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81.
Márcio Arab Murad Rogério Martins Saldanha Da Gama Rubens Sampaio Filho 《Meccanica》1992,27(2):95-104
Non-Darcy flows in saturated porous media with significative boundary and inertia effects are modelled applying the Continuum
Theory of Mixtures approach and simulated by discretization of the governing equations by the finite volume method.
Sommario Flussi di tipo ‘Non-Darcy’ in mezzi porosi saturi, con significativi effetti di bordo ed inerziali, vengono modellati applicando l'approccio della Teoria delle Miscele per il Continuo e simulati mediante discretizzazione delle equazioni governanti con il metodo del volume finito.相似文献
82.
The numerical simulation of complex flows demands efficient algorithms and fast computer platforms. The use of adaptive techniques permits adjusting the discretisation according to the analysis requirements, but creates variable computational loads that are difficult to manage in a parallel/vector program. This paper describes the approach adopted to implement an adaptive finite element incompressible Navier–Stokes solver on the Cray J90 machine. Performance measurements for the simulation of free and forced convection incompressible flows indicate that the techniques employed result in a fast parallel/vector code. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
83.
Luiz Jardelino de Lacerda Neto Andreza Guedes Barbosa Ramos Thiago Sampaio de Freitas Cristina Rodrigues dos Santos Barbosa Drcio Luiz de Sousa Júnior Abolghasem Siyadatpanah Morteza Nejat Polrat Wilairatana Henrique Douglas Melo Coutinho Francisco Assis Bezerra da Cunha 《Molecules (Basel, Switzerland)》2021,26(18)
Products of natural origin remain important in the discovery of new bioactive molecules and are less damaging to the environment. Benzaldehyde is a product of the metabolism of plants, and similarly to oxygenated terpenes, it can have antibacterial activity against Staphylococcus aureus and toxic action against Drosophila melanogaster; we aimed to verify these activities. The broth microdilution tests determined the minimum inhibitory concentration (MIC) of benzaldehyde alone and in association with antibiotics and ethidium bromide (EtBr). Toxicity against Drosophila melanogaster was determined by fumigation tests that measured lethality and damage to the locomotor system. The results indicated that there was an association of norfloxacin and ciprofloxacin with benzaldehyde, from 64 μg/mL to 32 μg/mL of ciprofloxacin in the strain K6028 and from 256 μg/mL to 128 μg/mL of norfloxacin in the strain 1199B; however, the associations were not able to interfere with the functioning of the tested efflux pumps. In addition, benzaldehyde had a toxic effect on flies. Thus, the results proved the ability of benzaldehyde to modulate quinolone antibiotics and its toxic effects on fruit flies, thus enabling further studies in this area. 相似文献
84.
The drill-string dynamics is difficult to predict due to the non-linearities and uncertainties involved in the problem. In this paper a stochastic computational model is proposed to model uncertainties in the bit–rock interaction model. To do so, a new strategy that uses the non-parametric probabilistic approach is developed to take into account model uncertainties in the bit–rock non-linear interaction model. The mean model considers the main forces applied to the column such as the bit–rock interaction, the fluid–structure interaction and the impact forces. The non-linear Timoshenko beam theory is used and the non-linear dynamical equations are discretized by means of the finite element method. 相似文献
85.
Raquel A. Fernandes Maria J. Sampaio Joaquim L. Faria Cludia G. Silva 《Molecules (Basel, Switzerland)》2022,27(4)
Vitamin B3 (nicotinic acid, VB3) was synthesized through the photocatalytic oxidation of 3-pyridinemethanol (3PM) under visible-light-emitting diode (LED) irradiation using metal-free graphitic carbon nitride (GCN) - based materials. A bulk (GCN) material was prepared by a simple thermal treatment using dicyandiamide as the precursor. A post-thermal treatment under static air and nitrogen flow was employed to obtain the GCN-T and GCN-T-N materials, respectively. The conditions adopted during the post-treatment revealed differences in the resulting materials’ morphological, electronic, and optical properties. The post-treated photocatalysts revealed an enhanced efficiency in the oxidation of 3PM into VB3, with the GCN-T-N photocatalyst being the best-performing material. The defective surface, reduced crystallinity, and superior photoabsorption of GCN-T-N account for this material’s improved performance in the production of VB3. Nevertheless, the presence of nitrogen vacancies in the carbon nitride structure and, consequently, the creation of mid-gap states also accounts to its highly oxidative ability. The immobilization of GCN-T-N in sodium alginate hydrogel was revealed as a promising strategy to produce VB3, avoiding the need for the photocatalyst separation step. Concerning the mechanism of synthesis of VB3 through the photocatalytic oxidation of 3PM, it was possible to identify the presence of 3-pyridinecarboxaldehyde (3PC) as the intermediary product. 相似文献
86.
Remor Marcelo Bevilacqua Vilas Boas Marcio Antnio Sampaio Silvio Csar Damatto Sandra Regina Stevaux Jos Cndido dos Reis Ralpho Rinaldo 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):1019-1027
Journal of Radioanalytical and Nuclear Chemistry - The objective was to rebuild the history of sedimentation and accumulation of nutrients rate in the Upper Paraná River floodplain. Two corers... 相似文献
87.
88.
Sampaio RN Gomes WR Araujo DM Machado AE Silva RA Marletta A Borissevitch IE Ito AS Dinelli LR Batista AA Zílio SC Gonçalves PJ Barbosa Neto NM 《The journal of physical chemistry. A》2012,116(1):18-26
The present work employs a set of complementary techniques to investigate the influence of outlying Ru(II) groups on the ground- and excited-state photophysical properties of free-base tetrapyridyl porphyrin (H(2)TPyP). Single pulse and pulse train Z-scan techniques used in association with laser flash photolysis, absorbance and fluorescence spectroscopy, and fluorescence decay measurements, allowed us to conclude that the presence of outlying Ru(II) groups causes significant changes on both electronic structure and vibrational properties of porphyrin. Such modifications take place mainly due to the activation of nonradiative decay channels responsible for the emission quenching, as well as by favoring some vibrational modes in the light absorption process. It is also observed that, differently from what happens when the Ru(II) is placed at the center of the macrocycle, the peripheral groups cause an increase of the intersystem crossing processes, probably due to the structural distortion of the ring that implies a worse spin-orbit coupling, responsible for the intersystem crossing mechanism. 相似文献
89.
Ana Dolores Santiago de Freitas Everardo Valadares de Sá Barretto Sampaio Rômulo Simões Cezar Menezes Holm Tiessen 《Isotopes in environmental and health studies》2013,49(2):210-218
Foliar δ15N values are useful to calculate N2 fixation and N losses from ecosystems. However, a definite pattern among vegetation types is not recognised and few data are available for semi-arid areas. We sampled four sites in the Brazilian caatinga, along a water availability gradient. Sites with lower annual rainfall (700 mm) but more uniform distribution (six months) had δ15N values of 9.4 and 10.1 ‰, among the highest already reported, and significantly greater than those (6.5 and 6.3 ‰) of sites with higher rainfall (800 mm) but less uniform distribution (three months). There were no significant differences at each site among species or between non-fixing legume and non-legume species, in spite of the higher N content of the first group. Therefore, they constitute ideal reference plants in estimations of legume N2 fixation. The higher values could result from higher losses of 15N depleted gases or lower losses of enriched 15N material. 相似文献
90.
Rita Coimbra Marco O. P. Sampaio Rui Santos 《The European Physical Journal C - Particles and Fields》2013,73(5):1-15
We present the first version of a new tool to scan the parameter space of generic scalar potentials, ScannerS (Coimbra et al., ScannerS project., 2013). The main goal of ScannerS is to help distinguish between different patterns of symmetry breaking for each scalar potential. In this work we use it to investigate the possibility of excluding regions of the phase diagram of several versions of a complex singlet extension of the Standard Model, with future LHC results. We find that if another scalar is found, one can exclude a phase with a dark matter candidate in definite regions of the parameter space, while predicting whether a third scalar to be found must be lighter or heavier. The first version of the code is publicly available and contains various generic core routines for tree level vacuum stability analysis, as well as implementations of collider bounds, dark matter constraints, electroweak precision constraints and tree level unitarity. 相似文献