The Au(I)-catalyzed novel conversion of α-acyloxy-α-alkynylsilanes to α-acyloxy-α′-silyl ketones is reported. Ph3PAuOTf in dioxane in the presence of 1 equiv of H2O efficiently catalyzed both the [3,3] sigmatropic rearrangement and allenic transformation of the resulting ester to give the α-acyloxy-α′-silyl ketones in a one-pot procedure. 相似文献
The differential cross sections for the (d, 6Li) reaction on targets of 12C, 16O, 24Mg, 40Ca, 58Ni and 94Mo have been measured at Ed = 54.2 MeV. The measured angular distributions have been analyzed by finite-range DWBA calculations, and spectroscopic factors for an α-cluster transfer have been extracted. In the DWBA analysis using an optical model with a phenomenological Woods-Saxon potential, the spin-orbit part of the deuteron optical potential played a significant role in reproducing the measured angular distributions but the spin-orbit part of the 6Li optical potential had a minor effect. Relative spectroscopic factors extracted from the present data were compared with theoretical predictions together with the results from the (p, pα) reaction. The relative spectroscopic factors for 1p-shell nuclei were in quantitative agreement with theoretical predictions. However, there were certain discrepancies between the spectroscopic factors extracted from the (d, 6Li) reaction and those from the (p, pα) reaction, and the discrepancies increased with target mass number. 相似文献
When poly(vinylidene fluoride) (PVDF) was ground with tetracyanoethylene (TCNE) powder in a vibration glass ball mill in vacuum in the dark at 77 K, the TCNE anion radical (TCNE-) was detected in the mixture by ESR spectroscopy. The TCNE.- is formed by the abstraction of electrons by TCNE from the anion that is produced by a heterogeneous bond scission of carbon-carbon bonds in the polymer main chain. The assignment of TCNE.- was carried out by the ESR spectral simulation on the basis of an anisotropic effective hyperfine tensor that includes a forbidden transition term. At least 85% of the bond scission of the PVDF main chain is induced by a heterogeneous process to produce ionic products. The yield of these mechanions seems to increase with the polarity of carbon-carbon bond owing to a substituent group bonded to the carbon in the polymer main chain. 相似文献
We present recent results on single particle transverse momentum distributions of pions, kaons and protons, measured in CERN Experiment NA44, of 200 AGeV/c S+S and 158 AGeV/c Pb+Pb central collisions. By comparing these data with thermal and transport models, freeze-out parameters like the temperatureTfo and the chemical potentials (μq,μs) are extracted and discussed. 相似文献
Proton-deuteron coincident cross sections in 12C,51V,90Zr(3He,pd) elastic breakup at 90 MeV have been calculated within the framework of the prior-form distorted-wave Born approximation (DWBA). Sufficient convergence of the calculations was obtained by including the pd relative angular momenta up to l = 4. The calculations reproduced the general trend of the coincident energy spectra and the angular correlation data, though deficiencies of the calculations were seen at some angles. The peripheral feature of the (3He, pd) elastic breakup is discussed from the angular momentum dependence of the transition amplitude. 相似文献
Fluorescence (FL) emission properties, microporous structures, energy‐minimized chain conformations, and lamellar layer structures of the silicon‐containing poly(diphenylacetylene) derivative of p‐PTMSDPA before and after desilylation were investigated. The nitrogen‐adsorption isotherms of p‐PTMSDPA film before and after desilylation were typical of type I, indicating microporous structures. The BET surface area and pore volume of the p‐PTMSDPA film were significantly reduced after the desilylation reaction, simultaneously, its FL emission intensity remarkably decreased. The theoretical calculation on both model compounds of p‐PTMSDPA and its desilylated polymer, PDPA, showed a remarkable difference in chain conformation: The side phenyl rings of p‐PTMSDPA are discontinuously arranged in a zig‐zag pattern, while the PDPA is continuously coiled in a helical manner. The lamellar layer distance (LLD) in the p‐PTMSDPA film significantly decreased after the desilylation reaction.
Tensor correlations in 4He were studied via the (p, dp) reaction at the incident energy of 392 MeV with a focus on spin configurations of correlated pn pairs in 4He at high relative momenta ${(P_{\rm rel}^{\rm cor})}$. The preliminary results show that the correlated pn pair at ${P_{\rm rel}^{\rm cor} = 310 {\rm MeV/c}}$ predominantly has the channel spin S = 1, which is consistent with the characteristics of tensor correlations. 相似文献
We are planning to perform an experiment at J-PARC and produce new neutron-rich Λ hypernuclei by using the (π?, K+) reaction (J-PARC E10). As the first step, we are planning to produce ${^6_{\Lambda}{\rm H}}$ hypernuclei with a 6Li target. To conduct this experiment, we are developing new detectors, those are scintillating fiber tracker, and silicon strip detector, for high rate operation to aim at increasing beam intensity up to 107/spill. As a result of beam test in Jun 2012, we are going to use high-rate beam at least 107/spill. 相似文献
Spectroscopy for neutron-rich nuclei 9He and 12Be has been performed by means of heavy-ion double charge exchange (HIDCX) (18O, 18Ne) reaction on stable target nuclei 9Be and 12C, respectively. Several clear peaks in 12Be at low excitation energy region even above neutron separation energy have been observed in one-shot measurement, whereas no prominent signals of 9He have been observed owing to the small cross section. It is shown that the HIDCX reaction is a new powerful spectroscopic tool for study of unstable neutron-rich nuclei. 相似文献