Growth of CdS nanoparticles by chemical method and its characterization

In the present work a simple chemical reduction method is followed to grow CdS nanoparticles at room temperature. The grown sample is ultrasonicated in acetone. The dispersed sample is characterized using electron diffraction technique. Simultaneously optical absorption of this sample is studied in the range of 400–700 nm. The photoluminescence spectrum of the sample is also studied. Results show the formation of nanoparticles. Hence an increase in band gap compared to bulk CdS and the as-prepared CdS nanoparticles have surface sulphur vacancies.      

Soliton model of atom

The Einstein-de Broglie soliton concept is applied to simulate stationary states of an electron in a hydrogen atom. According to this concept, the electron is described by the localized regular solutions to some nonlinear equations. It is shown that the electron-solilon center travels along some stationary orbit around the Coulomb center. The electromagnetic radiation is absent as the Poynting vector has non-wave asymptote O(r ^–3)after averaging over angles.     

Elliptical crack and punch problems solved by integral equation method for piezoelectric media

The problem of an elliptical crack embedded in an unbounded transversely isotropic piezoelectric media with the crack-plane parallel to the plane of isotropy of the media and subjected to remote normal mechanical as well as electric loading is considered first. The problem has been successfully reduced to a pair of coupled integral equations that are suitable for the application of an integral equation method developed earlier for three-dimensional problems of LEFM. Solution to the mechanical displacement and electric potentials are obtained for prescribed uniform loadings and expressions for corresponding intensity factors and crack opening displacement are deduced. The above method has further been applied to solve the problem of a rigid flat-ended elliptical punch indenting a transversely isotropic piezoelectric half-space surface with the plane of isotropy parallel to the surface. Solutions to mechanical stress and electric displacement are obtained for prescribed constant normal displacement and constant electric potential interior to the elliptical region and expression for the total force required to maintain a prescribed indentation is deduced.     

Experimental study of flow past a square cylinder at high Reynolds numbers

 Measurements of two-components of velocity in the wake of a square cylinder using a hot-wire anemometer are reported. Two Reynolds numbers, namely 8700 and 17,625, have been considered. The measurements were carried out in a low-speed, low-turbulence wind tunnel. Benchmark experiments at much lower Reynolds numbers show good agreement between the present experiments and published results. At higher Reynolds numbers, the experimental data reveal anticipated trends in terms of wake recovery and turbulence decay. Both velocity and velocity fluctuations show symmetry about the wake axis. The experimental data have been compared with the large eddy simulation (LES) calculation reported by Wang et al. [University of Illinois at Urbana – Champaign (1996) Report CFD 96-03] and LDV measurements of Lyn et al. [J Fluid Mech (1995) 304: 285–319]. The agreement among the three sets is generally acceptable in terms of the time-averaged velocity components, but not the velocity fluctuations. The turbulence fluctuations in the present experiments are seen to be lower than in the referred work. The differences have been traced to factors such as the aspect ratio, blockage ratio and upstream turbulence. Experiments with increased upstream turbulence did show a reduction in the discrepancy between the present experiments and the published data. An assessment of the experimental data in terms of physical mechanisms revealed that (a) streamwise normal stresses were correlated with the vortex centers, and (b) the turbulence kinetic energy profiles are similar to the turbulence shear stress. Spectral analysis of the velocity signals was carried out in the present work. Energy transfer from the mean flow to the streamwise velocity fluctuation was confirmed in the near wake. A redistribution of the kinetic energy between the streamwise and transverse components of velocity over a longer distance downstream was subsequently observed. Received: 17 May 1999/Accepted: 29 December 1999     

Prediction of barrier inhomogeneities and carrier transport in Ni-silicided Schottky diode

Based on Quantum Mechanical (QM) carrier transport and the effects of interface states, a theoretical model has been developed to predict the anomalous current-voltage (I-V) characteristics of a non-ideal Ni-silicided Schottky diode at low temperatures. Physical parameters such as barrier height, ideality factor, series resistance and effective Richardson constant of a silicided Schottky diode were extracted from forward I-V characteristics and are subsequently used for the simulation of both forward and reverse I-V characteristics using a QM transport model in which the effects of interface state and bias dependent barrier reduction are incorporated. The present analysis indicates that the effects of barrier inhomogeneity caused by incomplete silicide formation at the junction and the interface states may change the conventional current transport process, leading to anomalous forward and reverse I-V characteristics for the Ni-silicided Schottky diode.     

Anisotropic Cosmological Models with Perfect Fluid and Dark Energy Reexamined

We consider a self consistent system of Bianchi type-I (BI) gravitational field and a binary mixture of perfect fluid and dark energy. The perfect fluid is taken to be the one obeying the usual equation of state, i.e., p = ξε, with ζ∉[0, 1] whereas, the dark energy is considered to be obeying a quintessence-like equation of state. The modification of the ordinary quintessence lies in the fact that its pressure becomes positive if the (dark) energy density exceeds some critical value. Exact solutions to the corresponding Einstein equations are obtained. The model in consideration gives rise to a Universe which is spatially finite. Depending on the choice of problem parameters the Universe is either close with a space-time singularity, or an open one which is oscillatory, regular and infinite in time. PACS numbers: 04.20.Ha, 03.65.Pm, 04.20.Jb     

Self-sorting of multicomponent Pt(II) metallacages

Structural Chemistry - Using a social self-sorting phenomenon, two Pt(II)←pyridyl, carboxylate heteroleptic metallacages cage 1 and cage 2 have been constructed in nearly quantitative yields...     

DFT study of response mechanism and selectivity of poly(3,4-ethylenedioxythiophene) towards CO2 and SO2 as gas sensor

Structural Chemistry - To evaluate the sensing ability of poly(3,4-ethylenedioxythiophene) (PEDOT) towards CO2 and SO2 gaseous molecules, an extensive quantum mechanical study has been carried out...