全文获取类型
收费全文 | 983篇 |
免费 | 107篇 |
国内免费 | 39篇 |
专业分类
化学 | 762篇 |
晶体学 | 13篇 |
力学 | 49篇 |
综合类 | 1篇 |
数学 | 43篇 |
物理学 | 261篇 |
出版年
2024年 | 2篇 |
2023年 | 21篇 |
2022年 | 40篇 |
2021年 | 43篇 |
2020年 | 50篇 |
2019年 | 34篇 |
2018年 | 37篇 |
2017年 | 38篇 |
2016年 | 71篇 |
2015年 | 49篇 |
2014年 | 65篇 |
2013年 | 79篇 |
2012年 | 111篇 |
2011年 | 77篇 |
2010年 | 56篇 |
2009年 | 29篇 |
2008年 | 64篇 |
2007年 | 47篇 |
2006年 | 49篇 |
2005年 | 26篇 |
2004年 | 12篇 |
2003年 | 15篇 |
2002年 | 15篇 |
2001年 | 4篇 |
2000年 | 7篇 |
1999年 | 4篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 9篇 |
1995年 | 8篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 10篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1986年 | 2篇 |
1985年 | 7篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有1129条查询结果,搜索用时 15 毫秒
131.
Following the approach of optical reference geometry we derive the expression for the total force in the radial direction acting on a charged particle in magnetic fields superimposed on the static Schwarzschild background and show the possible existence of bound orbits for particles in the field of ultra compact objects at distancesr?3m wherein the Lorentz force counterbalances both the gravitational and centrifugal forces. 相似文献
132.
dc ionic conductivity measurements were made on single crystals of Pb(NO3)2 doped with monovalent Na+ and K+ in the temperature range of 100–400°C. In the extrinsic region the conductivity was found to decrease with Na+ having a smaller ionic size, and to increase with K+ with larger ionic size compared to the host Pb ion. Conductivity is attributed to the mobility of anti-Frenkel defects as in the case of PbF2. Dielectric loss measurements were made on the Pb(NO3)2: K+ system in the frequency range of 300 Hz to 20 kHz at different temperatures. Impurity vacancy pairs of the type K+-(NO-3)V are found to be responsible for the observed dielectric loss peaks. The maximum peak frequency is found to increase with temperature. 相似文献
133.
134.
Factors influencing the in vitro release of bovine serum albumin (BSA) from poly(butylcyanoacrylate) (PBCA) nanocapsules, such as the pH value, BSA loading, the polymeric nanocapsule walls and protein molecular weight, were investigated in detail. The BSA release rate was affected by the degradation rate of the polymeric wall and protein loading. For low molecular weight proteins, the initial burst release was faster than that of high molecular weigh proteins and got to equilibrium quickly. Sodium dodecyl sulfate–polyacrylamide gel electrophoresis results showed that BSA encapsulated within PBCA nanocapsules did not suffer covalent aggregation or fragmentation during the initial days of in vitro incubation. For nanocapsules prepared by interfacial polymerization in water-in-oil microemulsions, these findings were useful as a foundation for the development of nanocapsules with desired properties. 相似文献
135.
N. Katayama M. Kajita H. Koiso Y. Kubota F. Sai S. Sakamoto F. Shimizu T. Tsuboyama S.S. Yamamoto 《Nuclear Physics A》1984,423(3):410-418
We have investigated the dp → ppn non-spectator breakup reaction obtained from the KEK l m liquid hydrogen bubble chamber exposed to a beam of deuterons at ten momenta in the range 2.0–3.7 GeV/c. The pn and pp effective mass distributions in the two momentum regions 2.0–2.9 GeV/c and 3.0–3.7 GeV/c show no structure. 相似文献
136.
Microwave-assisted growth and characterization of water-dispersed CdTe/CdS core-shell nanocrystals with high photoluminescence 总被引:5,自引:0,他引:5
He Y Lu HT Sai LM Lai WY Fan QL Wang LH Huang W 《The journal of physical chemistry. B》2006,110(27):13370-13374
A novel microwave-assisted method of growth of high-quality CdTe/CdS core-shell nanocrystals in the aqueous phase is presented in this paper. The photoluminescence quantum yield (PLQY) is greatly enhanced by epitaxial growth of the CdS shell. Under optimum conditions, the PLQY of as-prepared nanocrystals reaches as high as 75% without any post-treatment. Furthermore, these investigations demonstrate that microwave irradiation is tremendously useful for fast epitaxial growth of nanocrystals due to its special characteristics. As a result, the microwave synthesis is sufficiently time-economizing (only five minutes are required) to obtain optimum amounts of CdTe/CdS core-shell nanocrystals in comparison to the conventional illumination method (several days are required). Therefore, this current research not only provides a rapid microwave synthesis for producing highly fluorescent CdTe/CdS core-shell nanocrystals, but also it presents some advantages of the microwave synthesis in comparison to the illumination method. 相似文献
137.
Sathish RS Sujith U Rao GN Janardhana C 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,65(3-4):565-570
A simple fluorescent detection based on the ligand exchange mechanism is proposed for the fluoride ion in aqueous media. This procedure is based on the exchange of 8-hydroxyquinoline (oxine) coordinated to Zr(IV) by fluoride ion without interference from other common anions. The ternary complex of oxine with [Zr(H(2)O)(2)EDTA].2H(2)O formed by replacing two water molecules in aqueous solution provides a sensitive signalling system for fluoride ion in the concentration range from 6 x 10(-7)M to 8 x 10(-4)M. The green fluorescence (lambda(max)=532 nm) exhibited by the complex upon excitation at 247 nm decreases in intensity with fluoride addition with a detection limit of 12 ppb. The complexation reaction between oxine and Zr(IV)-EDTA and the ligand exchange reaction with fluoride ion has been investigated by UV-vis and fluorescence spectroscopies combined with the PM3 semi-empirical quantum chemical calculations. Job's method of continuous variation and the molar ratio method ascertain a 1:1 stoichiometry composition of the chelate in aqueous media. 相似文献
138.
First-Principles Study of Electronic and Optical Properties of Y1-xCaxTiO3 (x=0, 0.25, 0.5, 0.75)
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The full potential linearized augmented plane wave (FP-LAPW) method with the generalized gradient approximation (GGA) is applied to study the electronic and optical properties of perovskite-type compounds Y1-xCaxTiO3. The lattice parameters, magnetic moment, band structure, density of states and optical conductivity are obtained. The results show that the Ca ion plays an important role in the electronic properties and optical responses. Moreover, the optical properties including the dielectric function, absorption spectrum, extinction coefficient, energy-loss spectrum and refractive index are also discussed. 相似文献
139.
Self-assembly of decylphosphonic acid (DPA) and octadecylphosphonic acid (ODPA) was studied on aluminum films using XPS, ToF-SIMS and surface wettability. Modified aluminum films were tested for passivation against silanization and subsequent oligonucleotide attachment. Passivation ratios of at least 450:1 compared to unprotected aluminum were obtained, as quantified by attachment of radio-labeled oligos. 相似文献
140.
Sai Hung Marten Ting 《Applied Mathematical Finance》2013,20(6):595-613
AbstractIn this paper we derive asymptotic expansions for Australian options in the case of low volatility using the method of matched asymptotics. The expansion is performed on a volatility scaled parameter. We obtain a solution that is of up to the third order. In case that there is no drift in the underlying, the solution provided is in closed form, for a non-zero drift, all except one of the components of the solutions are in closed form. Additionally, we show that in some non-zero drift cases, the solution can be further simplified and in fact written in closed form as well. Numerical experiments show that the asymptotic solutions derived here are quite accurate for low volatility. 相似文献