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991.
C. V. Yelamaggad S. Anitha Nagamani U. S. Hiremath D. S. Rao S. Krishna Shankar Prasad 《Liquid crystals》2013,40(10):1581-1583
A new set of trimesogens consisting of a cholesteryl ester, a biphenyl and an azobenzene mesogenic segment joined together through either odd-even, even-even or odd-odd central alkylene spacers has been synthesized and the liquid crystalline properties investigated. The trimesogens having even-even and odd-odd central alkylene spacers exhibit the undulated twist grain boundary phase (UTGBC*) mesophase over a temperature range of ~40-50°C. 相似文献
992.
993.
Venkata Krishna Reddy Motakatla Anusha Gokanapalli Vasu Govardhana Reddy Peddiahgari 《应用有机金属化学》2019,33(11)
A series of new benzimidazolium chlorides bearing N,N′‐benzyl, 2,4,6‐trimethylbenzyl and 2,4,6‐triisopropylbenzyl substituents have been designed and synthesized from various o‐phenylenediamines. Subsequently, corresponding Cu‐based N‐heterocyclic carbenes (NHCs) were generated in situ in the reaction medium which represents a new application of NHCs exploiting distinct catalytic property towards intermolecular cyclization reaction cascade for the synthesis of 2‐aryl‐3‐(arylethynyl)quinoxalines from o‐phenylenediamines and terminal alkynes. The outcome of the cyclization reaction product depends upon the N,N′‐substituents present on the benzimidazolium chlorides. 相似文献
994.
Prolinamides derived from l-proline and N,N-dialkyl 2-aminocamphor-10-sufonamides have been synthesized and used as organocatalysts in the direct intermolecular aldol reaction. Reactions of several aromatic aldehydes with cyclohexanone, cyclopentanone, 4-oxa and 4-sulfa-cyclohexanones and acetone are investigated employing 1a as an organocatalyst. Very high to excellent selectivities are obtained in these direct aldol reactions. 相似文献
995.
Ohne Zusammenfassung
Deutsch von Alfred Kuhn (Leipzig). 相似文献
996.
Hari Krishna Bisoyi 《Tetrahedron letters》2008,49(22):3628-3631
The synthesis and mesomorphism of the first examples of ‘discotic liquid crystal pentamers’ are reported. Structural characterization of these difunctional pentamers has been achieved by FTIR, NMR, and elemental analysis. The mesophase behavior exhibited by these ‘star-shaped’ molecules has been studied by polarizing optical microscopy and differential scanning calorimetry. The columnar hexagonal structure of the mesophase was established with the help of X-ray diffraction studies. 相似文献
997.
D. S. Shankar Rao Geetha G. Nair S. Krishna Prasad S. Anita Nagamani C. V. Yelamaggad 《Liquid crystals》2013,40(8):1239-1243
We report optical, X-ray, polarization and response time measurements on a new 'bananas-haped' mesogen. The material has a salicylaldimine segment in the linear part of the core, but is otherwise structurally similar to the mesogen first reported to show a banana mesophase. Textural and X-ray studies show that this mesophase has all the characteristics of the recently discovered B7 phase. It is observed that the voltage required to obtain electrical switching is quite low compared with values for the few other materials exhibiting the B7 phase. 相似文献
998.
A facile, InCl3 and/or DABCO mediated 1, 3-dipolar cycloaddition of ethyl diazoacetate (EDA) with various activated olefins under solvent-free conditions at ambient temperature to afford 3, 5-disubstituted pyrazolines and pyrazoles in moderate to good yields is reported. 相似文献
999.
1000.