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71.
Pawel J. Kulesza Silvia Zamponi Marcin A. Malik Krzysztof Miecznikowski Mario Berrettoni Roberto Marassi 《Journal of Solid State Electrochemistry》1997,1(1):88-93
Using Prussian blue (PB) electrodeposited on gold-covered foil as a model system, we have demonstrated the usefulness of
the time-derivative measurements of absorbance versus potential (linear potential-scan voltabsorptometry) for spectroelectrochemical
characterization of thin electrochromic films. The time-derivative signals were monitored for PB at 680 and 420 nm in potassium,
sodium and lithium electrolytes. Information obtained from cyclic voltabsorptometry is equivalent or complementary to that
from conventional cyclic voltammetry. In the case of PB films investigated in lithium electrolyte, the voltabsorptometric
time-derivative peaks are better defined than the respective voltammetric peaks. The combination of voltabsorptometry with
voltammetry enables molar absorptivity and/or film loading to be determined. Also, concentration changes of differently colored
mixed-valence redox centers can be monitored as a function of applied potential.
Received: 16 January 1997 / Accepted: 11 March 1997 相似文献
72.
73.
Pawel Winter 《BIT Numerical Mathematics》1985,25(3):485-496
The generalized Steiner problem (GSP) is concerned with the determination of a minimum cost subnetwork of a given network where some (not necessarily all) vertices satisfy certain pairwise (vertex or edge) connectivity requirements.The GSP has applications to the design of water and electricity supply networks, communication networks and other large-scale systems where connectivity requirements ensure the communication between the selected vertices when some vertices and/or edges can become inoperational due to scheduled maintenance, error, or overload.The GSP is known to beNP-complete. In this paper we show that if the subnetwork is required to be biconnected or respectively edge-biconnected, and the underlying network is outerplanar, the GSP can be solved in linear time. 相似文献
74.
Pawel Kruszyński 《Reports on Mathematical Physics》1975,7(3):395-401
The problem of linearity of probability measures on hyperfinite factors is studied in Part I. Part II contains the extension of Vital-Hahn-Saks, Egoroff and Lusic theorems for probability measures on von Neumann algebras. These problems have immediate connections with properties of physical states on observable algebras in the sense of Mackey. 相似文献
75.
Pawel M. Idziak 《Algebra Universalis》1988,25(1):365-383
The aim of this paper is to prove that every finitely generated, arithmetical variety of finite type, in which every subdirectly irreducible algebra has linearly ordered congruences has a decidable first order theory of its finite members. The proof is based on a representation of finite algebras from such varieties by some quotients of special subdirect products in which sets of indices are partially ordered into dual trees. Then the result of M. O. Rabin about decidability of the monadic second order theory of two successors is applied.Presented by Stanley Burris. 相似文献
76.
Jan Purczynski Pawel Rolicz Ryszard Sikora 《Applied Physics A: Materials Science & Processing》1975,8(1):71-74
The method of separation of variables has been applied to determine the magnetic field of the system consisting of a thin ellipsoidal coil and a ferromagnetic ellipsoid of revolution. The inductance and the force acting between the coil and the ellipsoid are also examined. 相似文献
77.
Konstantin Mischaikow Marian Mrozek Pawel Pilarczyk 《Foundations of Computational Mathematics》2005,5(2):199-229
We introduce an efficient algorithm to compute the homomorphism
induced in (relative) homology by a continous map.
The algorithm is based on a cubical approximation of the map
and the theory of multivalued maps.
A software implementation of the algorithms introduced in this paper
is available at [27]. 相似文献
78.
Pawel Traczyk 《manuscripta mathematica》1988,61(3):279-284
A negative link is an oriented link that can be represented by a diagram with all the crossings negative. In this paper we prove the following theorem. 相似文献
79.
80.
EPR spectra of Gd3+-doped Ce2(SO4)3.8H2O and La2(SO4)3.9H2O single crystals have been measured with an X-band spectrometer at room and low temperatures. The absolute signs of spin Hamiltonian parameters have been determined for the La2(SO4)3.9H2O host from intensities of lines at liquid helium temperature; for the Ce2(SO4).8H2O host the lines broaden considerably below 60 K, not permitting the determination of absolute signs of spin Hamiltonian parameters. The data are analysed using a rigourous least-squares procedure, fitting simultaneously all lines obtained for several orientations of the external magnetic field. The zero-field splittings have been computed for both the hosts. The characteristics of EPR spectra of Gd3+ in these hosts are compared with those obtained in other rare-earth trisulphate octahydrate hosts. 相似文献