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41.
Krishnan Kumar Elias Saion M. K. Halimah Yap CK Muhd Suhaimi Hamzah 《Journal of Radioanalytical and Nuclear Chemistry》2014,301(3):667-676
A study is carried out on the concentrations of rare earth element (REE) elements present in surface mangrove sediments from 10 locations throughout west coast Malaysia. In carrying out the analysis, the best and most convenient method being the instrumental neutron activation analysis (INAA). Samples were obtained, dried, crushed to powdery form and samples prepared for INAA. All the samples for analysis were weighted approximately 150 mg for short irradiation and 200 mg for long irradiation time. As calibration and quality control procedures, blank samples, standard reference material SL-1 were then irradiated with thermal neutron flux of 4 × 1012 cm?2 s?1 at the MINT TRIGA Mark II research reactor which operated at 750 kW by using a pneumatic transport facility. The REE elements of surface sediment samples in this study are Dy, Sm, Eu,Yb, Lu, Tb, La and Ce. It was found that the level of concentrations of all the REE elements varies in the range (0.35–117.4 mg/kg). The geochemical behavior of REEs in surface sediments and normalized pattern (chondrite and shale) has been studied. The degree of sediments contaminations were computed using an enrichment factor. The results showed that the enrichment factor varied in the range (0.75–6.75). 相似文献
42.
Dr. Samer Gozem Dr. Ekaterina Mirzakulova Dr. Igor Schapiro Dr. Federico Melaccio Prof. Dr. Ksenija D. Glusac Prof. Dr. Massimo Olivucci 《Angewandte Chemie (International ed. in English)》2014,53(37):9870-9875
The photophysics of flavins is highly dependent on their environment. For example, 4a‐hydroxy flavins display weak fluorescence in solution, but exhibit strong fluorescence when bound to a protein. To understand this behavior, we performed temperature‐dependent fluorescent studies on an N(5)‐alkylated 4a‐hydroxy flavin: the putative bacterial luciferase fluorophore. We find an increase in fluorescence quantum yield upon reaching the glass transition temperature of the solvent. We then employ multiconfigurational quantum chemical methods to map the excited‐state deactivation path of the system. The result reveals a shallow but barrierless excited state deactivation path that leads to a conical intersection displaying an orthogonal out‐of‐plane distortion of the terminal pyrimidine ring. The intersection structure readily explains the observed spectroscopic behavior in terms of an excited‐state barrier imposed by the rigid glass cavity. 相似文献
43.
Endothelial cell dysfunction is considered to be one of the major causes of vascular complications in diabetes. Polyphenols are known as potent antioxidants that can contribute to the prevention of diabetes. Corn silk has been reported to contain polyphenols and has been used in folk medicine in China for the treatment of diabetes. The present study aims to investigate the potential protective role of the phenolic-rich fraction of corn silk (PRF) against injuries to vascular endothelial cells under high glucose conditions in vitro and in vivo. The protective effect of PRF from high glucose toxicity was investigated using human umbilical vein endothelial cells (HUVECs). The protective effect of PRF was subsequently evaluated by using in vivo methods in streptozotocin (STZ)-induced diabetic rats. Results showed that the PRF significantly reduced the cytotoxicity of glucose by restoring cell viability in a dose-dependent manner. PRF was also able to prevent the histological changes in the aorta of STZ-induced diabetic rats. Results suggested that PRF might have a beneficial effect on diabetic patients and may help to prevent the development and progression of diabetic complications such as diabetic nephropathy and atherosclerosis. 相似文献
44.
Saker Saloum Samer Abou Shaker M.Nidal Alkafri Asmhan Obaid Rokayya Hussin 《Surface and interface analysis : SIA》2019,51(7):754-762
Plasma-polymerized hexamethyldisiloxane (pp-HMDSO) thin films have been deposited in a radiofrequency (RF) remote plasma-enhanced chemical vapor deposition (PECVD) system, on different types of substrates: silicon wafers, glass, quartz crystals, and chemiresistor structure. The as-grown thin films have been post treated in two types of reactive plasmas produced in SF6 and O2 gases. The effect of this surface modification on different properties of the as-grown pp-HMDSO thin film (chemical structure, elemental composition, surface morphology, film density and thickness, optical bandgap, and electrical resistivity) has been investigated. It is found that SF6 plasma and O2 plasma surface modifications of the as-grown pp-HMDSO thin film induce property changes different from each other. SF6 plasma converted the as-grown pp-HMDSO film to a more porous material and caused a narrowing of its optical band gap of about 33%, while O2 plasma induced a lowering of film electrical resistivity of about two orders of magnitude. 相似文献
45.
Samer El Zant Klaus M. Frahm Katia Jaffrès-Runser Dima L. Shepelyansky 《The European Physical Journal B - Condensed Matter and Complex Systems》2018,91(1):7
We apply the reduced Google matrix method to analyze interactions between 95 terrorist groups and determine their relationships and influence on 64 world countries. This is done on the basis of the Google matrix of the English Wikipedia (2017) composed of 5 416 537 articles which accumulate a great part of global human knowledge. The reduced Google matrix takes into account the direct and hidden links between a selection of 159 nodes (articles) appearing due to all paths of a random surfer moving over the whole network. As a result we obtain the network structure of terrorist groups and their relations with selected countries including hidden indirect links. Using the sensitivity of PageRank to a weight variation of specific links we determine the geopolitical sensitivity and influence of specific terrorist groups on world countries. The world maps of the sensitivity of various countries to influence of specific terrorist groups are obtained. We argue that this approach can find useful application for more extensive and detailed data bases analysis. 相似文献
46.
47.
Samer Al-Ashhab 《Journal of Pure and Applied Algebra》2007,208(2):647-653
Given a complex that is a differential graded vector space, it is known that a single mapping defined on a space of it where the homology is non-trivial extends to a strongly homotopy Lie algebra (on the graded space) when that mapping satisfies two conditions. This strongly homotopy Lie algebra is non-trivial (it is not a Lie algebra); however we show that one can obtain an sh-Lie algebra where the only non-zero mappings defining it are the lower order mappings. This structure applies to a significant class of examples. Moreover in this case the graded space can be replaced by another graded space, with only three non-zero terms, on which the same sh-Lie structure exists. 相似文献
48.
49.
Hairul Hisham Hamzah Nur Hidayah Saleh Bhavik Anil Patel Mohd Muzamir Mahat Saiful Arifin Shafiee Turgut Snmez 《Molecules (Basel, Switzerland)》2021,26(1)
The development of low-cost electrode devices from conductive materials has recently attracted considerable attention as a sustainable means to replace the existing commercially available electrodes. In this study, two different electrode surfaces (surfaces 1 and 2, denoted as S1 and S2) were fabricated from chocolate wrapping aluminum foils. Energy dispersive X-Ray (EDX) and field emission scanning electron microscopy (FESEM) were used to investigate the elemental composition and surface morphology of the prepared electrodes. Meanwhile, cyclic voltammetry (CV), chronoamperometry, electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV) were used to assess the electrical conductivities and the electrochemical activities of the prepared electrodes. It was found that the fabricated electrode strips, particularly the S1 electrode, showed good electrochemical responses and conductivity properties in phosphate buffer (PB) solutions. Interestingly, both of the electrodes can respond to the ruthenium hexamine (Ruhex) redox species. The fundamental results presented from this study indicate that this electrode material can be an inexpensive alternative for the electrode substrate. Overall, our findings indicate that electrodes made from chocolate wrapping materials have promise as electrochemical sensors and can be utilized in various applications. 相似文献
50.
S. P. Low A. Ahmad H. Hamzah M. Y. A. Rahman 《Journal of Solid State Electrochemistry》2011,15(11-12):2611-2618
A nanocomposite polymer electrolyte consisting of 49% poly(methyl methacrylate)-grafted natural rubber (MG49) as a polymer matrix, lithium tetrafluoroborate (LiBF4) as a dopant salt, and titanium dioxide (TiO2) as an inert ceramic filler was prepared by solution casting technique. The ceramic filler, TiO2, was synthesized in situ by a sol?Cgel process. The ionic conductivity was investigated by alternating current impedance spectroscopy. X-ray diffraction (XRD) was used to determine the structure of the electrolyte, and its morphology was examined by scanning electron microscopy (SEM). The highest conductivity, 1.4?×?10?5 S cm?1 was obtained at 30 wt.% of LiBF4 salt addition with 6 wt.% of TiO2 filler content. Ionic conductivity was found to increase with the increase of salt concentration. The optimum value of conductivity was found at 6 wt.% of TiO2. The XRD analysis revealed that the crystalline phase of the polymer host slightly decreased with the addition of salt and filler. The SEM analysis showed that the smoother the surface of the electrolyte, the higher its conductivity. 相似文献