Photooxygenation of alkynylperylenes. Formation of dibenzo[jk,mn]phenanthrene-4,5-diones

3-(1-Alkynyl)perylenes undergo oxygenation when subjected to irradiation with visible light under aerated conditions. The structures of novel oxygenated products formed in this manner are assigned as regioisomeric dibenzo[jk,mn]phenanthrene-4,5-diones.     

Improvement of Cu2ZnSnS4 thin film morphology using Cu–Zn–Sn–O precursor fabricated by sputtering

The new precursor of Cu–Zn–Sn–O (CZTO) was proposed for Cu₂ZnSnS₄ (CZTS) thin film fabrication to improve film morphology. The CZTS thin film grown from Cu–Zn–Sn (CZT) precursors has many bumps. We deposited CZTO precursors on Mo/soda-lime glass (SLG) substrates by RF sputtering using a CZT (Cu:Zn:Sn = 2:1:1) target in Ar and O₂ atmosphere at various O₂ partial pressures (0%, 5%, 17% and 20%). Subsequently, the CZTO precursors were sulfurized in Ar and S atmosphere to fabricate CZTS thin films. The CZTO precursors were amorphous. The morphology of the CZTS thin films was improved by the CZTO precursors. All of the CZTS films fabricated in this study had the same crystal structure. Composition analysis revealed that 50% of O were detected in the CZTO precursor, but O was not detected after sulfurizing process, indicating that O was substituted by S. The CZTS thin film from the CZTO precursor fabricated at O₂ partial pressure of 20% had similar composition for solar cell absorber.     

Zinc halide-promoted cyclization of propargyl amide enynes: novel six-membered ring formation

Highly unusual zinc halide-promoted cyclization of propargyl amide enynes in the presence of an alcohol or a Brønsted acid afforded novel six-membered rings.     

Search for invisible decay of the Upsilon(1S)

We report results of a search for the invisible decay of the Upsilon(1S) via the Upsilon(3S)-->pi+ pi- Upsilon(1S) transition using a data sample of 2.9 fb-1 at the Upsilon(3S) resonance. The data were collected with the Belle detector at the KEKB asymmetric-energy e+ e- collider. No signal is found, and an upper limit for the branching fraction at the 90% confidence level is determined to be B(Upsilon(1S)-->invisible)<2.5 x 10(-3).     

Binary quantum turbulence arising from countersuperflow instability in two-component Bose-Einstein condensates

We theoretically study the development of quantum turbulence from two counter-propagating superfluids of miscible Bose-Einstein condensates by numerically solving the coupled Gross-Pitaevskii equations. When the relative velocity exceeds a critical value, the countersuperflow becomes unstable and quantized vortices are nucleated, which leads to isotropic quantum turbulence consisting of two superflows. It is shown that the binary turbulence can be realized experimentally in a trapped system.     

Improvement of color rendering index of BGYR laser illuminants

Optical Review - Laser-driven phosphor conversion (PC)-type white light sources are receiving a great deal of attention in next-generation high-intensity lighting and display technologies. Laser...     

Spectral simulation for infrared surface electromagnetic wave spectroscopy

Infrared surface electromagnetic wave spectra, which are obtained by the Otto and Kretschmann configurations, are calculated by the Fresnel formula of stratified layers. The calculated reflectivity is plotted as a function of incidence angle, air gap thickness, metal layer thickness, and wavenumbers. From these calculations, optimum experimental variables for both configurations are predicted in the infrared region. At the optimum angle of incidence, the z-component of the electric field intensity was found to be maximum at the surface of silver. The calculated SEW spectra of a PVAc film on silver show a large value of ΔR and a strong frequency dependence. The Otto configuration has advantages in the mid-infrared region.     

Spallative ablation of dielectrics by X-ray laser

A short laser pulse in wide range of wavelengths, from infrared to X-ray, disturbs electron–ion equilibrium and increases pressure in a heated layer. The case where the pulse duration τ _L is shorter than acoustic relaxation time t _s is considered in the paper. It is shown that this short pulse may cause thermomechanical phenomena such as spallative ablation regardless of wavelength. While the physics of electron–ion relaxation strongly depends on wavelength and various electron spectra of substances: there are spectra with an energy gap in semiconductors and dielectrics opposed to gapless continuous spectra in metals. The paper describes entire sequence of thermomechanical processes from expansion, nucleation, foaming, and nanostructuring to spallation with particular attention to spallation by X-ray pulse.