Sodium atom emission from nitrogen afterglows: excitation process and doppler temperature

We have investigated the dependence of Doppler temperature of the D₁ sodium emission (λ 5896 Å) from a nitrogen afterglow, on the afterglow conditions. We found that afterglows having low N-atom concentrations give emission lines for which T (λ 5896 Å) = 900 ± 200°K.By contrast, in an afterglow emitting the N₂ bands brightly, the temperature of the λ 5896 Å line was 1300°K to 1500°K while in a similar environment (but with much more sodium present) the temperature of the Na λ 6154 Å line was around 900°K.     

On the separation of Co and Ni from chloride media withAliquat 336-TBP andAliquat 336-TOPO

Summary The extraction behaviour of Co and Ni chlorides withAliquat 336-TBP andAliquat 336-TOPO (Aliquat 336: tri-n-octylmethylammonium chloride,TBP: tri-n-butylphosphate,TOPO: tri-n-octylphosphine oxide) was investigated. The synergistic action ofTOPO in the extraction of Co and Ni withAliquat 336 manifested itself in an increase of the distribution ratio of Co with increasing ofTOPO concentration at constantAliquat 336 concentration without deterioration of the separation factor Co/Ni which still was above 200. Mixed complexes of the general formulaMeCl_2+mA_mB_n (Me: Co or Ni,A:Aliquat 336, A:TBP orTOPO) withm ranging from 2 to 5 andn from 1 to 3 were present in the organic phase of both systems. The coexistence of several synergistic Co/Ni species in the equilibrium organic phase is reported for the first time.

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Zur Abtrennung von Co und Ni aus chloridhaltigen Medien mitAliquat 336-TBP undAliquat 336-TOPO

Zusammenfassung Das Extraktionsverhalten von Kobalt- und Nickelchloriden mitAliquat 336-TBP undAliquat 336-TOPO (Aliquat 336: Tri-n-octylmethylammoniumchlorid,TBP: Tri-n-butylphosphat,TOPO: Tri-n-octylphosphinoxid) wurde untersucht. Die synergistische Wirkung vonTOPO bei der Extraktion von Co und Ni mitAliquat 336 manifestiert sich in einer Erhöhung des Verteilungsverhältnisses von Co mit steigenderTOPO-Konzentration, ohne daß dadurch der Co/Ni-Trennfaktor verschlechtert wird (> 200). Für beide Systeme konnten in der organischen Phase gemischte Komplexe der allgemeinen FormelMeCl_2+m A _mB_n nachgewiesen werden (Me: Co oder Ni,A:Aliquat 336,B:TBP orderTOPO,m : 2–5,n: 1–3). Zum ersten Mal wird über die Koexistenz verschiedener synergistischer Co/Ni-Spezies in der organischen Phase im Gleichgewicht berichtet.

     

Reduction of quinones with zinc metal in the presence of zinc ions: application of post-column reactor for the fluorometric detection of vitamin K compounds

A simple and effective chemical method has been developed for quantitatively reducing quinones, which is based on their reaction with zinc metal and zinc ions. Comparison of this method with conventional electrochemical reduction revealed the chemical method to be considerably superior. The reduction of quinones to their corresponding hydroquinones was verified by ultraviolet spectrophotometry. The reduction methodology has been applied to derivatize phylloquinone and its metabolite, namely phylloquinone 2,3-epoxide, 'on-line', with subsequent fluorometric detection of the generated hydroquinones.     

Non-linear behaviour of foams under static and impact three point bending

The influence of impregnation on mechanical properties of polyurethane foams at room temperature has been experimentally evaluated in both static and impact loading conditions. The impregnation layer increases the flexural modulus and changes the foam behaviour at impact. For un-impregnated foam the energy absorbed to fracture is equal to the impact energy, while for the impregnated specimens the energy absorbed to fracture is approximately 80% of the impact energy, which indicated that the other part of the impact energy was consumed for internal damage. The same amount of energy was reached for both static and impact tests, but different shapes of energy versus displacement curves were obtained. For notched specimens under impact load, the effect of impregnation is cancelled and identical behaviour was obtained for un-impregnated and impregnated specimens.     

一类具时滞耗散型Duffing方程的周期解

利用Mawhin重合度理论研究了一类耗散型时滞Duffing方程ax″+f[x′(t-τ1(t))]+cx+g(x(t-τ2(t)))=p(t)周期解的存在性,得到了该方程2π周期解存在的充分性定理.     

吡罗昔康凝胶有效成分的紫外分光光度法测定

吡罗昔康凝胶是吡罗昔康加适量的基质的透明的透皮吸收制剂。本文提出了对其有效成分吡罗昔康进行紫外光光度测定的方法，该方法简便、快速，能用于纯度较高的样品分析，可作为吡罗昔康凝胶药品质量标准控制方法。     

长径比可控的CdS纳米棒制备及光催化性能研究

采用溶剂热法制备了长径比可控的纤锌矿CdS纳米棒;以3CdSO4·8H2O、CH4 N2S为原料在180℃、24 h溶剂热反应条件下,通过改变Cd/S物质的量比和保温时间等因素来调节CdS纳米棒的长径比.利用扫描电镜(SEM)、X射线衍射(XRD)、紫外可见吸收光谱(UV-Vis)、光催化分别对其形貌、结构和光催化性能进行了表征和分析.结果表明:Cd/S摩尔比对CdS棒的生长起到关键作用,随着镉硫比的减小,CdS纳米棒的长径比逐渐增大.当Cd/S摩尔比为1∶6时,制备的CdS为长径比较大且表面光滑的纳米棒,纳米棒的尺寸大约为长800 nm、直径70nm.通过降解亚甲基蓝溶液测试了CdS纳米材料的可见光照射下的光催化性能,结果表明具有大长径比的CdS纳米棒表现出优异的光催化活性.     

新疆伊犁小于赞金矿床中FeS2的矿物学研究

小于赞金矿床赋存于下石炭统大哈拉军山组上亚组中酸性火山岩及火山碎屑岩中,为浅成低温热液型金矿。文章通过对小于赞矿区金矿床中FeS2的矿物学研究,对摸清金矿的机理具有现实意义,对指导该区进一步找矿具有重要意义。     

县域工业化进程中各地类效益及空间变化研究—–以宁波市鄞州区为例

利用Stata和GeoDa软件对鄞州区土地利用进行回归分析和空间分析, 研究结果表明: (1)各地类的集聚层次性显著; (2)各地类的经济效益差距变大; (3)经济效益变化是影响土地利用变化的重要因素, 由此提出提升土地利用效益应是调控土地利用方式的首要手段.