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91.
WANG Shou-Xin FU Yi-Feng FAN Zhi-Jin MI Na ZHANG Hai-Ke SONG Hai-Bin Belskaya N.P Bakulev V.A 《结构化学》2011,30(2)
The title compound naphthalen-2-y1-4-methy1-1,2,3-thiadiazole-5-carboxylate(C14H10N2O2S,Mr = 270.31)was synthesized by the reaction of 4-methyl-1,2,3-thiadiazole-5-carbonyl chloride with 2-naphthol,and its structure was characterized by IR,1H NMR,high-resolution mass spectrometry and single-crystal X-ray diffraction.The crystal belongs to orthorhombic,space group Pbcn with a = 23.475(5),b = 9.6640(19),c = 10.814(2)(A°),β = 90.00°,Z= 8,V= 2453.2(9)(A°)3,Mr = 270.30,Dc = 1.464 g/cm3,μ= 0.262 mm-1,F(000)= 1120,R = 0.0444 and wR = 0.1099.X-ray analysis revealed that the thiadiazole and naphthalene rings were non-planar,while,the thiadiazole ring and the ester group were essentially planar,and two intermolecular hydrogen bonds C(6)-H(6)…O(1)and C(14)-H(14)…O(1)were observed.The preliminary biological test showed that the title compound had antifungal and antivirus activities against tobacco mosaic virus. 相似文献
92.
以高锰酸钾和醋酸锰为前驱体, 通过液相沉淀法合成得到二氧化锰. 在不同温度热处理条件下研究二氧化锰的结构转变及其作为超级电容器电极材料的电化学行为. 采用X射线衍射(XRD), 扫描电镜(SEM), 氮气物理吸附和热重(TG)等手段表征产物的结构特点; 采用循环伏安和恒流充放电等方法表征其电化学行为. 结果表明: 合成的二氧化锰是具有中孔特征的α-MnO2, 比表面积为253 m2·g-1, 颗粒尺寸在50-100 nm之间. 350 °C以下的低温热处理使氧化锰仍能保持α-MnO2的晶体结构, 比表面积为170 m2·g-1左右, 单电极比电容值由原来未热解时的267 F·g-1增加到250 °C热处理后的286 F·g-1. 高温热处理(>450 °C)导致氧化锰逐渐过渡为α-Mn2O3, 且表面积下降约为30 m2·g-1, 比电容急剧下降. 低温热处理后氧化锰的电化学稳定性明显提高, 在50 mV·s-1的快速扫描速率下, 电极具有良好的倍率特性. 相似文献
93.
以磷酸、B4C和Al2O3为原料,采用一种新的微波水热法对C/C复合材料基体进行了抗氧化改性,重点研究了微波水热时间对改性试样物相组成、微观结构和抗氧化性能的影响。采用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、能量色散谱仪(EDS)及X射线光电子能谱(XPS)对改性后试样进行了表征。结果表明:改性后复合材料表面覆盖了一层由熔融态的HPO3、B2O3和结晶的Al(PO3)3、微量B4C粒子组成的涂层。经60~120 min的微波水热改性,复合材料的抗氧化性能随着微波水热处理时间的延长而改善,达到一定程度后,其变化不再明显。微波水热处理100 min后的试样抗氧化性能最佳,在600℃静态空气气氛下氧化16 h后,氧化失重仅为9.5×10-4 g.cm-2,氧化失重速率维持在4.46×10-5 g.cm-2.h-1的极低水平。 相似文献
94.
The spherical oil agglomeration of barite suspensions in the presence of surfactant and cosurfactant
Zygmunt Sadowski 《Colloids and surfaces. A, Physicochemical and engineering aspects》1993,80(2-3):147-152
The spherical agglomeration of barite particles using oil in the presence of both surfactant and cosurfactant was studied. It was found that the mineral suspension needed a critical surfactant concentration to initiate oil agglomeration. The addition of long-chain aliphatic alcohols to the organic phase decreased the critical surfactant concentration. This phenomenon was ascribed to a screening effect of alcohol molecules in the adsorption layer of surfactant. When sodium chloride was added to the solution the spherical agglomeration disappeared even though the surfactant adsorption at the barite/solution interface increased. It was concluded that the disappearance of oil agglomeration was caused by a bilayer of the surfactant which was formed on the barite surface. In the barite—surfactant—alcohol—oil—brine system the agglomeration process is only realized with the long-chain alcohols. This behaviour can be explained by microemulsion formation at the mineral/solution interface. 相似文献
95.
V. A. Gribkov A. V. Dubrovsky M. Paduch M. J. Sadowski M. Scholz K. Tomaszewski K. Malinowski E. Skladnik-Sadowska P. Strzyzewski A. K. Marchenko A. V. Tsarenko S. A. Masljaev V. N. Pimenov 《Czechoslovak Journal of Physics》2006,56(12):1401-1416
The paper presents results of recent experiments, as performed with the PF-1000 and PF-6 Plasma-Focus facilities, which were
aimed at investigation of the correlation between processes of the irradiation of different materials of fusion devices and
results of this irradiation. Among the irradiated samples there were pure tungsten, tantalum, copper, aluminum, and alloys,
based on these metals, various steels, carbon and carbon-based materials, which are designed for plasma facing components
or constructional parts of future thermonuclear reactors of the inertial- and magnetic-confinement types. The corpuscular
radiation consisted of high-energy (E
D>100 keV) deuterium ion beams and fast (v
str ≥ 107 cm/s) deuterium-plasma streams. They were investigated by a number of methods with spatial and temporal resolution. Particular
attention was paid to the verification of diagnostic techniques, which might be used for time- and space-resolved studies
of the interaction process. Correlation of these data with information obtained from subsequent analytical investigation of
some of the irradiated specimens, as performed by means of a number of methods typical for material sciences, gives possibility
to deduce physical mechanisms of the deuterium implantation and radiation damage of the investigated materials in dependence
on the conditions of their irradiation. 相似文献
96.
97.
硒的原子吸收分析进展 总被引:16,自引:1,他引:15
米瑞华 《光谱学与光谱分析》1993,13(4):103-110
本文对1985年以来硒的原子吸收分析,从石墨炉法、氢化物法、氢化物-石墨炉法和火焰法四个方面的分析进展进行综合评述。 相似文献
98.
99.
WANG Dian-Fu SONG He-Shan MI Dong 《理论物理通讯》2004,42(9)
In terms of the Nambu-Jona-Lasinio (NJL) mechanism, the dynamical symmetry breaking of a simple localgauge model is investigated. An important relation between the vacuum expectation value of gauge fields and scalarfields is derived by solving the Euler equation for the gauge fields. Based on this relation the SU(3) gauge potential isgiven which can be used to explain the asymptotic freedom and confinement of quarks in a hadron. The confinementbehavior at finite temperatures is also investigated and it is shown that color confinement at zero temperature can bemelted away under high temperatures. 相似文献
100.