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41.
42.
Ohne ZusammenfassungFür viele wertvolle Hinweise möchte ich an dieser Stelle meinem akademischen Lehrer, Herrn Prof. Dr. W. von Wahl, danken  相似文献   
43.
We experimentally demonstrate the C-band wavelength conversion using four-wave mixing in a 17-mm-long silicon-on-insulator waveguide pumped by a dispersed mode-locked femtosecond laser pulse. The idler can be observed with an incident average pump power lower than 4 dBm, and about 35 nm of conversion bandwidth from 1530nm to 1565nm is measured by using a 1550-nm pump wavelength. The pulse-pumped efficiency is demonstrated to be higher, by more than 22 dB, than the cw-pumped efficiency. The conversion efficiency variations with respect to the pump and signal powers are also investigated.  相似文献   
44.
We analyze the problem of pricing and hedging contingent claims in the multi-period, discrete time, discrete state case using the concept of a “λ gain–loss ratio opportunity”. Pricing results somewhat different from, but reminiscent of, the arbitrage pricing theorems of mathematical finance are obtained. Our analysis provides tighter price bounds on the contingent claim in an incomplete market, which may converge to a unique price for a specific value of a gain–loss preference parameter imposed by the market while the hedging policies may be different for different sides of the same trade. The results are obtained in the simpler framework of stochastic linear programming in a multi-period setting, and have the appealing feature of being very simple to derive and to articulate even for the non-specialist. They also extend to markets with transaction costs.  相似文献   
45.
Acylations of 1,3-dimethyl- ( 1 ) and 1,3,7-trimethylpyrrolo[2,3-d]pyrimidine-2,4-dione ( 2 ) with anhydrides in the presence of trifluoroacetic acid proceed well to give in good yields the corresponding 7-acyl derivatives 3–11 . The 6-trichloroacetyl derivatives 5 and 6 are sensitive towards nucleophiles, which displace the trichloromethyl group easily by formation of the corresponding 6-carboxylic acid derivatives 12–23. The newly synthesized compounds have been characterized by elemental analysis, uv and 1H nmr spectra and pKa, determinations.  相似文献   
46.
The three dimensional structure of Ferric uptake regulation protein dimer from E. coli, determined by molecular modeling, was docked on a DNA fragment (iron box) and Zn2+ ions were added in two steps. The first step involved the binding of one Zn2+ ion to what is known as the zinc site which consists of the residues Cys 92, Cys 95, Asp 137, Asp141, Arg139, Glu 140, His 145 and His 143 with an average metal-Nitrogen distance of 2.5 Å and metal-oxygen distance of 3.1–3.2 Å. The second Zn2+ ion is bound to the iron activating site formed from the residues Ile 50, His 71, Asn 72, Gly 97, Asp 105 and Ala 109. The binding of the second Zn2+ ion strengthened the binding of the first ion as indicated by the shortening of the zinc-residue distances. Fe2+, when added to the complex consisting of 2Zn2+/Fur dimer/DNA, replaced the Zn2+ ion in the zinc site and when a second Fe2+ was added, it replaced the second zinc ion in the iron activating site. The binding of both zinc and iron ions induced a similar change in Fur conformations, but shifted residues closer to DNA in a different manner. This is discussed along with a possible role for the Zn2+ ion in the Fur dimer binding of DNA in its repressor activity. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
47.
ABSTRACT: BACKGROUND: This study was done to obtain concentrated polyunsaturated fatty acid (PUFA) linoleic acid (LA; 18:2) and monounsaturated fatty acid (MUFA) oleic acid (OA; 18:1) from Jatropha curcas seed oil by urea complexation. Urea complexation is a method used by researchers to separate fatty acids (FAs) based on their molecular structure. Effects the ratio of urea-to-FAs, crystallization temperature and crystallization time on the final products of urea complexation were examined. D-optimal Design was employed to study the significance of these factors and the optimum conditions for the technique were predicted and verified. RESULTS: Optimum conditions of the experiment to obtain maximum concentration of LA were predicted at urea-to-FAs ratio (w/w) of 5:1, crystallization temperature of 10 C and 24 h of crystallization time. Under these conditions, the final non-urea complex fraction (NUCF) was predicted to contain 92.81% of LA with the NUCF yield of 7.8%. The highest percentage of OA (56.14%) was observed for samples treated with 3:1 urea-to-FAs ratio (w/w) at 10 C for 16 h. The lowest percentage of LA (8.84%) was incorporated into urea complex fraction (UCF) with 1:1 urea-to-FAs ratio (w/w) at 10 C for 8 h. CONCLUSIONS: The separation of PUFA (LA) and MUFA (OA) described here. Experimental variables should be carefully controlled in order to recover a maximum content of PUFA and MUFA of interest with reasonable yield% with a desirable purity of fatty acid of interest.  相似文献   
48.
The photostabilization of poly(methyl methacrylate) (PMMA) films by Schiff bases of 2,5-dimercapto-1,3,4-thiadiazole compounds was investigated. The PMMA films containing concentration of complexes 0.5% by weight were produced by the casting method from chloroform solvent. The photostabilization activities of these compounds were determined by monitoring the hydroxyl index with irradiation time. The changes in viscosity average molecular weight of PMMA with irradiation time were also tracked (using benzene as a solvent). The quantum yield of the chain scission (Φcs) of these complexes in PMMA films was evaluated and found to range between 4.19 × 10?5 and 8.75 × 10?5. Results obtained showed that the rate of photostabilization of PMMA in the presence of the additive followed the trend:[1] > [2] > [3] > [4] > [5].According to the experimental results obtained, several mechanisms were suggested depending on the structure of the additive. Among them, UV absorption, peroxide decomposer, and radical scavenger for photostabilizer mechanisms were suggested.  相似文献   
49.
The aim of this work is to establish the existence of multi-peak solutions for the following class of quasilinear problems
$$ - \mbox{div} \bigl(\epsilon^{2}\phi\bigl(\epsilon|\nabla u|\bigr)\nabla u \bigr) + V(x)\phi\bigl(\vert u\vert\bigr)u = f(u)\quad\mbox{in } \mathbb{R}^{N}, $$
where \(\epsilon\) is a positive parameter, \(N\geq2\), \(V\), \(f\) are continuous functions satisfying some technical conditions and \(\phi\) is a \(C^{1}\)-function.
  相似文献   
50.
Ncoh/NComp and NKβ/NKα intensity ratios of scattered photons by Zn in the linear region and the infinite mass thickness region are measured as functions of the pressure used for compressing the pellets with a Si(Li) detector using Am-241 and Fe-55 annular source. Besides, the effect on the experimental intensity ratio of relation between two different thicknesses of sample with applied different pressures on the sample is investigated in this study. Harmony between the linear and infinitive (critical) thickness region and the applied pressure on the sample has directly affected the experimental intensity ratios. Experimental results were not compared with various theoretical values in the literature, for present results constitute the first experimental measurements.  相似文献   
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