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61.
M. M. Taqui Khan S. A. Samad M. R. H. Siddiqui H. C. Bajaj G. Ramachandraiah 《Polyhedron》1991,10(23-24)
The interaction of molecular hydrogen with [Rh(PPh3)3]+ (1a) “immobilized” in the interlamellar spaces of montmorillonite resulted in the formation of a monohydrido complex, [RhIIH(PPh3)3] (2a), characterized by electrochemical data of the clay-loaded electrode, IR, EPR and hydrogen absorption studies. Heterogenized homogeneous catalytic hydrogenation of cyclohexene catalysed by 1a was investigated in the temperature range 283–313 K. The order of reaction with respect to cyclohexene and hydrogen concentration is fractional and first order with respect to catalyst concentration. Thermodynamic parameters ΔH0 and ΔS0 corresponding to the formation of the monohydrido species were found to be 18 kcal mol−1 and 61 e.u., respectively. The activation enthalpy, ΔH‡, and entropy, ΔS‡, for the hydrogenation of cyclohexene by the RhII—H complex in clay are more negative by about 2 kcal mol−1 and 7 e.u. compared to Wilkinson's catalyst, RhCl(PPh3)3 (1), in homogeneous solution. 相似文献
62.
An organic‐inorganic composite electrode was prepared by the sol‐gel method. For this purpose the carbon composite electrode (CCE) was modified with copper hexacyanoferrate (CuHCF). The CuHCF‐CCE was prepared by two methods. In one method CCE was prepared in one step and in another method the electrode was prepared in a two‐step process. The electrochemical behavior of the CuHCF modified electrode was studied by cyclic voltammetry; the modified electrode shows a pair of peaks with a surface‐confined characteristic in a 0.1 M phosphate buffer (pH 7) with K+ cation, as a supporting electrolyte. The CuHCF‐CCE showed electrocatalytic activity toward oxidation of Dopamine (DA). The kinetics of the catalytic reaction was investigated by using chronoamperometry. The average value of the rate constant for catalytic reaction and the diffusion coefficient were calculated. At a 0.85 V potential under hydrodynamic conditions (stirred solution), the oxidation current is proportional to the dopamine concentration, and the calibration plot was linear over the concentration range of 5‐85 μM. 相似文献
63.
Lilian Cristina Trevizan Dário Santos Jr. Ricardo Elgul Samad Nilson Dias Vieira Jr. Cassiana Seimi Nomura Lidiane Cristina Nunes Iolanda Aparecida Rufini Francisco José Krug 《Spectrochimica Acta Part B: Atomic Spectroscopy》2008
Laser induced breakdown spectroscopy (LIBS) has become an analytical tool for the direct analysis of a large variety of materials in order to provide qualitative and/or quantitative information. However, there is a lack of information for LIBS analysis of agricultural and environmental samples. In this work a LIBS system has been evaluated for the determination of macronutrients (P, K, Ca, Mg) in pellets of vegetal reference materials. An experimental setup was designed by using a Nd:YAG laser operating at 1064 nm and an Echelle spectrometer with ICCD detector. The plasma temperature was estimated by Boltzmann plots and instrumental parameters such as delay time, lens-to-sample distance and pulse energy were evaluated. Certified reference materials as well as reference materials were used for analytical calibrations of P, K, Ca, and Mg. Most results of the direct analysis of plant samples by LIBS were in reasonable agreement with those obtained by ICP OES after wet acid decomposition. 相似文献
64.
Seyed Mohammad Vahdat Robabeh Baharfar Akbar Heydari Samad Khaksar 《Tetrahedron letters》2008,49(46):6501-6504
A new and highly flexible procedure is described for the synthesis of α-amino- and α-hydroxy phosphonates. In the presence of a catalytic amount of oxalic acid (10 mol %), trimethyl phosphite reacts with aldehydes or imines (generated in situ from an aldehyde and an amine) to yield the corresponding coupled products in good yield. 相似文献
65.
Abbas Shockravi Ali Yousefi Samad Bavili Tabrizi Masoomeh Zakeri Ebrahim Abouzari‐Lotf Hashem Sharghi 《Journal of heterocyclic chemistry》2008,45(2):319-322
Novel macrocyclic di and tetraamide compounds have been synthesized by the reaction of 2‐2′‐sulfoxide‐bis‐(4‐methyl phenoxy) aceticester or aceticacid chloride) (obtained from corresponding bisphenol) with appropriate diamines. Also the results of the presence of base as template are discussed and compared. 相似文献
66.
O. El Samad C. Ardisson M. Hussonnois G. Ardisson 《Journal of Radioanalytical and Nuclear Chemistry》1992,164(3):171-182
233U -decay was reinvestigated using a radiochemically purified source and high efficiency HPGe coaxial detectors; the lowenergy -spectrum was also measured using a LEPS detector. The energy and intensity values of one hundred sixty three -lines were determined, from which forty eight are newly reported with respect to the last study of Canty et al. A revised229Th level scheme was built, using the Ritz combination principle, in which nine levels are newly observed, at 371.3, 381.8, 465.5, 569.2, 584.9, 605.1, 620.8, 656.9 and 749.9 keV. 相似文献
67.
A simple, inexpensive, environmentally friendly and efficient route for the synthesis of bis-indolyl methane derivatives by the reaction of indole or N-methyl indole with aldehydes using pentafluorophenylammonium triflate (PFPAT) as a catalyst is described. PFPAT organocatalyst is air-stable, cost-effective, easy to handle, and easily removed from the reaction mixtures. 相似文献
68.
Bioeffects of magnetic field exposure have been motivated accomplishing various studies. However, no consensus or guideline is available for experimental designs relating exposure conditions as yet. In the present work, in order to analyze and predict the melatonin excretion patterns in the rat exposed to extremely low frequency magnetic fields (ELF-MF), linear discriminate analysis (LDA) and support vector machines (SVMs) were utilized. Subsequently, performances of LDA and SVMs were compared through resubstitution and jackknife tests on a database containing 33 experiments. Predictor variables were more effective parameters including frequency, polarization, exposure duration and strength of magnetic fields. Also, five performance measures including accuracy, sensitivity, specificity, matthew's correlation coefficient (MCC) and normalized percentage better than random (S) were used to evaluate the performance of models. The LDA as a conventional model obtained poor prediction performance. On the other hand, SVMs as a more powerful model, which has not been introduced in predicting melatonin excretion patterns in the rat exposed to ELF-MF, showed 0.38 value of MCC through jackknife test that confirms the higher reliability of the SVMs. 相似文献
69.
A simple and facile synthesis of 14-aryl and alkyl-14H-dibenzo[a,j]xanthenes and 1,8-dioxooctahydroxanthene derivatives has been successfully developed by treatment of β-naphthol or dimedone with aldehydes under mild conditions in the presence of a pentafluorophenyl ammonium triflate(PFPAT) organocatalyst.These catalytic condensation reactions represent green chemical processes and the PFPAT organocatalyst is air-stable,cost-effective,easy to handle,and easily removed from the reaction mixtures. 相似文献
70.
Lilian Cristina Trevizan Dário Santos Jr. Ricardo Elgul Samad Nilson Dias Vieira Jr. Lidiane Cristina Nunes Iolanda Aparecida Rufini Francisco José Krug 《Spectrochimica Acta Part B: Atomic Spectroscopy》2009
Laser induced breakdown spectroscopy (LIBS) has been evaluated for the determination of micronutrients (B, Cu, Fe, Mn and Zn) in pellets of plant materials, using NIST, BCR and GBW biological certified reference materials for analytical calibration. Pellets of approximately 2 mm thick and 15 mm diameter were prepared by transferring 0.5 g of powdered material to a 15 mm die set and applying 8.0 tons cm− 2. An experimental setup was designed by using a Nd:YAG laser operating at 1064 nm (200 mJ per pulse, 10 Hz) and an Echelle spectrometer with ICCD detector. Repeatability precision varied from 4 to 30% from measurements obtained in 10 different positions (8 laser shots per test portion) in the same sample pellet. Limits of detection were appropriate for routine analysis of plant materials and were 2.2 mg kg− 1 B, 3.0 mg kg− 1 Cu, 3.6 mg kg− 1 Fe, 1.8 mg kg− 1 Mn and 1.2 mg kg− 1 Zn. Analysis of different plant samples were carried out by LIBS and results were compared with those obtained by ICP OES after wet acid decomposition. 相似文献