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71.
Various cyclopentenones are obtained in fair to high yields when ethylenic acyl bromides are condensed with cyclohexene at low temperature. With less reactive reagents, condensation occurs at 0 °C, leading to β-chloro-ketones. A muscone precursor is obtained in two steps with excellent yields. 相似文献
72.
R. G. Salih und M. Y. Shandala 《Colloid and polymer science》1978,256(6):610
Ohne Zusammenfassung 相似文献
73.
Orhan ?çelli Salih Erzeneo?lu 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,85(2):115-124
Effective atomic numbers of V2O3,VO2,VF3,NH4VO3,VF4,NiF2,NiCl2,NiF24H2O,NiCl26H2O,Ni(ClO4)26H2O were measured in the X-ray energy range 15.746- using an Si(Li) detector. The measured values are compared with the theoretical ones calculated using WinXcom. 相似文献
74.
Orhan ?çelli Salih Erzeneo?lu 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,83(2):229-236
Kβ/Kα intensity ratios of Zn were measured at a photon excitation energy of using a high-resolution Si(Li) detector for several thickness at different pressure. Present results were compared with theoretical data and other experimental values. The results were in good agreement theoretical values based on Hartree-Fock theory. 相似文献
75.
Najeba F. Salih Mohamad S. Jaafar 《Journal of Radioanalytical and Nuclear Chemistry》2014,300(2):693-699
Blood samples were acquired from 60 women aged 20–44 years having decreased fertility, infertile or with uterine tumors in the Iraqi Kurdistan region. The concentrations of α emitters in fresh blood ranged from 0.0029 to 0.0088 ppm, whereas those in powdered blood ranged from 0.0036 ppm in Eiskan to 0.0096 ppm in Halabjay–Kon in Sulaymania. The α emitter concentrations in fresh blood ranged from 0.0029 to 0.0139 ppm, whereas those in powdered blood ranged from 0.0031 ppm in Shorsh to 0.0146 ppm in Sedakan in the Erbil Governorate. However, the concentrations of α emitters in the blood of women with decreased fertility were higher in the North than women from South Iraq. The difference significantly p < 0.001 revealed higher means of track density of fresh and powder blood in Erbil compared to Sulaymania. α are more damaging to the living tissue and exposure of the gonads leads to decreased fertility in women, most of data have been significant therefore, the result shown the radiation effect on women fertility. 相似文献
76.
Wail Al Zoubi Min Jun Kim Abbas Ali Salih Al‐Hamdani Yang Gon Kim Young Gun Ko 《应用有机金属化学》2019,33(11)
Phosphorus‐based Schiff base were synthesized by treating bis{3‐[2‐(4‐amino‐1.5‐dimethyl‐2‐phenyl‐pyrazol‐3‐ylideneamino)ethyl]‐indol‐1‐ylmethyl}‐phosphinic acid with paraformaldehyde and characterized as a novel antioxidant. Its corresponding complexes [(VO)2L(SO4)2], [Ni2LCl4], [Co2LCl4], [Cu2LCl4], [Zn2LCl4], [Cd2LCl4], [Hg2LCl4], [Pd2LCl4], and [PtLCl]Cl2 were analyzed by Fourier transform‐infrared, (1H and 13C) nuclear magnetic resonance, and mass and UV–Vis spectroscopy. Experimental data showed that the ligand coordinated with the metal ions via donor atoms such as nitrogen to form an octahedral arrangement of the Schiff base around the central transition‐metal atom. The nature of these complexes was identified using the molar ratio and Job's methods, with the results agreeing with a metal‐to‐ligand (M:L) molar ratio of 2:1, expect for Pt, whose M:L was 1:1. Thermodynamic activation parameters such as ?E*, ?H*, ?S*, ?G*, and K were determined from the thermogravimetric analysis curve using the Coats–Redfern method. The antioxidant activities of the prepared compounds were assessed by using 1.1‐diphenyl‐2‐picrylhydrazyl as the free radical, and the results show that the complex Schiff bases were found to possess potent antioxidant activity. The structure–activity relationship of the ligand and its complexes indicates that the presence of electron‐donating moieties, such as Co(II) and Ni(II), in the chemical structure increases the antioxidant activity, whereas the Pt(IV) and Pd(II) complexes diminished the antioxidant activity, indicating the superior activity of the hydroxyl radical (OH·) over the superoxide radical. 相似文献
77.
Vladimir V. Egorov Andrei D. Novakovskii Faisal A. Salih Andrei V. Semenov Yauhen B. Akayeu 《Electroanalysis》2020,32(4):674-682
The recently proposed interface equilibria‐triggered dynamic diffusion model of the boundary potential has proven its high predictive efficiency for quantification of the ion exchange and co‐extraction effects at the interface, as well as of the trans‐membrane transfer effect, on the electrode response. It is applicable for both ion exchanger‐based and neutral carrier‐based electrodes. In this communication, the adaptability of this model to more complex cases, when non‐ion‐exchange extraction processes at the interface (partition of organic acids’ and bases’ molecular forms and extraction of ionic associates) are coupled with protolytic equilibria in the aqueous phase and with self‐solvation process in the membrane phase, is demonstrated. By the example of electrodes reversible to ions of highly lipophilic physiologically active bases and acids (amiodarone, verapamil, vinpocetine, salicylic acid), it is shown that the peculiarities of their functioning, such as a very strong pH effect on the potential of cation‐selective electrodes, non‐monotonic pH dependence of the potential and super‐Nernstian response slope in certain pH region for a salicylate‐selective electrode, are well described within the model. 相似文献
78.
Design of novel substituted phthalocyanines; synthesis and fluorescence,DFT, photovoltaic properties
Mehmet Salih AIRTA Derya GÜNG
RDÜ SOLUN Ümit YILDIKO Abdullah
ZKARTAL 《Turkish Journal of Chemistry》2020,44(6):1574
The 4-(2-[3,4-dimethoxyphenoxy] phenoxy) phthalonitrile was synthesized as the starting material of new syntheses. Zinc, copper, and cobalt phthalocyanines were achieved by reaction of starting compound with Zn(CH3COO)2, CuCl2, and CoCl2 metal salts. Basic spectroscopic methods such as nuclear magnetic resonance electronic absorption, mass and infrared spectrometry were used in the structural characterization of the compounds. Absorption, excitation, and emission measurements of the fluorescence zinc phthalocyanine compound were also investigated in THF. Then, structural, energy, and electronic properties for synthesized metallophthalocyanines were determined by quantum chemical calculations, including the DFT method. The bandgap of HOMO and LUMO was determined to be chemically active. Global reactivity (I, A, η, s, μ, χ, ω) and nonlinear properties were studied. In addition, molecular electrostatic potential (MEP) maps were drawn to identify potential reactive regions of metallophthalocyanine (M-Pc) compounds. Photovoltaic performances of phthalocyanine compounds for dye sensitive solar cells were investigated. The solar conversion efficiency of DSSC based on copper, zinc, and cobalt phthalocyanine compounds was 1.69%, 1.35%, and 1.54%, respectively. The compounds have good solubility and show nonlinear optical properties. Zinc phthalocyanine gave fluorescence emission. 相似文献
79.
80.
A metal-insulator crossover appears in the experimental data for in-plane resistivity of underdoped cuprates and a range of
superconducting cuprates in the presence of a strong magnetic field suppressing superconductivity. We propose an explanation
for this phenomenon based on a gauge field theory approach to the t-J model. In this approach, based on a formal spin-charge
separation, the low energy effective action describes gapful spinons (with a theoretically derived doping dependence of the
gap m
s
2
∼ δ| ln δ|) and holons with finite Fermi surface (ɛF ∼ tδ) interacting via a gauge field whose basic effect on the spinons is to bind them into overdamped spin waves, shifting their
gap by a damping term linear in T, which causes the metal-insulator crossover. The presence of a magnetic field perpendicular to the plane acts by increasing
the damping, in turn producing a big positive transverse in-plane magnetoresistance at low T, as experimentally observed. 相似文献