99.
The classical Voigt functions occur frequently in a wide variety of problems in astrophysical spectroscopy, emission, absorption
and transfer of radiation in heated atmosphere, and plasma dispersion, and indeed also in the theory of neutron reactions.
Here, in the present paper, by applying several known upper bounds for the first-kind Bessel function J
ν
(x) given recently by (for example) Landau, Olenko and Krasikov, sharp bounding inequalities are obtained for the unified multivariable
Voigt function V
μ,ν
(x; y) in terms of the confluent Fox-Wright function 1ψ0 and its incomplete variant 1ψ0. Connections of the unified multivariable Voigt function V
μ,ν
(x; y) with other unifications and generalizations of the classical Voigt function are also briefly pointed out. 相似文献
100.
E. Hernández L. Rodríguez-Marín 《Journal of Optimization Theory and Applications》2007,134(1):119-134
In this paper, we study optimization problems where the objective function and the binding constraints are set-valued maps
and the solutions are defined by means of set-relations among all the images sets (Kuroiwa, D. in Takahashi, W., Tanaka, T.
(eds.) Nonlinear analysis and convex analysis, pp. 221–228, 1999). We introduce a new dual problem, establish some duality theorems and obtain a Lagrangian multiplier rule of nonlinear type
under convexity assumptions. A necessary condition and a sufficient condition for the existence of saddle points are given.
The authors thank the two referees for valuable comments and suggestions on early versions of the paper. The research of the
first author was partially supported by Ministerio de Educación y Ciencia (Spain) Project MTM2006-02629 and by Junta de Castilla
y León (Spain) Project VA027B06. 相似文献