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61.
62.
We explore the effect of the external magnetic and Aharonov–Bohm (AB) flux fields on the energy levels of Dirac particle subjects to mixed scalar and vector anharmonic oscillator field in the two-dimensional (2D) space. We calculate the exact energy eigenvalues and the corresponding un-normalized two-spinor-components wave functions in terms of the chemical potential parameter, magnetic field strength, AB flux field and magnetic quantum number by using the Nikiforov–Uvarov (NU) method. 相似文献
63.
Zaher Barghouthi Sameer Amereih 《International journal of environmental analytical chemistry》2013,93(5):565-577
A simple field method which allows the determination of fluoride in drinking water with a small handheld instrument called Arsenator was developed. Arsenator is a commercially available instrument which was used successfully for reliable determination of arsenic. In the proposed method the functionality of the Arsenator which is based on a photometric measurement of a spot on the reagent paper is expanded to analyse fluoride. A polymeric aluminium complex of 5-(2-carboxyphenylazo)-8-hydroxyquinoline (LH2) has been prepared as a new specific reagent for fluoride. Job's method of continuous variation was adopted for the determination of the composition of the coloured complex, which was further characterized by UV-VIS spectroscopic studies. The molar absorptivity of the complex formation is 8.48?×?103?L?mol?1?cm?1 at 410?nm. The coloured complex reacts with fluoride on an impregnated paper where its colour changes are dependent on the concentration of fluoride in water samples. The change in the colour was measured using the Arsenator. The method allows a reliable determination of fluoride in the range 0.3 to 2.0?mg?L?1. Further spectophotometric determinations of fluoride in drinking water were also studied. The determination is based on the reaction of aluminium complex with fluoride in the examined samples. Beer's law is obeyed in the range 0.3 to 2.0?mg?L?1 of fluoride at 495?nm. Sensitivity, detection limit and quantitation limit of the method were found to be 0.251?±?0.007?µg?1?mL, 0.1?mg?L?1 and 0.3?mg?L?1, respectively. The optimum reaction conditions and other analytical conditions were evaluated. The effect of interfering ions on the determination is described. There is no interference by nitrate or chloride. Sulphate interfered only at high concentrations which are not expected in drinking water. 相似文献
64.
Sameer Chavda 《Tetrahedron letters》2008,49(52):7398-7402
The resolution of a series of active esters (derived from acetyl mandelic acid) using an equimolar combination of quasi-enantiomeric oxazolidin-2-ones is discussed. The levels of diastereoselectivity and the facial selectivity were found to be dependent on the structural nature of the pro-leaving group. 相似文献
65.
Angus S. Mackay Joshua W. C. Maxwell Max J. Bedding Dr. Sameer S. Kulkarni Dr. Stephen A. Byrne Lucas Kambanis Dr. Mihai V. Popescu Prof. Robert S. Paton Assoc. Prof. Lara R. Malins Dr. Anneliese S. Ashhurst Dr. Leo Corcilius Prof. Richard J. Payne 《Angewandte Chemie (International ed. in English)》2023,62(50):e202313037
Mild strategies for the selective modification of peptides and proteins are in demand for applications in therapeutic peptide and protein discovery, and in the study of fundamental biomolecular processes. Herein, we describe the development of an electrochemical selenoetherification (e-SE) platform for the efficient site-selective functionalization of polypeptides. This methodology utilizes the unique reactivity of the 21st amino acid, selenocysteine, to effect formation of valuable bioconjugates through stable selenoether linkages under mild electrochemical conditions. The power of e-SE is highlighted through late-stage C-terminal modification of the FDA-approved cancer drug leuprolide and assembly of a library of anti-HER2 affibody conjugates bearing complex cargoes. Following assembly by e-SE, the utility of functionalized affibodies for in vitro imaging and targeting of HER2 positive breast and lung cancer cell lines is also demonstrated. 相似文献
66.
Kuehner JP Naik SV Kulatilaka WD Chai N Laurendeau NM Lucht RP Scully MO Roy S Patnaik AK Gord JR 《The Journal of chemical physics》2008,128(17):174308
A theory is developed for three-laser electronic-resonance-enhanced (ERE) coherent anti-Stokes Raman scattering (CARS) spectroscopy of nitric oxide (NO). A vibrational Q-branch Raman polarization is excited in the NO molecule by the frequency difference between visible Raman pump and Stokes beams. An ultraviolet probe beam is scattered from the induced Raman polarization to produce an ultraviolet ERE-CARS signal. The frequency of the ultraviolet probe beam is selected to be in electronic resonance with rotational transitions in the A (2)Sigma(+)<--X (2)Pi (1,0) band of NO. This choice results in a resonance between the frequency of the ERE-CARS signal and transitions in the (0,0) band. The theoretical model for ERE-CARS NO spectra has been developed in the perturbative limit. Comparisons to experimental spectra are presented where either the probe laser was scanned with fixed Stokes frequency or the Stokes laser was scanned with fixed probe frequency. At atmospheric pressure and an NO concentration of 100 ppm, good agreement is found between theoretical and experimental spectral peak locations and relative intensities for both types of spectra. Factors relating to saturation in the experiments are discussed, including implications for the theoretical predictions. 相似文献
67.
Talreja S Kenis PJ Zukoski CF 《Langmuir : the ACS journal of surfaces and colloids》2007,23(8):4516-4522
The quality, size, and number of protein crystals grown under conditions of continuous solvent extraction are dependent on the rate of solvent extraction and the initial protein and salt concentration. An increase in the rate of solvent extraction leads to a larger number of crystals. The number of crystals decreases, however, when the experiment is started with an initial protein concentration that is closer to the solubility boundary. Here we develop a kinetic model capable of predicting changes in the number and size of protein crystals as a function of time under continuous evaporation. Moreover, this model successfully predicts the initial condition of drops that will result in gel formation. We test this model with experimental crystal growth data of hen egg white lysozyme for which crystal nucleation and growth rate parameters are known from other studies. The predicted and observed rates of crystal growth are in excellent agreement, which suggests that kinetic constants for nucleation and crystal growth for different proteins can be extracted by applying a kinetic model in combination with observations from a few evaporation-based crystallization experiments. 相似文献
68.
Mahmoud EL-Morshedy Fahad Sameer Alshammari Abhishek Tyagi Iberahim Elbatal Yasser S. Hamed Mohamed S. Eliwa 《Entropy (Basel, Switzerland)》2021,23(4)
In this article, we have proposed a new generalization of the odd Weibull-G family by consolidating two notable families of distributions. We have derived various mathematical properties of the proposed family, including quantile function, skewness, kurtosis, moments, incomplete moments, mean deviation, Bonferroni and Lorenz curves, probability weighted moments, moments of (reversed) residual lifetime, entropy and order statistics. After producing the general class, two of the corresponding parametric statistical models are outlined. The hazard rate function of the sub-models can take a variety of shapes such as increasing, decreasing, unimodal, and Bathtub shaped, for different values of the parameters. Furthermore, the sub-models of the introduced family are also capable of modelling symmetric and skewed data. The parameter estimation of the special models are discussed by numerous methods, namely, the maximum likelihood, simple least squares, weighted least squares, Cramér-von Mises, and Bayesian estimation. Under the Bayesian framework, we have used informative and non-informative priors to obtain Bayes estimates of unknown parameters with the squared error and generalized entropy loss functions. An extensive Monte Carlo simulation is conducted to assess the effectiveness of these estimation techniques. The applicability of two sub-models of the proposed family is illustrated by means of two real data sets. 相似文献
69.
Chemical Synthesis of the 20 kDa Heme Protein Nitrophorin 4 by α‐Ketoacid‐Hydroxylamine (KAHA) Ligation
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Dr. Chunmao He Dr. Sameer S. Kulkarni Dr. Frédéric Thuaud Prof. Dr. Jeffrey W. Bode 《Angewandte Chemie (International ed. in English)》2015,54(44):12996-13001
The chemical synthesis of the 184‐residue ferric heme‐binding protein nitrophorin 4 was accomplished by sequential couplings of five unprotected peptide segments using α‐ketoacid‐hydroxylamine (KAHA) ligation reactions. The fully assembled protein was folded to its native structure and coordinated to the ferric heme b cofactor. The synthetic holoprotein, despite four homoserine residues at the ligation sites, showed identical properties to the wild‐type protein in nitric oxide binding and nitrite dismutase reactivity. This work establishes the KAHA ligation as a valuable and viable approach for the chemical synthesis of proteins up to 20 kDa and demonstrates that it is well‐suited for the preparation of hydrophobic protein targets. 相似文献
70.
Relativistic symmetries with the trigonometric Poeschl-Teller potential plus Coulomb-like tensor interaction
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The Dirac equation is solved to obtain its approximate bound states for a spin-1/2 particle in the presence of trigonometric Poeschl-Teller (tPT) potential including a Coulomb-like tensor interaction with arbitrary spin-orbit quantum number κ using an approximation scheme to substitute the centrifugal terms κ(κ± i 1)r^-2. In view of spin and pseudo-spin (p-spin) symmetries, the relativistic energy eigenvalues and the corresponding two-component wave functions of a particle moving in the field of attractive and repulsive tPT potentials are obtained using the asymptotic iteration method (AIM). We present numerical results in the absence and presence of tensor coupling A and for various values of spin and p-spin constants and quantum numbers n and κ. The non-relativistic limit is also obtained. 相似文献