全文获取类型
收费全文 | 122篇 |
免费 | 0篇 |
专业分类
化学 | 84篇 |
力学 | 7篇 |
数学 | 20篇 |
物理学 | 11篇 |
出版年
2023年 | 2篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2015年 | 3篇 |
2014年 | 3篇 |
2013年 | 3篇 |
2012年 | 4篇 |
2011年 | 5篇 |
2010年 | 4篇 |
2009年 | 4篇 |
2008年 | 6篇 |
2007年 | 3篇 |
2006年 | 4篇 |
2005年 | 6篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 3篇 |
2001年 | 5篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1994年 | 3篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1977年 | 4篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1970年 | 2篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1965年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有122条查询结果,搜索用时 15 毫秒
21.
22.
23.
Sheng Yao Chun-Ping Tang Yang Ye Tibor Kurtn Attila Kiss-Szikszai Sndor Antus Gennaro Pescitelli Piero Salvadori Karsten Krohn 《Tetrahedron: Asymmetry》2008,19(17):2007-2014
Nine bis-9,10-dihydrophenanthrene and 9,10-dihydrophenanthrene/(dihydro)stilbene derivatives, including the new phochinenins G-L 1–6, were isolated from the whole plant of Pholidota chinensis. Their structures were elucidated on the basis of extensive spectroscopic investigations (1D, 2D NMR, and HR-EIMS). Owing to the sterically hindered rotation around the biaryl axis, some of these biaryl compounds can exist as a pair of enantiomers, but were isolated as racemates. Computed inversion barriers of selected atropisomeric derivatives suggested that phochinenins K 5, gymconpin C 7, and flavanthrin 9 have stable atropisomers. Their racemates were separated by HPLC on an optically active stationary phase, and were stereochemically characterized on-line by circular dichroism (CD) spectroscopy (LC-CD coupling), in conjunction with quantum-mechanics CD calculations. 相似文献
24.
25.
Salvadori B Capitani G Mellini M Dei L 《Journal of colloid and interface science》2006,298(1):487-490
Calcium sulphate dihydrate nanocrystals of 25-100 nm width have been synthesized in 100% purity and yield by means of a method--the cryo-vacuum process--consisting of rapid freezing of quasi-saturated solutions and subsequent vacuum assisted sublimation of water. Transmission electron microscopy reveals both curled nano-lamellae and smaller, irregular particles; electron diffraction patterns demonstrated that the particles are crystalline. This is a very powerful method for the 'clean' synthesis of moderately and completely water-soluble inorganic materials. 相似文献
26.
Karolína Salvadori Alena Krupkov Lucie ervenkov astn Monika Müllerov Vclav Eigner Tom Strak Petra Cuínov 《Molecules (Basel, Switzerland)》2021,26(18)
The repetition of urea-based binding units within the receptor structure does not only lead to monomer properties multiplication. As confirmed by spectroscopic studies, UV-Vis and 1H-NMR in classical or competitive titration mode, the attachment to a carrier allocates the active moieties to mutual positions predetermining the function of the whole receptor molecule. Bivalent receptors form self-aggregates. Dendritic receptors with low dihydrogen phosphate loadings offer a cooperative complexation mode associated with a positive dendritic effect. In higher dihydrogen phosphate concentrations, the dendritic branches act independently and the binding mode changes to 1:1 anion: complexation site. Despite the anchoring, the dendritic receptors retain the superior efficiency and selectivity of a monomer, paving the way to recyclable receptors, desirable for economic and ecological reasons. 相似文献
27.
By reaction of mercatopropylsilanized silica with quinine in the presence of AIBN as radical initiator, a silica supported alkaloid can be obtained, which is effective in the HPLC resolution of racemic arylalkylcarbinols and binaphtol derivatives. 相似文献
28.
29.
30.
Metal hydride complexes find widespread application in catalysis and their properties are often understood on the basis of the available crystal structures. However, some catalytically relevant metal hydrides are only spontaneously formed in situ, cannot be isolated in large quantities or crystallised and their structure is therefore ill defined. One such example is the paramagnetic Ti(iii)-hydride involved in homogeneous Ziegler–Natta catalysis, formed upon activation of CpTi(iv)Cl3 with modified methylalumoxane (MMAO). In this contribution, through a combined use of electron paramagnetic resonance (EPR), electron-nuclear double resonance (ENDOR) and hyperfine sublevel correlation (HYSCORE) spectroscopies we identify the nature of the ligands, their bonding interaction and the extent of the spin distribution. From the data, an atomistic and electronic model is proposed, which supports the presence of a self-assembled ion pair between a cationic terminal Ti-hydride and an aluminate anion, with a hydrodynamic radius of ca. 16 Å.Catalytically competent titanium-hydrides are reactive and difficult to isolate. We use EPR spectroscopy to define the electronic and geometrical structures as well as dynamics of an open-shell Ti-H active in syndiospecific olefin polymerization. 相似文献