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11.
Hadi Amiri Amir Charkhi Mohammad Ali Moosavian Seyyed Javad Ahmadi Hamed Nourian 《Chemical Papers》2017,71(9):1587-1596
The polydimethylsiloxane (PDMS) mixed matrix membrane with dispersed phase of nanozeolite silicalite-1 has been synthesized on polyethersulphone (PES) as a support, and its performance in the gas separation of xenon and krypton has been studied. For this purpose, nanozeolite silicalite-1 is synthesized by the hydrothermal clear solution method and is characterized by XRD and SEM analysis. In this research, the separation performance of MMM has also been compared with the polymeric PDMS membrane. Furthermore, the effect of feed pressure and loading percentage of nanozeolite in the polymeric matrix are evaluated. The results indicate that the addition of nanozeolite to the polymeric matrix improves its separation performance, and that the changes of the feed pressure have no major effect. The average permeability of the krypton and xenon gases through the PDMS polymeric membrane is calculated as 1.25 × 10?9 and 1.78 × 10?9 cm mol/(cm2 s kPa), respectively, while by adding only 5 wt% of nanosilicalite-1 to the polymeric matrix of the membrane, this amount increased to 1.82 × 10?9 and 8.07 × 10?9 cm mol/(cm2 s kPa), respectively. In addition, the presence of nanosilicalite-1 as the filler leads to an increase in the selectivity of xenon to krypton up to 4.38. 相似文献
12.
Issa Yavari Mina Haghdadi Rahebeh Amiri 《Phosphorus, sulfur, and silicon and the related elements》2013,188(10):2015-2023
Ab initio calculations at HF/6-31+G? level of theory for geometry optimization, and MP2/6-31+G?//HF/6-31+G? and B3LYP/6-31+G?//HF/6-31+G? levels for a single-point total energy calculation, are reported for the chair and twist conformations of 1,2-dithiane (1), 3,3,6,6-tetramethyl-1,2-dithiane (2), 1,2,4,5-tetrathiane (3), and 3,3,6,6-tetramethyl-1,2,4,5-tetrathiane (4). The C2 symmetric chair conformations of 1 and 2 are calculated to be 21.9 and 8.6 kJ mol?1 more stable than the corresponding twist forms. The calculated energy barriers for chair-to-twist processes in 1 and 2 are 56.3 and 72.8 kJ mol?1, respectively. The C2h symmetric chair conformation of 3 is 10.7 kJ mol?1 more stable than the twist form. Interconversion of these forms takes place via a C2 symmetric transition state, which is 67.5 kJ mol?1 less stable than 3-Chair. The D2 symmetric twist-boat conformation of 4 is calculated to be 4.0 kJ mol?1 more stable than the C2h symmetric chair form. The calculated strain energy for twist to chair process is 61.1 kJ mol?1. 相似文献
13.
Reza Takjoo Alireza Akbari Mehdi Ahmadi Hadi Amiri Rudbari Giuseppe Bruno 《Central European Journal of Chemistry》2013,11(11):1844-1851
A new Schiff base ligand of 5-bromo-2-hydroxybenzaldehyde S-ethyl-isothiosemicarbazone (H2L) was synthesized and its mixed-ligand Cu(II) complex was also prepared by reaction of Cu(NO3)2·3H2O with H2L and imidazole. Their structures were fully characterized by elemental analysis, FT-IR, molar conductivity and UV-Vis methods. The analytical data suggest that the metal, H2L and imidazole ratios in the Schiff base complex are 1:1:1. Single crystal diffraction was also used to better understand the molecular structure of the Cu(II) complex. The results of physico-chemical analyses of the Schiff base complex reveal the coordination geometry around the central atom is square planar. The H2L ligand (NNO donor) is coordinated to the metal center as a tridentate bionegatively agent. Another position of the square planar geometry is occupied by the imidazole ligand. Furthermore, computational studies of the new complex were performed by carrying out DFT calculations. Geometry optimization and natural band analysis of the complex is discussed in further detail. 相似文献
14.
An efficient, solid‐catalyst‐mediated Hantzsch synthesis of 1,4‐dihydropyridines is described. This procedure has such advantages as short reaction time, high yields, and simple workup. The catalyst could be reused several times and keeps its initial activity in the subsequent reactions. 相似文献
15.
A simple, efficient, and rapid method for high-yielding regioselective mono bromination of phenols and anilines has been achieved by treatment with N-bromasaccharin in the presence of a catalytic amount of tungstophosphoric acid. 相似文献
16.
An environmentally benign, one-pot, four-component synthesis of chemically and pharmaceutically interesting dithiocarbamate derivatives is reported. The one-pot reaction of various aromatic aldehydes, ketones, aliphatic amines, and carbon disulfide, in the presence of potassium hydroxide in urea-choline chloride deep eutectic solvent or ethanol, leads to the corresponding dithiocarbamates in good to excellent yields. This method provides a convenient and time-saving strategy, with a simple work-up procedure. 相似文献
17.
New polypyrrole–carbon nanotubes–silicon dioxide solid‐phase microextraction fiber for the preconcentration and determination of benzene,toluene, ethylbenzene,and o‐xylene using gas liquid chromatography
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Ali Sarafraz‐Yazdi Gholamhossein Rounaghi Iman Razavipanah Hossein Vatani Amirhassan Amiri 《Journal of separation science》2014,37(18):2605-2612
For the first time, a polypyrrole–carbon nanotubes–silicon dioxide composite film coated on a steel wire was prepared by an electrochemical method. Scanning electron microscopy images showed that this composite film was even and porous. The prepared fiber was used as an absorbent for the headspace solid‐phase microextraction of benzene, toluene, ethylbenzene, and o‐xylene, followed by gas chromatographic analysis. This method presented an excellent performance, which was much better than that of a polypyrrole–carbon nanotube fiber. It was found that under the optimized conditions, the linear ranges were 0.01–200 ng/mL with correlation coefficients >0.9953, the detection limits were 0.005–0.020 ng/mL, the relative standard deviations were 3.9–6.4% for five successive measurements with a single fiber, and the reproducibility was 5.5–8.5% (n = 3). Finally, the developed method was successfully applied to real water samples, and the relative recoveries obtained for the spiked water samples were from 91.0 to 106.7%. 相似文献
18.
Chromatographia - Tocilizumab is a monoclonal antibody used in the treatment of several inflammatory and autoimmune diseases as well as cancers. Tocilizumab improves clinical outcomes and reduce... 相似文献
19.
Gagan Chhabra Chandra K. Singh Deeba Amiri Neha Akula Nihal Ahmad 《Molecules (Basel, Switzerland)》2021,26(5)
Immunomodulation of the tumor microenvironment is emerging as an important area of research for the treatment of cancer patients. Several synthetic and natural agents are being investigated for their ability to enhance the immunogenic responses of immune cells present in the tumor microenvironment to impede tumor cell growth and dissemination. Among them, resveratrol, a stilbenoid found in red grapes and many other natural sources, has been studied extensively. Importantly, resveratrol has been shown to possess activity against various human diseases, including cancer. Mechanistically, resveratrol has been shown to regulate an array of signaling pathways and processes involving oxidative stress, inflammation, apoptosis, and several anticancer effects. Furthermore, recent research suggests that resveratrol can regulate various cellular signaling events including immune cell regulation, cytokines/chemokines secretion, and the expression of several other immune-related genes. In this review, we have summarized recent findings on resveratrol’s effects on immune regulatory cells and associated signaling in various cancer types. Numerous immunomodulatory effects of resveratrol suggest it may be useful in combination with other cancer therapies including immunotherapy for effective cancer management. 相似文献
20.
Abdolahi Sahar Hajjami Maryam Gholamian Fatemeh 《Research on Chemical Intermediates》2021,47(5):1883-1904
Research on Chemical Intermediates - The aim of present investigation is the synthesis of mesoporous catalyst based on hexagonal mesoporous silica. HMS support has exceptional properties such as... 相似文献