Effective medium representation and complex modes in 3D periodic metamaterials made of cubic resonators with large permittivity at mid-infrared frequencies

We review some of the techniques that lead to the effective medium representation of a three-dimensional (3D) periodic metamaterial. We consider a 3D lattice of lead telluride cubic resonators at mid-infrared (MIR) frequencies. Each cubic resonator is modeled with both an electric and a magnetic dipole, through a method called the dual dipole approximation. The electric and magnetic polarizabilities of a cubic resonator are computed via full-wave simulations by mapping the resonator's scattered field under electric/magnetic excitation only to the field radiated by an equivalent electric/magnetic dipole. We then analyze the allowed modes in the lattice, with transverse polarization and complex wavenumber, highlighting the attenuation that each mode experiences after one free space wavelength. We observe the presence of two modes with low attenuation constant, dominant in different frequency ranges, able to propagate inside the lattice: this allows the treatment of the metamaterial as a homogeneous material with effective parameters, evaluated by using various techniques. We then show that the metamaterial under analysis allows for the generation of artificial magnetism (i.e., relative effective permeability different than unity, including negative permeability with low losses) at MIR frequencies.     

Ionic electroactive polymer metal composites: Fabricating,modeling, and applications of postsilicon smart devices

Smart systems adapt to the surrounding environments in a number of ways. They are capable to scavenge energy from available sources, sense and elaborate external stimuli and adequately react. Electro Active Polymers are playing a main role in the realization of smart systems for applications if fields such as bio inspired and autonomous robotics, medicine, and aerospace. This paper focus on the possibility to use Ionic Polymer Metal Composites as a class of materials relevant to the realization of post silicon smart systems. The three main aspects of this new technology, i.e., fabrication methods, modeling, and applications are described with emphasis to most recent results. Attention is given to main challenges and shortcomings to be solved for technology, modelling, and control of IPMC based devices that need to be solved before this new technology can be fully exploited in real world applications. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013     

Special issue on “Advances on model-based clustering and classification”

Advances in Data Analysis and Classification -     

Certification of nitrate in spinach powder reference material SPIN-1 by high-precision isotope dilution GC–MS

A high-precision exact-matching quadruple isotope dilution method (ID⁴MS) was employed for the quantitation of nitrate in an air-dried spinach powder Certified Reference Material (CRM). The analyte was extracted in hot water following addition of ¹⁵NO\({}_{3}^{-}\) internal standard. The blend was then treated with sulfamic acid to remove nitrite and with triethyloxonium tetrafluoroborate to promote aqueous conversion of nitrate into volatile EtONO₂. The derivative was analyzed by headspace GC–MS with 3-min elution time. The method performance was validated with a series of tests which demonstrated adequate selectivity and ruggedness. This method supported the development of novel SPIN-1 CRM giving a modest contribution to its uncertainty (u_char = 0.85%). With respect to previous attempts, the SPIN-1 was proven stable, homogeneous (u_hom = 0.44%), and suitable for spinach monitoring under EU regulations. On dried basis, the nitrate content of SPIN-1 was found to be 22.53 ± 0.43 mg/g (U_c = 1.9%, k = 2). The material was also used in an inter-laboratory study where four laboratories employed a total of ten measurement methods.

SPIN-1 Certified Reference Material for nitrate in spinach powder

     

On circular–linear one-factorizations of the complete graph

In Korchmáros et al. (2018)one-factorizations of the complete graph $K_n$ are constructed for $n=q+1$ with any odd prime power $q$ such that either $q\equiv 1(mod4)$ or $q=2^h?1$. The arithmetic restriction $n=q+1$ is due to the fact that the vertices of $K_n$ in the construction are the points of a conic $\Omega$ in the finite plane of order $q$. Here we work on the Euclidean plane and describe an analogous construction where the role of $\Omega$ is taken by a regular $n$-gon. This allows us to remove the above constraints and construct one-factorizations of $K_n$ for every even $n\ge 6$.     

Solution-Based,Anion-Doping of Li4Ti5O12 Nanoflowers for Lithium-Ion Battery Applications

Solution-based, anionic doping represents a convenient strategy with which to improve upon the conductivity of candidate anode materials such as Li₄Ti₅O₁₂ (LTO). As such, novel synthetic hydrothermally-inspired protocols have primarily been devised herein, aimed at the large-scale production of unique halogen-doped, micron-scale, three-dimensional, hierarchical LTO flower-like motifs. Although fluorine (F) doping has been explored, the use of chlorine (Cl) dopants is the primary focus here. Several experimental variables, such as dopant amount, lithium hydroxide concentration, and titanium butoxide purity, were probed and perfected. Furthermore, the Cl doping process did not damage the intrinsic LTO morphology. The analysis, based on interpreting a compilation of SEM, XRD, XPS, and TEM-EDS results, was used to determine an optimized dopant concentration of Cl. Electrochemical tests demonstrated an increased capacity via cycling of 12 % for a Cl-doped sample as compared with pristine LTO. Moreover, the Cl-doped LTO sample described in this study exhibited the highest discharge capacity yet reported at an observed rate of 2C for this material at 143mAh g⁻¹. Overall, these data suggest that the Cl dopant likely enhances not only the ion transport capabilities, but also the overall electrical conductivity of our as-prepared structures. To help explain these favorable findings, theoretical DFT calculations were used to postulate that the electronic conductivity and Li diffusion were likely improved by the presence of increased Ti³⁺ ion concentration coupled with widening of the Li migration channel.