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31.
Symmetric and nonsymmetric diindolocarbazoles were successfully synthesized for the first time by a Cadogan ring closure using N-alkyl-2,7-disubstituted carbazole precursors. Cyclization reaction on N-alkyl-2,7-di(2'-nitrophenyl) carbazole derivatives is not regioselective and produced a separable mixture of symmetric and nonsymmetric diindolocarbazoles. A carbazole derivative with methyl protective groups at the 1- and 8-positions was therefore used to obtain a symmetric ladder oligo(p-aniline) (compound 22). Optical and electrochemical properties of compound 22 indicate that its neutral semiconducting form is stable in air. This novel class of electroactive ladder oligomers should create new opportunities in micro- and nanoelectronics. 相似文献
32.
A novel podophyllotoxin lignan from Justicia heterocarpa 总被引:2,自引:0,他引:2
Chromatographic separation of the extract of Justicia heterocarpa T. ANDERS. afforded, in addition to known fatty acids, terpenoids and steroids, a new podophyllotoxin lignan. Structures were elucidated by spectroscopic methods, and the structure of the new lignan was confirmed by single crystal X-ray diffraction studies, which have shown that there is a H-bonding stabilized dimer. 相似文献
33.
We study the adiabatic time evolution of quantum resonances over time scales which are small compared to the lifetime of the
resonances. We consider three typical examples of resonances: The first one is that of shape resonances corresponding, for
example, to the state of a quantum-mechanical particle in a potential well whose shape changes over time scales small compared
to the escape time of the particle from the well. Our approach to studying the adiabatic evolution of shape resonances is
based on a precise form of the time-energy uncertainty relation and the usual adiabatic theorem in quantum mechanics. The
second example concerns resonances that appear as isolated complex eigenvalues of spectrally deformed Hamiltonians, such as
those encountered in the N-body Stark effect. Our approach to study such resonances is based on the Balslev-Combes theory
of dilatation-analytic Hamiltonians and an adiabatic theorem for nonnormal generators of time evolution. Our third example
concerns resonances arising from eigenvalues embedded in the continuous spectrum when a perturbation is turned on, such as
those encountered when a small system is coupled to an infinitely extended, dispersive medium. Our approach to this class
of examples is based on an extension of adiabatic theorems without a spectral gap condition. We finally comment on resonance
crossings, which can be studied using the last approach. 相似文献
34.
35.
H. A. H. Salem 《Computational Mathematics and Modeling》2008,19(4):429-436
A fixed point theorem is established to prove the existence of a global solution to some fractional differential equations
involving the Caputo derivatives under a, not necessarily small, growth condition on the nonlinearity. 相似文献
36.
Amorphous silicon carbide (SiC) thin films were deposited on silicon substrates by pulsed laser ablation at room temperature. Thicknesses and surface morphology of the thin films were characterized using optical profilers, atomic force and field emission scanning electron microscopy. Nanohardnes, modulus and scratch resistance properties were determined using XP nanoindenter. The results show that crack free, smooth and nanostructured thin films can be deposited using low laser energy densities. 相似文献
37.
Experimental Techniques - 相似文献
38.
I. Kashif S.M. Salem H. Farouk S.A. Salah 《Journal of Physics and Chemistry of Solids》2006,67(11):2370-2375
The affect of sulphur on the structural properties of iron sodium diborate glasses having the composition {(100−x)Na2B4O7+xFe2O3}+yS, where x=0.05, 0.15 and 0.25 mol% and Y=0, 2.5 and 5 wt% was studied by infrared, Mossbauer spectroscopy and magnetic susceptibility measurements. It was found that, for samples having 5 mol% Fe2O3 and free from sulphur, the iron ions are present in both Fe2+ and Fe3+ states and also 92% of the total iron enters the glass network as a glass former. The ratio of Fe3+/Fe2+ increases with increasing the iron content for sulphur-free samples and others containing sulphur. This ratio also decreases with increasing the sulphur content. The magnetic susceptibility was found to decrease with increasing the sulphur content. Also, the increase of Fe2O3 content led to a less symmetrical environment of Fe3+ ions and vice versa for the Fe2+ environment. 相似文献
39.
40.
Hesham Salem 《Chromatographia》2010,72(3-4):327-330
A simple, selective, sensitive, precise, simultaneous liquid chromatographic analysis of capsules containing thioctic acid, benfotiamine and cyanocobalamin was described. Good chromatographic separation was achieved using a Zorbax C18 (4.6 cm × 250 mm, 5 μm) and a mobile phase consisting of acetonitrile–phosphate buffer pH 3.5 (15:85, v/v) at a flow rate of 0.9 mL min?1. The ultraviolet detector was set a wavelength of 280 nm. Thioctic acid, benfotiamine and cyanocobalamin were eluted at 2.869, 3.752 and 13.689 min, respectively. The linear ranges for thioctic acid, benfotiamine and cyanocobalamin were 30–180, 4–24 and 0.025–0.150 μg mL?1, respectively. The recoveries of thioctic acid, benfotiamine and cyanocobalamine in pharmaceutical preparation were all greater than 98% and their relative standard deviations were less than 2.0%. The limits of detection were 2.57, 0.19 and 0.003 μg mL?1 for thioctic acid, benfotiamine and cyanocobalamin, respectively. 相似文献