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11.
E. Samsøe P. M. Petersen S. Andersson-Engels P. E. Andersen 《Applied physics. B, Lasers and optics》2005,80(7):861-864
A frequency-doubled laser diode system for generation of blue–UV light is described. The system is based on an external-cavity high-power laser diode with double feedback from the zeroth and the first orders of a diffraction grating. Light at 405 nm is generated in a single-pass configuration using periodically poled KTiOPO4. We show that the double grating feedback improves the second harmonic conversion efficiency by several orders of magnitude as compared to the freely running laser. The conversion efficiency may be improved further such that higher second-harmonic powers may be generated. 相似文献
12.
13.
L.R. BrownR.L. Sams I. KleinerC. Cottaz L. Sagui 《Journal of Molecular Spectroscopy》2002,215(2):178-203
Over 1000 measured line intensities of phosphine (PH3) are reported for the region 830 to 1310 cm−1, which contains the two lowest fundamentals in Coriolis interaction. These measurements are fitted to 1.5% for ν2 at 992.13 cm−1 and 2.1% for ν4 at 1118.31 cm−1, respectively, using five intensity parameters that include three Herman-Wallis type terms. In addition, some 60 intensities of the 2ν2-ν2 hot band are modeled. The corresponding assignments and line positions of the dyad from previous work [L. Fusina and G. Di Lonardo, J. Mol. Struct.517-518, 67-78 (2000)] are combined with the present intensity study to provide an improved PH3 database for planetary studies. The total integrated intensity for the dyad is 156.(4) cm−2 atm−1 at 296 K. 相似文献
14.
R.S. Disselkamp J.F. Kelly R.L. Sams G.A. Anderson 《Applied physics. B, Lasers and optics》2002,75(2-3):359-366
Optical feedback to the laser source in tunable diode laser spectroscopy (TDLS) is known to create intensity modulation noise
due to elatoning and optical feedback (i.e. multiplicative technical noise) that usually limits spectral signal-to-noise (S/N).
The large technical noise often limits absorption spectroscopy to noise floors 100-fold greater than the Poisson shot noise
limit due to fluctuations in the laser intensity. The high output powers generated from quantum cascade (QC) lasers, along
with their high gain, makes these injection laser systems especially susceptible to technical noise. In this article we discuss
a method of using optimal filtering to reduce technical noise. We have observed S/N enhancements ranging from ∼20% to a factor
of ∼50. The degree to which optimal filtering enhances S/N depends on the similarity between the Fourier components of the
technical noise and those of the signal, with lower S/N enhancements observed for more similar Fourier decompositions of the
signal and technical noise. We also examine the linearity of optimal filtered spectra in both time and intensity. This was
accomplished by creating a synthetic spectrum for the species being studied (CH4, N2O, CO2 and H2O in ambient air) utilizing line positions and linewidths with an assumed Voigt profile from a commercial database (HITRAN).
Agreement better than 0.036% in wavenumber and 1.64% in intensity (up to a 260-fold intensity ratio employed) was observed.
Our results suggest that rapid ex post facto digital optimal filtering can be used to enhance S/N for routine trace gas detection.
Received: 1 April 2002 / Revised version: 7 May 2002 / Published online: 21 August 2002
RID="*"
ID="*"Corresponding author. Fax: +1-509/376-6066, E-mail: robert.disselkamp@pnl.gov 相似文献
15.
The gas-phase high-resolution spectrum is reported for v1 of the linear molecule thioborine (HBS) from 2775 cm?1 to 2720 cm?1. Band centers and rotational constants are given for the 1000-0000 transitions of H11B32S, H10B32S, H11B34S and H10B34S and for the 1110-0110 transitions of H11B32S and H10B32S. A valence force field is determined from measured values of v1, Do (the centrifugal distortion) and q (the l-doubling constant). The remaining unobserved vibrational fundamentals are calculated from the force constants. 相似文献
16.
The photophysical properties of osmium(II) bis(2,2':6',2' '-terpyridine) have been recorded over a wide temperature range. An emission band is observed and attributed to radiative decay of the lowest-energy metal-to-ligand, charge-transfer (MLCT) triplet state. This triplet is coupled to two other triplet states that lie at higher energy. The second triplet, believed to be of MLCT character, is reached by crossing a barrier of only 640 cm(-1), but the highest-energy triplet, considered to be of metal-centered (MC) character, is separated from the lowest-energy MLCT triplet by a barrier of 3500 cm(-1). Analysis of the emission spectrum shows that both low- and high-frequency modes are involved in the decay process, while weak emission is seen from the second excited triplet state. The magnitude of the low- and high-frequency modes depends on temperature in fluid solution but not in a KBr disk. Apart from a substantial lowering of the triplet energy, the photophysical properties are relatively insensitive to the presence of an ethynylene substituent at the 4' position of each terpyridine ligand. However, the barrier to reaching the MC triplet is markedly reduced, and the vibrational modes become less sensitive to changes in temperature. 相似文献
17.
18.
Liondas CA; Chrissoulidis DP 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(3):275-287
This paper is intended to clarify a misunderstanding concerningthe source singularity of the electric Green's tensor for aperfectly conducting semi-infinite cone of circular cross-section.Tai's series expansion of the Green's tensor is known to lacka singular term at the source region. Jones has reconstructedthe solution to this problem and has pointed out the differencebetween his result and that of Tai. The aim of our paper isto demonstrate that, although Jones's closed-form solution iscorrect, there is a mistake in his comparison with Tai's seriessolution. We conclude that one of the two additional singularterms that Jones claims as missing from Tai's formula must beomitted. Besides, we compare Jones's closed-form solution withSmyshlyaev's solution to the very same problem. We concludethat the magnetic field expressions given by Jones and Smyshlyaevcoincide, but a singular term is missing from Smyshlyaev's expressionfor the electric field. 相似文献
19.
Goodman TNT; Micchelli CA; Rodriguez G; Seatzu S 《IMA Journal of Numerical Analysis》1998,18(3):331-354
It is shown that, under certain conditions, orthonormalizingthe positive integer shifts of an exponentially decaying functionon the half line by the Gram-Schmidt process leads to a limitingprofile given by orthonormalizing all their integer shifts onthe whole line. These results derive from properties of Choleskyfactorization of bi-infinite and semi-infinite matrices. Anexample is provided by the negative exponential function andconjectures are given, supported by numerical evidence, forthe Gaussian and Lorentz function. 相似文献
20.
J.P. Bouanich A. Predoi-Cross R.L. Sams C.P. Rinsland V. Malathy Devi 《Journal of Molecular Spectroscopy》2005,231(1):85-95
A semiclassical theory based upon the Robert-Bonamy formalism has been developed to explain the experimental measurements of self-broadening, self-induced pressure shift coefficients in the ν1,ν2, 2ν2 bands of H12C14N and the 2ν1 band of H13C14N, as well as the temperature dependences of these parameters with special emphasis on the ν2 band. Our calculations include only electrostatic interactions and neglect the vibrational dependence of the isotropic part of the intermolecular potential, which probably has a weak contribution to the HCN self-shifts for the bands investigated in this study. The agreement between theory and measurements is good in the cases of self-broadening coefficients and their variation with temperature, as well as the self-shift coefficients determined at room temperature. However, the observed temperature dependence of self-shift coefficients in the ν2 band is different from that derived theoretically. 相似文献