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121.
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Ulrike Paap Vera Seidl Karsten Meyer Florian Maier Hans-Peter Steinrück 《Molecules (Basel, Switzerland)》2022,27(23)
We investigated the surface tension and surface composition of various mixtures of the two ionic liquids (ILs) 1-methyl-3-octyl-imidazolium hexafluorophosphate [C8C1Im][PF6] and 1,3-bis(polyethylene glycol)imidazolium iodide [(mPEG2)2Im]I in the temperature range from 230 to 370 K under ultraclean vacuum conditions. The surface tension was measured using a newly developed apparatus, and the surface composition was determined by angle-resolved X-ray photoelectron spectroscopy (ARXPS). In the pure ILs, the alkyl chains of [C8C1Im][PF6] and the PEG chains of [(mPEG2)2Im]I are enriched at the IL/vacuum interface. In the mixtures, a strong selective surface enrichment of the alkyl chains occurs, which is most pronounced at low [C8C1Im][PF6] contents. For the surface tension, strong deviations from an ideal mixing behaviour take place. By applying a simple approach based on the surface composition of the mixtures as deduced from ARXPS, we are able to predict and reproduce the experimentally measured temperature-dependent surface tension values with astonishingly high accuracy. 相似文献
123.
Tanja Vidaković-Koch Tamara Miličić Luka A. Živković Hoon Seng Chan Ulrike Krewer Menka Petkovska 《Current Opinion in Electrochemistry》2021
The nonlinear frequency response analysis (NFRA) can be seen as an extension of electrochemical impedance spectroscopy. NFRA gives a full and detailed representation of the system response and can establish a connection between model parameters and the experimentally observed phenomena. In this article, different theoretical NFRA approaches and the most recent application examples are discussed. A simple electrochemical example is used to showcase the benefits and disadvantages of analyzing the system response by using different approaches. In addition, it was shown how to extract experimental harmonic values and analyze them. 相似文献
124.
Laura M. Luh Ulrike Scheib Katrin Juenemann Lars Wortmann Michael Brands Philipp M. Cromm 《Angewandte Chemie (International ed. in English)》2020,59(36):15448-15466
Targeted protein degradation (TPD), the ability to control a proteins fate by triggering its degradation in a highly selective and effective manner, has created tremendous excitement in chemical biology and drug discovery within the past decades. The TPD field is spearheaded by small molecule induced protein degradation with molecular glues and proteolysis targeting chimeras (PROTACs) paving the way to expand the druggable space and to create a new paradigm in drug discovery. However, besides the therapeutic angle of TPD a plethora of novel techniques to modulate and control protein levels have been developed. This enables chemical biologists to better understand protein function and to discover and verify new therapeutic targets. This Review gives a comprehensive overview of chemical biology techniques inducing TPD. It explains the strengths and weaknesses of these methods in the context of drug discovery and discusses their future potential from a medicinal chemist's perspective. 相似文献
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Holger Lange María Machón Mikhail Artemyev Ulrike Woggon Christian Thomsen 《固体物理学:研究快报》2007,1(6):274-276
We investigated the influence of an epitaxially grown ZnS shell on the phonon spectra of CdSe nanorods of different sizes. The CdSe related Raman peaks shift with addition of a ZnS shell. The longitudinal optical phonon shifts slightly due to strain and the low‐energy shoulder shifts stronger, which can be explained within a model for surface optical phonons. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Adam Berliner Ulrike Bostelmann Richard A. Brualdi Louis Deaett 《Graphs and Combinatorics》2006,22(2):173-183
Let G=(V,E) be a graph with n vertices and e edges. The sum choice number of G is the smallest integer p such that there exist list sizes (f(v):v ∈ V) whose sum is p for which G has a proper coloring no matter which color lists of size f(v) are assigned to the vertices v. The sum choice number is bounded above by n+e. If the sum choice number of G equals n+e, then G is sum choice greedy. Complete graphs Kn are sum choice greedy as are trees. Based on a simple, but powerful, lemma we show that a graph each of whose blocks is sum
choice greedy is also sum choice greedy. We also determine the sum choice number of K2,n, and we show that every tree on n vertices can be obtained from Kn by consecutively deleting single edges where all intermediate graphs are sc-greedy. 相似文献
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