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61.
A quantitative and fast method of dissolution of refractory thoria (ThO2) was developed for the determination of thorium (Th) in a given sample. The dissolution of sintered ThO2 powder, microspheres and pellets using 88% phosphoric acid was investigated. The conditions of quantitative dissolution of ThO2 microspheres were optimized by conventional heating in autoclave and also by microwave heating. 100 mg of sintered ThO2 microspheres were dissolved in 8 g of phosphoric acid in an autoclave, and heating at 170 °C for 3 h, in comparison to 5 g of phosphoric acid by microwave heating (375 W) at 220 °C for 1 h. Dissolution studies on the powder form of sintered ThO2 were also performed. 1 g of sintered ThO2 powder could be dissolved in 6.5 g of phosphoric acid in autoclave heating at 170 °C for 1 h. Strong complexing of (PO4)3− with Th4+ may be the influencing factor for quantitative dissolution of ThO2. 相似文献
62.
V. V. Vinogradov A. V. Agafonov A. V. Vinogradov K. T. Pillai Rajesh V. Pai S. K. Mukerjee S. K. Aggarwal 《Journal of Sol-Gel Science and Technology》2011,60(1):6-10
Mesoporous γ-Al2O3 materials with high surface area and a narrow pore size distribution were synthesized by facile sol–gel procedure with application
of the polymer–colloid complex as a template. 相似文献
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66.
N K Porwal R M Kadam Y Babu M D Sastry M D Aggarwal Putcha Venkateswarlu 《Pramana》1997,48(4):929-935
Photo-induced charge transfer and its kinetics were investigated in Bi12SiO20 in 10–300 K temperature range, using EPR of Fe3+ centre, underin situ illumination with copper vapour laser (CVL). The decay kinetics was found to follow double exponential behaviour. Relaxation
of the photo-induced electron transfer to the preillumination condition occurred even at 10 K. Shallow traps were, therefore,
associated with the electron trapping, leading to a better understanding of the fast photorefractive response of BSO. 相似文献
67.
The sodium anion of trans-1,3-dithiane-1,3-dioxide reacts with unhindered aromatic and heteroaromatic aldehydes to give adducts with 95:5 to 97:3 diastereoselectivity. 相似文献
68.
Nonconvex programming problems are frequently encountered in engineering and operations research. A large variety of global optimization algorithms have been proposed for the various classes of programming problems. A new approach for global optimum search is presented in this paper which involves a decomposition of the variable set into two sets —complicating and noncomplicating variables. This results in a decomposition of the constraint set leading to two subproblems. The decomposition of the original problem induces special structure in the resulting subproblems and a series of these subproblems are then solved, using the Generalized Benders' Decomposition technique, to determine the optimal solution. The key idea is to combine a judicious selection of the complicating variables with suitable transformations leading to subproblems which can attain their respective global solutions at each iteration. Mathematical properties of the proposed approach are presented. Even though the proposed approach cannot guarantee the determination of the global optimum, computational experience on a number of nonconvex QP, NLP and MINLP example problems indicates that a global optimum solution can be obtained from various starting points. 相似文献
69.
A series of 2-(arylimino)-3-(hydroxyimino)butanes 3a–g, easily accessed by the condensation of variously substituted anilines 1a–g with biacetyl monoxime 2, were efficiently cyclized to afford 2,3-dimethylquinoxaline-1-oxides 4a–g using bis(acetoxy)phenyl-λ 3-iodane as an oxidant. This methodology utilizes a commercially available and environmental benign oxidant to achieve the title compounds in excellent yields under mild conditions.
[Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.] 相似文献
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