Salt crystallization during evaporation: impact of interfacial properties

Salt damage in stone results in part from crystallization of salts during drying. We study the evaporation of aqueous salt solutions and the crystallization growth for sodium sulfate and sodium chloride in model situations: evaporating droplets and evaporation from square capillaries. The results show that the interfacial properties are of key importance for where and how the crystals form. The consequences for the different forms of salt crystallization observed in practice are discussed.     

Repulsive and attractive critical Casimir forces

When confining vacuum fluctuations between two identical walls, the Casimir force manifests itself as a mutual attraction of the walls. When confining concentration fluctuations of a binary liquid mixture, an analogous force should exist near the critical temperature T_C; it is called the critical Casimir force. Here we show experimentally that this purely entropic force can be either attractive or repulsive, depending on the boundary conditions for the fluctuations. For symmetrical boundary conditions an attractive force is found while asymmetrical ones lead to a repulsive force. This is observed directly by confining the fluctuations in a thin wetting film. Depending on the boundary conditions either a thinning or a thickening of the film is observed when T→T_C.     

Positive solution to the nonlinear abstract Hammerstein equation and applications to {\phi} -Laplacian BVPs

We provide in this paper existence results for positive solution to the abstract Hammerstein equation NFu = u where N : E → E is a completely continuous operator, F : C → C is a continuous and bounded map and C is a cone in the Banach space E. The obtained results are used to prove existence results for positive solution to ${\phi}$ -Laplacian boundary value problem.     

Hannay Angles and Grassmannian Action—Angle Quantum States

Theoretical and Mathematical Physics - We show how to derive the Hannay angles of Grassmannian classical mechanics from the evolution of Grassmannian action—angle quantum states. Just as in...     

A New modelling strategy for phase-change heat transfer in turbulent interfacial two-phase flow

The paper presents a modelling strategy for phase-change heat transfer in turbulent interfacial two-phase flow. The computational framework is based on interface tracking ITM (level set approach), combined with large-scale prediction of turbulence, a new methodology known as Large-Eddy & Interface Simulation (LEIS), where super-grid scale turbulence and interfaces are directly solved, whereas the sub-scale parts are modelled. Because steady-state flow conditions are difficult to attain, recourse is made of the Very Large-Eddy Simulation (V-LES) instead of LES, where the flow-dependent cut-off filter is larger and independent from the grid. The computational approach is completed by a DNS-based interfacial phase-change heat transfer model built within the Surface Divergence (SD) theory. The original SD model is found to return better results when modified to account for scale separation, i.e. to segregate low-Re from high-Re number flow portions in the same flow. The model was first validated for an experiment involving a smooth to wavy turbulent, stratified steam-water flow in a 2D channel (Lim et al., 1984, Condensation measurement of horizontal concurrent steam-water flow, ASME J. Heat Transfer 106, 425–432.), revealing that the original SD model performs better for high interfacial shear rates. This screening phase also demonstrated that the most critical issue is the accurate prediction of the interfacial shear using ITM. The model was then applied successfully to predict condensing steam in the event of emergency core cooling in a Pressurized Water Reactor (PWR), where water is injected into the cold leg during a postulated loss-of-coolant-accident. The simulation results agree fairly well with the COSI (short for COndensation at Safety Injections) data (Janicot and Bestion, 1993, Condensation modelling for ECC injection, Nucl. Eng. Des. 145, 37–45).     

A silver nanoparticles-catalyzed efficient three-component synthesis of polysubstituted 4H-chromenylphosphonates and their antioxidant activity

Abstract

A simple and efficient protocol for one-pot three-component synthesis of structurally diverse dialkyl 2-amino-3-cyano-4H-chromen-4-ylphosphonates from the condensation of salicylaldehydes, malononitrile, and trialkyl phosphite using silver nanoparticles as catalyst in ethanol at reflux has been developed. Selected new compounds were evaluated for their antioxidant activity by free radical screening using 2,2-diphenyl-1-picrylhydrazyl (DPPH) method. Among the compounds employed, 5a, 5?b, and 5?h showed promising DPPH radical scavenging activities compared to the experimental standards at low concentration (100?µg/mL) after 24?h incubation.     

Thermal degradation behaviour of a nearly alternating copolymer of vinylidene cyanide with 2,2,2-trifluoroethyl methacrylate

The thermal decomposition under non-oxidative conditions of a copolymer of vinylidene cyanide (VCN) and 2,2,2-trifluoroethyl methacrylate (MATRIF) was investigated by thermogravimetry (TG) and Pyrolysis-GC-MS. The type and composition of the pyrolytic products and the shape of the TG curve indicate that both the main thermal degradation process, with onset at 368 °C, and a minor weight loss at around 222 °C are mainly associated with random main-chain scission. The kinetic parameters were determined by means of dynamic and, in the case of the main degradation stage, also isothermal methods. The results obtained from the dynamic methods (Friedman, Flynn-Wall-Ozawa, and Kissinger, respectively) are in good agreement with those obtained from isothermal TG data. The activation energy was in the 177-213 kJ/mol range for the first stage, and 224-295 kJ/mol for the second stage, the highest respective values being determined from the kinetic analysis according to the Kissinger method.     

Ferromagnetism and ferroelectricity in Eu<Emphasis Type="Italic">X</Emphasis> (<Emphasis Type="Italic">X</Emphasis> = <Emphasis Type="Italic">O</Emphasis>, <Emphasis Type="Italic">S</Emphasis>): pressure effects

Ferromagnetism and ferroelectricity in Eu monochalcogenides have been investigated by ab initio density functional theory in the DFT+U approach. Exchange interaction parameters and Curie temperatures under pressure are studied and discussed using Heisenberg Hamiltonian with first and second-nearest-neighbor interactions. The calculations showed that the hydrostatic pressure perfectly improves the Curie temperature (EuO: T _C = 175 K; EuS: T _C = 33.8 K) and in the other hand it cannot induce the spontaneous polarization (P _s ). The effect of uniaxial and biaxial pressure is also studied. Although the uniaxial strains slightly increases the Curie temperature, it ensures the ferrolectricity in these systems by producing a spontaneous polarization of the order of P _s (EuO) = 57.50 μC/cm² and P _s (EuS) = 42.86 μC/cm² with pressures of 5% and 4%, respectively. The search for new model systems is a necessity to better understand the physics related to multiferroïc materials and to consider possible applications.