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241.
Ilia A. Guzei Samuel Dagorne Richard F. Jordan 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(2):143-144
The crystal structure of μ-hydroxo-bis{[N-isopropyl-2-(isopropylamino)troponimino-N,N′](methyl)gallium(II)} tetrakis(pentafluorophenyl)borate (troponimine is 2,4,6-cycloheptatrien-1-imine), [Ga2(C14H22N2)2(OH)]B(C6H5)4, is discussed. The two (iPr2-ATI)GaMe (ATI is aminotroponimime) units of the dinuclear cation are linked by a bridging hydroxo group and are both slightly twisted from planarity. 相似文献
242.
Marcelo Samuel Berman 《International Journal of Theoretical Physics》1990,29(6):571-577
We review general relativistic and Brans-Dicke cosmological models of the early universe and for the present phase. Both theories render similar results, in general, as far as Mach's principle is concerned. There is some difference in the stability problem for the inflationary phase, and we point out how to test one theory against the other experimentally. 相似文献
243.
Marcelo Samuel Berman 《International Journal of Theoretical Physics》1990,29(12):1415-1417
A very general flat solution for Brans-Dicke cosmology with a perfect-fluid, Robertson-Walker metric and a perfect gas law of state is examined regarding density perturbations. The model has growing instabilities, but not of exponential character. 相似文献
244.
245.
Jean Thomas Issenhuth Samuel Dagorne Stphane Bellemin-Laponnaz 《Journal of molecular catalysis. A, Chemical》2008,286(1-2):6-10
The paper describes our preliminary studies on the use of PMHS as a functionalizable polymer and hydride source for the kinetic resolution of secondary alcohols via chiral Cu(I)-catalyzed dehydrogenative silylating process. The chiral phosphine that chelates the Cu metal center has little influence on the selectivity factor of the kinetic resolution. The use of a stereogenic silane appears to be a key requirement to reach enantiodifferentiation in such a process. 相似文献
246.
Samuel C. Hooker 《Fresenius' Journal of Analytical Chemistry》1889,28(1):711
Ohne Zusammenfassung 相似文献
247.
Magnesium 总被引:1,自引:0,他引:1
L. La Rosa C. Fr. Miller Samuel G. Lasky Frau L. Walter-Levy 《Analytical and bioanalytical chemistry》1936,104(5-6):228-229
248.
Polycrystalline K2.5Bi2.5Ti4O13 (I) is prepared by solid state reaction of KNO3, Bi2O3, and TiO2 (Al2O3 crucible, 750 °C, 16 h). 相似文献
249.
Ghodrat Mahmoudi Habibar Chowdhury Samuel E. Lofland 《Journal of Coordination Chemistry》2017,70(12):1973-1983
Two coordination polymers, [Mn2(μ-L1)2(μ-N3)2]n (1) and [Mn(μ-HL2)(SCN)2]n (2), were assembled in a single-pot from MnCl2·4H2O, HL1 (2-acetylpyridine isonicotinoylhydrazone) or HL2 (2-acetylpyridine nicotinoylhydrazone) and ancillary ligand sources (NaN3 or NH4NCS). The products were fully characterized, including by single-crystal X-ray diffraction, which revealed a 2-D metal–organic layer in 1 and a 1-D zigzag coordination chain in 2. Both 1 and 2 are constructed from six-coordinate Mn(II) nodes that adopt distorted octahedral (MnN5O) environments; the adjacent nodes are driven by the μ-L1 and μ-N3 linkers in 1 or μ-HL2 linkers in 2 to form different metal–organic networks. Their topological classification was performed, disclosing the hcb and 2C1 topology in 1 and 2, respectively. Different weak non-covalent interactions promote dimensionality extension. Variable-temperature magnetic susceptibility measurements were carried out, revealing weak ferromagnetic and antiferromagnetic interactions in 1 and 2, respectively. 相似文献
250.
A key bottleneck in the profiling of lipids is the multistep derivatization required prior to gas chromatography (GC) analysis. A single in-vial lipid derivatization and analysis may significantly minimize sample loss and improve analytical sensitivity. A cotton fiber-supported poly(glycidylmethacrylate-co-ethylene glycol dimethacrylate) polymer microbrush microreactor loaded with Candida antarctica lipase B was developed for the facile conversion of triacylglycerols into fatty acid ethyl ester derivatives for gas chromatograph–mass spectrometry (GC–MS) analysis. The polymer microbrush microreactor was fabricated in effort to provide efficient, simplified, cost effective, and high-throughput GC–MS determination of triacylglycerols. The polymer microbrush microreactor was used as an in-vial triacylglycerol transesterification platform, with economical sample consumption of less than or equal to 100?µL and significant reduction of reagents. To evaluate the polymer microbrush microreactor performance for lipids, a triolein standard and camelina oil triacylglycerols were quantitatively transformed into ethyl oleate and fatty acid ethyl esters, respectively, following a 3?h reaction time. The lipase-loaded cotton fiber-supported poly(glycidylmethacrylate-co-ethylene glycol dimethacrylate) polymer microbrush microreactors were reusable for up to five times for quantitative transesterification with minimal loss of lipase activity. 相似文献