全文获取类型
收费全文 | 429篇 |
免费 | 18篇 |
国内免费 | 1篇 |
专业分类
化学 | 357篇 |
晶体学 | 2篇 |
力学 | 3篇 |
物理学 | 86篇 |
出版年
2022年 | 5篇 |
2020年 | 5篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 12篇 |
2015年 | 8篇 |
2014年 | 9篇 |
2013年 | 17篇 |
2012年 | 12篇 |
2011年 | 12篇 |
2010年 | 6篇 |
2009年 | 9篇 |
2008年 | 20篇 |
2007年 | 18篇 |
2006年 | 22篇 |
2005年 | 22篇 |
2004年 | 38篇 |
2003年 | 29篇 |
2002年 | 28篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 12篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 2篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 4篇 |
1968年 | 2篇 |
1967年 | 2篇 |
1965年 | 3篇 |
排序方式: 共有448条查询结果,搜索用时 0 毫秒
101.
Naoto Aoyagi Yoshio Furusho Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2013,51(5):1230-1242
Hydroiodides of secondary and primary amines effectively catalyzed the reaction of carbon dioxide and epoxides under mild conditions such as ordinary pressure and ambient temperature, to obtain the corresponding five‐membered cyclic carbonates in moderate to high yields. Detailed investigation showed that the catalytic activity was highly affected by the counter anions of the ammonium salts; the iodides catalyzed efficiently the carbonate‐forming reactions, whereas the bromide and chloride counterparts exhibited almost no catalysis. We also revealed that two important factors on the amine moieties that affected the catalytic reactions. First, the catalytic activity increased with increasing bulkiness of the substituents on the ammonium nitrogen atoms. Second, the catalysis became more efficient as the parent amines become more basic. Dicyclohexylammonium iodide was the best catalyst among the ammonium salts investigated in this study. As an application of this reaction system, we synthesized homo‐ and copolymers bearing epoxide pendant groups as substrates, which were converted with high efficiency into the corresponding homo‐ and copolymers bearing cyclic carbonate pendant groups under 1 atm at 45 °C. All polymers were easily purified simply by precipitation in water, and were isolated in high yields (>95%). © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
102.
Nobuyasu Itoh Takamitsu Otake Yoshie Aoyagi Mayumi Matsuo Takashi Yarita 《Chromatographia》2009,70(7-8):1073-1078
We applied liquid chromatography-dopant-assisted atmospheric pressure photoionization-mass spectrometry to quantify four distinct pesticides (isoprothiolane, fenitrothion, fthalide, and ethophenprox) in unpolished rice flour. Although the effect of acetone as a dopant on enhancement of ionization differed among the pesticides, the analytical results by LC-DA-APPI-MS with a dopant flow rate of 50 μL min?1 were not only repeatable (relative SD < 9%, n = 3) but also comparable to those by gas chromatography–mass spectrometry. 相似文献
103.
Saori Ichinose Mayumi Nakamura Mayu Maeda Rie Ikeda Mitsuhiro Wada Mio Nakazato Yoshihito Ohba Noboru Takamura Takahiro Maeda Kiyoshi Aoyagi Kenichiro Nakashima 《Biomedical chromatography : BMC》2009,23(9):935-939
A semi‐micro column HPLC‐fluorescence method for routine determination of thiol derivatives such as homocysteine (Hcy), cysteine (Cys) and cysteamine (CA) is described. The thiol derivatives labeled with ammonium‐7‐fluorobenzo‐2‐oxa‐1,3‐diazole‐4‐sulfonate (SBD‐F) were isocratically separated within 12 min on a semi‐micro ODS column (Daisopak‐SP‐120‐5‐ODS‐BP) with a mixture of 25 mm acetate buffer (pH 2.00) and CH3CN as a mobile phase. The purity and similarity of SBD‐thiols by a multi‐wavelength fluorescence detector were more than 92.3 and 96.7%. The detection limits of Hcy, Cys and CA at a signal‐to‐noise ratio of 3 were 0.16, 0.47 and 0.03 µm , respectively. Furthermore validation parameters such as accuracy, precision and robustness of the proposed method showed satisfactory results. Almost 850 plasma sample injections (range 572–1076, n = 3) for a column could be performed without differences in retention time and peak heights of labels. As an application of the proposed method, the determination of thiol derivatives in normal human plasma (n = 103) was demonstrated. The correlation coefficients between Hcy vs Cys and Hcy vs CA were 0.38 and −0.35, respectively. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
104.
This study intends to determine the rational criteria (e.g., threshold value) for applying the weight variation test and to investigate the adequacy of the acceptance value for existing commercial products in Japan. The studied products were 489 lots (3 lots x 163 products) of compressed tablets (plain, film-coated, sugar-coated) and 42 lots (3 lots x 14 products) of hard capsules marketed in Japan. The individual drug content and the weight of 10 units in a lot were determined for each product and the acceptance values were calculated according to the Japanese Pharmacopoeia thirteenth edition (JP13) Content Uniformity Test (M=100.0, k=2.2). Product-specific intra-lot relative standard deviation of content (RSDD), weight (RSDW) and concentration (RSDC) were calculated by analysis of variance (ANOVA) using three lots of data per product. The RSDD and RSDC tended to increase with the decrease of the label strength for plain tablets, but not for film-coated and sugar-coated tablets, and hard capsules. A good correlation was found between RSDD and RSDC but not between RSDD and RSDW. These findings indicate that 1) it is difficult to rationally set the threshold level for weight variation, especially regarding the dosage forms except for plain tablets, 2) the application of weight variation tests should, in principle, be decided on the mixing homogeneity that is RSDC. 3) Most (99.6%) of the tablets and all the capsules investigated met the requirement of content uniformity test of JP13. Therefore the criteria of the JP13 content uniformity test are considered acceptable from the viewpoint of manufacturing capability. 相似文献
105.
106.
107.
108.
Kazuhira Miwa Shinobu Aoyagi Takahiro Sasamori Shogo Morisako Hiroshi Ueno Yutaka Matsuo Hideki Yorimitsu 《Molecules (Basel, Switzerland)》2022,27(2)
The reduction of fullerene (C60) with sodium dispersion in the presence of an excess amount of dipropyl sulfate was found to yield highly propylated fullerene, C60(nC3H7)n (max. n = 24), and C60(nC3H7)20 was predominantly generated as determined by mass spectroscopy. 相似文献
109.
Palladium-catalyzed oxidative alkynylation of alkenes using tert-propargylic alcohols as alkynylation reagents via C-C bond cleavage under an oxygen atmosphere affords the corresponding ene-yne compounds. 相似文献
110.
Joachim Mohn Christina Biasi Samuel Bodé Pascal Boeckx Paul J. Brewer Sarah Eggleston Heike Geilmann Myriam Guillevic Jan Kaiser Kristýna Kantnerová Heiko Moossen Joanna Müller Mayuko Nakagawa Ruth Pearce Isabell von Rein David Steger Sakae Toyoda Wolfgang Wanek Sarah K. Wexler Naohiro Yoshida Longfei Yu 《Rapid communications in mass spectrometry : RCM》2022,36(13):e9296