全文获取类型
收费全文 | 149篇 |
免费 | 4篇 |
国内免费 | 2篇 |
专业分类
化学 | 104篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 35篇 |
物理学 | 12篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 10篇 |
2021年 | 12篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 5篇 |
2017年 | 2篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 9篇 |
2013年 | 15篇 |
2012年 | 15篇 |
2011年 | 10篇 |
2010年 | 7篇 |
2009年 | 8篇 |
2008年 | 5篇 |
2007年 | 3篇 |
2006年 | 4篇 |
2004年 | 2篇 |
2003年 | 4篇 |
2002年 | 1篇 |
2000年 | 3篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1988年 | 1篇 |
1982年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有155条查询结果,搜索用时 31 毫秒
111.
Hisham A Rameshkumar KB Sherwani N Al-Saidi S Al-Kindy S 《Natural product communications》2012,7(5):663-666
The essential oil compositions of the rhizomes of Cyperus conglomeratus (Cyperaceae) collected from Oman and the leaves of two Annonaceae plants, Desmos chinensis var. lawii and Cyathocalyx zeylanicus collected from India were studied by GC, GC-MS and 13C NMR spectroscopy. Twenty-six compounds, representing 84.4% of the oil were identified in C. conglomeratus, where eugenol (31.3%), alpha-cyperone (10.5%) and cyperotundone (8.4%) were the major compounds. Twelve compounds, constituting 100%, were identified in D. lawii oil, of which benzyl benzoate (58.7%), beta-caryophyllene (23.2%), limonene (4.9%) and alpha-humulene (4.0%) were the major constituents. Thirty-two compounds, comprising 98.0%, were identified in C. zeylanicus oil, of which beta-caryophyllene (21.6%), alpha-pinene (20.4%) and E-beta-ocimene (11.8%) were the major components. The antibacterial and antifungal activities of the oils were tested against a panel of five bacterial and two fungal strains. The oils showed moderate activity against all the tested microbial strains. The minimum inhibitory concentrations of the oils were also determined. 相似文献
112.
113.
In Ax (Ann. Math. 93(2):252–268, 1971), J. Ax proved a transcendency theorem for certain differential fields of characteristic zero : the differential counterpart of the still open Schanuel conjecture about the exponential function over ${\mathbb{C}}$ (Lang, Introduction to transcendental numbers, 1966). In this article, we derive from Ax’s theorem transcendency results in the context of differential valued exponential fields. In particular, we obtain results for exponential Hardy fields, Logarithmic-Exponential power series fields, and Exponential-Logarithmic power series fields. 相似文献
114.
115.
In this paper, we investigate the essential approximate point spectrum and the essential defect spectrum of a 2 × 2 block
operator matrix on a Banach space. Furthermore, we apply the obtained results to two-group transport operators in the Banach
space L
p
([−a, a] × [−1, 1]) × L
p
([−a, a] × [−1, 1]), a > 0, p ≥ 1. 相似文献
116.
The possibility of using 14 MeV neutron activation for rapid, nondestructive elemental analysis of high Tc superconductors is considered. A method was elaborated and applied for investigating Y–Ba–Cu–O samples with different oxygen content. Derived from the measurements of a typical sample the uncertainty of the elemental concentrations, including oxygen, is not more than 1. 1%. 相似文献
117.
The validity of the Poisson and theP(k) modified Poisson statistical density functions of observing k events in a short time interval t=T/n, proposed previously by others, is investigated experimentally in radioactive decay detection for various measuring times, T. The experiments to measure radioactive decay were performed with 89my (T1/2=16.06 s), using a multichannel analyzer operating in the multiscaling mode. According to the results, Poisson statistics adequately describes the counting experiment for short measuring times (up to T<0.5 T1/2) and its application is recommended. However, analysis of the data demonstrated, with confidence, that for long measurements (T>1 T1/2) Poisson distribution is not valid and the modified Poisson function is preferable. 相似文献
118.
A simple, selective and sensitive luminescence method for the assay of piroxicam (PX) in pharmaceutical formulation is developed. The method is based on the luminescence sensitization of europium (Eu3+) by complexation with PX. The signal for PX–EU is monitored at λex=358 nm and λem=615 nm. Optimum conditions for the formation of the complex in methanol were 0.01 M TRIS buffer and 0.2 mM of Eu3+ which allows the determination of 100–2000 ppb of pX in batch method and 100–1000 ppb with limit of detection (LOD) = 23.0 ppb using sequential injection analysis (SIA). The relative standard deviations of the method range between 2 and 3% indicating excellent reproducibility of the method. The proposed method was successfully applied for he assay of PX in pharmaceutical formulations (Feldene capsules and tablets). Average recoveries of 101.0±0.3 and 98.8±2.7% were obtained for capsules in methanol using batch and sequential injection (SI) methods, respectively. 相似文献
119.
Micellization of monomeric and dimeric (gemini) surfactants in polar nonaqueous-water-mixed solvents
Kabir-ud-Din Umme Salma Siddiqui Sanjeev Kumar Aijaz Ahmad Dar 《Colloid and polymer science》2006,284(7):807-812
Dimeric or gemini surfactants are novel surfactants that are finding a great deal of discussion in the academic and industrial arena. They consist of two hydrophobic chains and two polar head groups covalently linked by a spacer. Data on critical micelle concentration (cmc) and degree of counterion dissociation (α) are reported on bis-cationic C16H33N+(CH3)2–(CH2)s–N+(CH3)2C16H33, 2Br−, referred to as 16-s-16, for spacer lengths s=4, 5, 6 in aqueous and in polar nonaqueous (1-propanol, 2-methoxyethanol or methyl cellosolve, dimethyl sulfoxide, acetonitrile)-water-mixed solvents. The behavior is compared with conventional monomeric surfactant cetyltrimethylammonium bromide (CTAB). Thermodynamic parameters are obtained from the temperature dependence of the cmc values. It is observed that micellization tendency of the surfactants decreases in the presence of polar nonaqueous solvents. However, detailed studies with dimethylsulfoxide (DMSO) show that the geminis nearly outclass the micellization-arresting property of this solvent. Also, within geminis, higher spacer length is found suitable for showing micellization even with high DMSO content (50% v/v). The implications of these results of gemini micellization may be useful in micellar catalysis in polar nonaqueous solvents. 相似文献
120.
Franz-Viktor Kuhlmann Salma Kuhlmann Saharon Shelah 《Proceedings of the American Mathematical Society》1997,125(11):3177-3183
We prove that for no nontrivial ordered abelian group does the ordered power series field admit an exponential, i.e. an isomorphism between its ordered additive group and its ordered multiplicative group of positive elements, but that there is a non-surjective logarithm. For an arbitrary ordered field , no exponential on is compatible, that is, induces an exponential on through the residue map. This is proved by showing that certain functional equations for lexicographic powers of ordered sets are not solvable.