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61.
Muhammad Yaseen Zahid Farooq Mian H. R. Mahmood Sheikh Asrar Ahmad Shahbaz Nazir Khalid Mahmood Anjum Syed Ali Raza Naqvi 《Journal of heterocyclic chemistry》2019,56(5):1520-1529
A new convenient solid–liquid condensation reaction procedure for the synthesis of novel asymmetric and symmetric meso‐tetraarylporphyrin and metalloporphyrin Schiff bases is reported. The condensation reaction between β‐formyl porphyrin or metalloporphyrins and aromatic amines was carried out at solid–liquid interface by using neutral alumina powder as a solid support for β‐formyl porphyrin or metalloporphyrins and absolute ethanol as the carrier solvent for aromatic amines. Six different asymmetric porphyrin/metalloporphyrin Schiff bases were synthesized via solid–liquid interface reaction methodology. The same solid–liquid synthetic methodology was applied for the synthesis of six novel symmetric Schiff base porphyrin/metalloporphyrin dimers. The comparison of UV–visible spectra of porphyrin Schiff base monomers and dimers revealed that some degree of electronic perturbation has occurred upon dimerization as the Soret bands of the monomers underwent peak broadening along with red shifts. Column chromatography and crystallization were used to purify the compounds. Fourier transform infrared, UV–visible, elemental analysis, 1H NMR, and mass spectrometry were used to characterize the newly synthesized compounds. 相似文献
62.
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64.
The energy spectrum and the angular correlation distributions for the reaction 12C(e, e'p)11B are calculated within the framework of DWBA using spherical Hartree-Fock wave functions. A comparison with experiment and some of the earlier calculations is made. It is observed that a large spatial extent of the wave functions significantly improves the agreement. 相似文献
65.
M. I. Al-Jarallah A. A. Naqvi Fazal-ur-Rehman M. Maselehuddin F. Abu-Jarad M. Raashid 《Radiation measurements》2003,36(1-6):471-474
In a prompt gamma ray neutron activation analysis (PGNAA) setup, the neutron moderation in the bulk sample also plays a key role. This can even dominate the thermalization effects of the external moderator in some cases. In order to study the neutron moderation effect in the bulk sample, moderators with two different sizes of the sample were tested at the King Fahd University of Petroleum & Minerals (KFUPM) PGNAA facility. In these tests, the thermal neutron relative intensity and prompt gamma ray yield from the two moderators were measured using nuclear track detectors (NTDs) and NaI detector, respectively. As predicted by Monte Carlo simulations, the measured intensity of thermal neutron inside the large sample cavity due to the external moderator was smaller than that from the smaller sample cavity. Due to its larger size, additional thermalization of neutrons will take place in the larger sample. In spite of smaller thermal neutron yield from the external moderator at the large sample location, higher yield of the prompt gamma ray was observed as compared to that from the smaller sample. This confirms the significance of neutron moderation effects in the bulk sample and can thereby affect the PGNAA geometry size. This allows larger samples in conjunction with smaller moderators in the PGNAA setup. 相似文献
66.
This paper reports the first time achievement of laser photolysis of thallium dimers by single photon absorption of N2-laser light at 337.1 nm resulting in a large population inversion of thallium 7 2S
excited state with respect to 6 2P
state. The photodissociation nitrogen laser pulse is spatially and temporally overlapped with the tunable dye laser pulse that is used for confirming the production of selectively excited thallium atoms. The dye laser excites the thallium atoms from 7 2S
state to high lying Rydberg states that collisionally ionize giving an ion-current signal which is subsequently processed by a box-car average/integrator and recorded on the chart recorder. The photodissociation of Tl2 to Tl(7 2S
) state demonstrates the existence of the molecular dissociative state 1g that is correlated with Tl 7 2S
+6 2P
states. A complete absence of 6 2P
state population among the photolysis products indicates a 100% prompt population inversion between 7 2S
and 6 2P
atomic states. 相似文献
67.
A. Aksoy M. N. Al-Haddad A. A. Naqvi K. Al-Nahdi 《Journal of Radioanalytical and Nuclear Chemistry》1994,181(1):131-140
An instrumental thermal neutron activation analysis facility based, on a 16 Ci241 Am–Be source, a high resolution -ray spectrometry setup and a PC-based data acquisition system at KFUPM is described. The thermal neutron flux distribution was determined from the induced activities of high purity indium foils. The absolute thermal neutron flux was calculated from the activities of bare and cadmium-covered gold foils at a position of 3 cm from the soource at which the flux reaches a maximum. The facility tests were carried out with the determination of manganese concentrations in six types of industrially important steel samples. The result of 1.33% manganese in SS-304 steel sample was in excellent agreement with the literature value. The method is nondestructive, economical and ideal for bulk analysis. 相似文献
68.
It is shown that the lifetimes of excited states of molecules which give a reasonably strong absorption (molar decadic extinction coefficient ∈ > 104M?1cm?1) at the frequency of the ruby laser can be determined from the saturation of the optical transitions. This is illustrated for DDI (1,1'-diethyl-2,2'-dicarbocyanine iodide) in glycerol, which appears to have a lowest excited state with a lifetime of 110 psec. This value agrees fairly well with that calculated from the formula for the rate of internal conversion derived from Siebrand's work. Under favourable conditions lifetimes as short as 10 psec can be measured. 相似文献
69.
N. P. S. Rana Padam Singh Ameer Azam A. H. Naqvi D. S. Srivastava 《Journal of Radioanalytical and Nuclear Chemistry》1996,213(2):127-133
The sandwiched pellet technique using Makrofol-E plastic track detectors has been employed to determine trace quantities of uranium in nine brands of flavored chewing tobaccos consumed by the Indian population. In this technique the nuclear reaction,235U(n,f), is used for the quantitative estimation of uranium. The maximum value of uranium (1.88 ppm) has been found in raw tobacco leaves (Surti), while the minimum (0.13 ppm) in Tulsi (Double Zero brand). Other seven brands showed intermediate values of U-contents which are also reported in this paper. These values are compared with the U-contents reported in the literature for other forms of tobaccos. 相似文献
70.
Robert Filler Garry L. Cantrell Donald Wolanin Saiyid M. Naqvi 《Journal of fluorine chemistry》1986,30(4):399-414
New and improved syntheses of 4,5,7,8-tetrafluoro- and 4,5,7,8,12,13,15,16-octafluoro[2.2]paracyclophanes are described. The preparation of the new compound, 4,5,7,8-tetrafluoro[2.2]metaparacyclophane, is outlined. 相似文献