全文获取类型
收费全文 | 385篇 |
免费 | 21篇 |
国内免费 | 13篇 |
专业分类
化学 | 267篇 |
晶体学 | 6篇 |
力学 | 4篇 |
数学 | 80篇 |
物理学 | 62篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 17篇 |
2021年 | 22篇 |
2020年 | 17篇 |
2019年 | 20篇 |
2018年 | 25篇 |
2017年 | 20篇 |
2016年 | 26篇 |
2015年 | 14篇 |
2014年 | 13篇 |
2013年 | 42篇 |
2012年 | 19篇 |
2011年 | 20篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 9篇 |
2007年 | 11篇 |
2006年 | 9篇 |
2005年 | 11篇 |
2004年 | 8篇 |
2003年 | 3篇 |
2002年 | 13篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1967年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有419条查询结果,搜索用时 875 毫秒
11.
The oxidation of some xylenols with iodine in aqueous ethanolic solutions in the presence of silver ions as a catalyst was investigated and used for microdetermination of these reductants. The study of these redox reactions and the microdetermination of these phenols were performed by volumetric and spectrophotometric methods. These methods were compared. The spectrophotometric method was more accurate at very low concentrations (60–488 μg). The volumetric methods used silver ions as catalyst. The potentiometric method is more accurate than the visual method. Possible schemes for the course of these redox reactions were suggested. One electron processes for oxidation of xylenols have been indicated. 相似文献
12.
M. Nasr H. H. Zoorob A. Zayed M. T. El-Wassimi 《Monatshefte für Chemie / Chemical Monthly》1979,110(4):913-918
Condensation of 4-bromomethylquinoline derivatives1 a-1 c with glycine and thioglycolic acid gave the corresponding quinolylmethylglycine and quinolylmethylthioacetic acid derivatives2 a-2 c and2 d-2 f, respectively. Cyclization of2 a-2 f was affected either by polyphosphoric acid or concentrated sulphuric acid to give3 a-3 f. Chlorination of2 a-2 f and3 a-3 f were also accomplished.
Die Reaktivität von 4-Brommethylchinolin-Derivaten gegenüber Glycin und Thioglycolsäure. Ein neues Ringsystem
Zusammenfassung Die Reaktion von 4-Brommethylchinolin-Derivaten1 a-c mit Glycin und Thioglycolsäure gab die entsprechenden Kondensationsprodukte2 a-c und2d-f.2 a-f konnten mit Polyphosphorsäure bzw. mit konzentrierter Schwefelsäure zu Benzo[c]-2,6-naphthyridinen3 a-f zyklisiert werden.2 a-f und3 a-f waren einer Chlorierung (POCl3) zugängig.相似文献
13.
M. A. Kenawy M. S. Sakr E. M. Sakr H. A. Zayed N. O. Mourad 《Czechoslovak Journal of Physics》1991,41(10):967-974
Transient and steady state creep of Al-4.5 wt. % Mg alloy was studied under various constant stresses ranging from 91 MPa to 117 MPa in the temperature range from 473 K to 553 K. The results of creep characteristics have shown two main deformation temperature regions (below 493 K and above 513 K as well as a transient region between these temperatures). Peak values of transient creep parametersB andn were obtained at 493 K. The transient creep parameterB was related to the steady state creep rate st through the exponent which was found to range from 0.85 to 0.5. The stress exponentm of the steady state creep has been found to be minimum at the steady state strain peaks, which is characteristic of dislocation climb along the grain boundaries. Microstructural analysis confirmed that the above mentioned mechanism took place in the dissolution region of-phase. 相似文献
14.
15.
Efficiencies of cationic gemini surfactant additives in improving the pour point depressant of crude oil were investigated. The length of alkyl chain is a major factor affecting the improvement of the pour point depression. The adsorption behavior of these gemini surfactants at air/solution and oil/solution interfaces were investigated by measuring the surface tension and interfacial tension as functions of concentration. It is found that there is a good relation between surface properties especially interfacial tension of the gemini surfactants and their efficiency in depressing the pour point. Also, the surface parameters and free energies of micellization and adsorption confirm the decreasing and improving of pour point depression. Crystallization study in crude oil revealed the relationship between the structure and activity of gemini surfactant additives. It is found that the x-ray diffraction patterns of waxes with additives are remarkably different from those without additives. The mechanism of the depressants action has been suggested according the adsorption of each additive. Adsorption of the additive on the surface of the wax particles inhibits their growth and alters the crystal habits through micelle core. Pretreatment of the crude oil with pour point depressants has received the greatest acceptance due to its simplicity and economy. 相似文献
16.
Coordination compounds of Fe(III), Zn(II), Ni(II), Co(II), Cu(II), Cd(II) and Mn(II) ions were synthesized from the ligand [4,4′‐((((ethane‐1,2‐diylbis(oxy))bis(2,1‐phenylene))bis(methanylylidene))bis(azanylylidene))diphenol]ethane (H2L) derived from the condensation of bisaldehyde and 4‐aminophenol. Microanalysis, magnetic susceptibility, infrared, 1H NMR and mass spectroscopies, molar conductance, X ray powder diffraction and thermal analysis were used to confirm the structure of the synthesized chelates. According to the data obtained, the composition of the 1:1 metal ion–bis‐Schiff base ligand was found to be [M(H2L)(H2O)2]Cln (M = Zn(II), Ni(II), Co(II), Cu(II), Cd(II) and Mn(II), n = 2; Fe(III), n = 3). Magnetic susceptibility measurements and reflectance spectra suggested an octahedral geometry for the complexes. Central metals ions and bis‐Schiff base coordinated together via O2 and N2 donor sites which as evident from infrared spectra. The Gaussian09 program was applied to optimize the structural formula for the investigated Schiff base ligand. The energy gaps and other important theoretical parameters were calculated applying the DFT/B3LYP method. Molecular docking using AutoDock tools was utilized to explain the experimental behaviour of the Schiff base ligand towards proteins of Bacillus subtilis (5 h67), Escherichia coli (3 t88), Proteus vulgaris (5i39) and Staphylococcus aureus (3ty7) microorganisms through theoretical calculations. The docked protein receptors were investigated and the energies of hydrogen bonding were calculated. These complexes were then subjected to in vitro antibacterial studies against several organisms, both Gram negative (P. vulgaris and E. coli) and Gram positive (S. pyogones and B. subtilis). The ligand and metal complexes exhibited good microbial activity against the Gram‐positive and Gram‐negative bacteria. 相似文献
17.
18.
19.
An efficient, solid‐catalyst‐mediated Hantzsch synthesis of 1,4‐dihydropyridines is described. This procedure has such advantages as short reaction time, high yields, and simple workup. The catalyst could be reused several times and keeps its initial activity in the subsequent reactions. 相似文献
20.
A simple, efficient, and rapid method for high-yielding regioselective mono bromination of phenols and anilines has been achieved by treatment with N-bromasaccharin in the presence of a catalytic amount of tungstophosphoric acid. 相似文献