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11.
Transition Metal Chemistry - A facile synthetic approach has been adopted towards the synthesis of (2R,3R)-N2,N3-bis((S)-1-phenylethyl)butane-2,3-diamine via demetalation of its dichloro Zn(II)... 相似文献
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Muhammad Omer Iqbal Muhammad Masood Ahmed Shafia Arshad Usman Javaid Imran Ahmad Khan Majid Manzoor Shumaila Andleeb Romana Riaz Shaukat Hussain Munawar Zahid Manzoor Asma Mumtaz 《Molecules (Basel, Switzerland)》2022,27(3)
Alhagi camelorum (AC) is an old plant with a significant therapeutic value throughout Africa, Asia, and Latin America. The overuse of cisplatin (Cis > 50 mg/m2) is associated with observed nephrotoxicity, ototoxicity, gastrotoxicity, myelosuppression, and allergic reactions. Remedial measures are needed for the protection of nephrotoxicity against cisplatin. Thus, we investigated the nephroprotective effects of AC plant extract to prevent cisplatin-induced nephrotoxicity in albino Wistar rats. The presence of polyphenols, phenolic compounds, tannins, and saponins was revealed during phytochemical investigation, and a significantly intense antioxidant activity was recorded. There were no toxicological symptoms in the treated rats, and no anatomical, physiological, or histological abnormalities were found compared to the control rats. The results of correcting cisplatin-induced nephrotoxicity revealed that the extract has a significant ability to treat kidney damage, with most parameters returning to normal after only three weeks of therapy. It is concluded that co-administration of cisplatin with AC extract showed exceptional nephroprotective effects at a dose of 600 mg/kg for Cis-induced nephrotoxicity. 相似文献
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M. Riaz 《Optics Communications》2006,263(2):267-274
We present first measurements on the resonance enhanced three-photon excitation in thallium, using a Nd:YAG laser pumped dye laser in conjunction with a thermionic diode ion detector. The even-parity 6s2ns2S1/2 (15 ? n ? 31) and nd 2D5/2 (13 ? n ? 42) Rydberg states have been observed. The measured level energies reveal a dynamic shift from the photoabsorption values, which is decreasing with increasing n, while the asymmetry in the line profile is observed to be increasing with increasing n. In addition, an autoionising level (sp24P3/2) adjacent to the ionization threshold has been observed and quantitatively analyzed using the Fano’s photoionization cross-section relation for an isolated autoionising resonance. 相似文献
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Mehfooz Haroon Saeed Aamer Faisal Muhammad Larik Fayaz Ali Muqadar Urooj Khatoon Saira Channar Pervaiz Ali Ismail Hammad Bilquees Salma Rashid Sajid Shafique Shagufta Mirza Bushra Dilshad Erum Ahmad Fawad 《Research on Chemical Intermediates》2020,46(5):2437-2456
Research on Chemical Intermediates - Meldrum’s acid derivatives were facile synthesized by one-pot condensation process and characterized by NMR (1H, 13C, DEPT-90 and DEPT-135) and EI-MS. The... 相似文献
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Rizwan Ahmad Niyaz Ahmad Muhammad Riaz Maria Al-tarouti Fatimah Aloufi Alaa AlDarwish Bayan Alalaq Badriah Alhanfoush Zahid Khan 《Biomedical chromatography : BMC》2020,34(11):e4942
A range of conventional, i.e. maceration, percolation, ultrasonic assisted, Soxhlet and Soxtec extraction (STE), to advanced extraction techniques of accelerated solvent extraction (ASE) was utilized for the first time in order to optimize the extract yield and recovery of phenolics—gallic acid (GA), rutin (RT) and quercetin (QT)—quantified via ultra-high performance liquid chromatography with diode array detector (UHPLC–DAD). The effect of solvents (n-hexane, dichloromethane and methanol) and temperature (60, 80 and 100°C) upon extraction yield, phenolic content and antioxidant activity (DPPH, ABTS and DPPH) was studied, and the method was validated in commercial food samples from Saudi Arabia, China and India. A high extract yield with percentage recovery was observed for STE (1221.10 mg/5 g; 24.42%) and ASE techniques (91.50 mg/1 g; 9.15%) in methanol at 100°C. UHPLC–DAD showed retention times (min) of 0.67, 1.93 and 1.90 for GA, RT and QT, respectively in the shortest runtime of 3 min. The yield for phenolics was higher for STE/ASE (ppm): 15.27/15.29 (GA), 85.24/37.56 (RT) and 52.20/33.40 (QT), respectively. In terms of antioxidant activities, low IC50 values (μg/ml) of 1.09/1.18 (DPPH), 2.11/5.32 (ABTS) and 4.35/7.88 (phenazine methosulfate–nicotinamide adenine dinucleotide) were observed for STE and ASE, respectively. Multivariate analysis for STE showed a significant (P = 0.000) correlation for extraction type vs. extract yield and phenolics content; however, there was no significance for antioxidant activities vs. extraction type. ASE showed a positive correlation for solvent vs. extraction yield, phenolics and antioxidant activity; however, there was no correlation for extraction yield and DPPH activity. Principal component analysis for STE showed a major variability (52.02%) for extraction yield and phenolics in PC1 followed by PC2 (38.30%) for antioxidant activities. For ASE, PC1 (48.68%) showed a positive correlation for solvent vs. extraction yield and phenolics while PC2 (33.12%) showed a positive correlation for temperature and antioxidant activities. STE and ASE were the optimized extraction techniques for the garlic food sample while a significant effect of solvent and temperature was observed upon extraction yield, phenolics and antioxidant activity. 相似文献
17.
In this article,three-dimensional mixed convection flow over an exponentially stretching sheet is investigated.Energy equation is modelled in the presence of viscous dissipation and variable thermal conductivity.Temperature of the sheet is varying exponentially and is chosen in a form that facilitates the similarity transformations to obtain self-similar equations.Resulting nonlinear ordinary differential equations are solved numerically employing the Runge-Kutta shooting method.In order to check the accuracy of the method,these equations are also solved using bvp4c built-in routine in Matlab.Both solutions are in excellent agreement.The effects of physical parameters on the dimensionless velocity field and temperature are demonstrated through various graphs.The novelty of this analysis is the self-similar solution of the threedimensional boundary layer flow in the presence of mixed convection,viscous dissipation and variable thermal conductivity. 相似文献
18.
H Wajahat A Riaz 《理论物理通讯》2020,72(7):75001-7
We present a matrix coupled dispersionless(CD) system. A Lax pair for the matrix CD system is proposed and Darboux transformation is constructed on the solutions of the matrix CD system and the associated Lax pair. We express an N soliton formula for the solutions of the matrix CD system in terms of quasideterminants. By using properties of the quasideterminants, we obtain some exact solutions, including bright and dark-type solitons, rogue wave and breather solutions of the matrix CD system. Furthermore, it has been shown that the solutions of the matrix CD system are expressed in terms of solutions to the usual CD system, sine-Gordon equation and Maxwell-Bloch system. 相似文献
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Diorganotin(IV) Complexes with Monohydrate Disodium Salt of Iminodiacetic Acid: Synthesis,Characterization, Crystal Structure and Biological Activities 下载免费PDF全文
Shabbir Hussain Saqib Ali Saira Shahzadi Corrado Rizzoli Muhammad Shahid 《中国化学会会志》2015,62(9):793-802
Diorganotin(IV) derivatives have been synthesized by the reaction of R2SnL2 (R=n‐Bu 1 , Ph 2 ) with monohydrate disodium salt of iminodiacetic acid ( Na2L ) in 1 : 1 M/L ratio under reflux conditions. The compounds have been characterized by FT‐IR, NMR (1H and 13C) spectoscopy, electron ionization mass spectrometry (EIMS), thermogravimetric analyses (TGA) and single crystal XRD. FTIR data indicates a mono‐dentate binding mode of the carboxylic acid group as well as participation of the amino nitrogen and aqua oxygen in coordination with organotin(IV) moieties. NMR data demonstrates a tetra‐coordinated environment around tin(IV) in solution. Mass spectrometric and thermogravimetric analyses verify the close similarities between the molecular structures of both complexes. The thermal stability of diphenyltin(IV) derivative ( 2 ) was found slightly higher than that of the free ligand ( Na2L ). Single crystal X‐ray analysis of the complex 1 have shown a hexa‐coordinated geometry around Sn(IV) with trans configuration. There are evidences for the existence of intermolecular hydrogen bonding in the structure of the complexes. The products displayed significant antibacterial and antifungal activities in contrast to the biologically inactive ligand precursor. However, the hemolytic cytoxicity of the complexes was comparatively high than the free ligand. 相似文献