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1.
Takuya Hashimoto Koichi Kitazawa Masaaki Nakabayashi Tadashi Shiraishi Youichi Suemune Takakazu Yamamoto Hideomi Koinuma 《应用有机金属化学》1991,5(4):325-330
For low-temperature deposition of oxide films relating to Bi-Sr-Ca-Cu-O superconductors, photo-absorption and -decomposition properties were examined with respect to copper and alkaline-earth ß-diketonates. It was confirmed that all ß-diketonates examined were promising as source materials for photochemical vapour deposition (photo-CVD) using a low-pressure mercury lamp, in view of their large light absorption coefficients at wavelength 254 nm. The light irradiation was effective for the formation of highly crystalline oxide films at temperatures below 600 °C. By combining two sources, Ca2CuO3 and SrCuO2 films were prepared. Photo-CVD of c-axis oriented Bi2Sr2CuOx film was achieved by the irradiation of ternary sources of Bi(C6H5)3 and strontium and copper ß-diketonates at 500 °C. 相似文献
2.
M. Saeki M. Nakada T. Kawasaki T. Nishimura T. Kitazawa M. Takeda 《Journal of Radioanalytical and Nuclear Chemistry》2006,270(2):379-384
Summary The correlations of isomer shifts in various neptunyl(V and VI) compounds with crystallographic structures were revaluated.
A linear correlation between the isomer shifts of neptunyl(VI) compounds and Np-O bond lengths of neptunyl group has been
demonstrated. On the other hand, it has been evidenced that the isomer shifts of neptunyl(V) compounds are correlated much
stronger with the mean Np-O distances in the crystals than the lengths in neptunyl(V) group. 相似文献
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Kana Kobayashi-Taguchi Takashi Saitou Yoshiaki Kamei Akari Murakami Kanako Nishiyama Reina Aoki Erina Kusakabe Haruna Noda Michiko Yamashita Riko Kitazawa Takeshi Imamura Yasutsugu Takada 《Molecules (Basel, Switzerland)》2022,27(10)
Fibroadenomas (FAs) and phyllodes tumors (PTs) are major benign breast tumors, pathologically classified as fibroepithelial tumors. Although the clinical management of PTs differs from FAs, distinction by core needle biopsy diagnoses is still challenging. Here, a combined technique of label-free imaging with multi-photon microscopy and artificial intelligence was applied to detect quantitative signatures that differentiate fibroepithelial lesions. Multi-photon excited autofluorescence and second harmonic generation (SHG) signals were detected in tissue sections. A pixel-wise semantic segmentation method using a deep learning framework was used to separate epithelial and stromal regions automatically. The epithelial to stromal area ratio and the collagen SHG signal strength were investigated for their ability to distinguish fibroepithelial lesions. An image segmentation analysis with a pixel-wise semantic segmentation framework using a deep convolutional neural network showed the accurate separation of epithelial and stromal regions. A further investigation, to determine if scoring the epithelial to stromal area ratio and the SHG signal strength within the stromal area could be a marker for differentiating fibroepithelial tumors, showed accurate classification. Therefore, molecular and morphological changes, detected through the assistance of computational and label-free multi-photon imaging techniques, enable us to propose quantitative signatures for epithelial and stromal alterations in breast tissues. 相似文献
7.
The kinetics of the flattening of surface corrugations of float glasses were investigated in dry nitrogen at 610 to 670°C. The amplitude of the sinusoidal surface profile decayed exponentially with time while its wavelength remained constant. The dependence of decay rate on wavelength indicated that the process is controlled by the viscous flow. From the obtained rate constant the viscosity was calculated using the surface energy value determined independently by the zero-creep method. The viscosity thus obtained reflects the mass transport property in the vicinity of the glass surface. It was several times larger than that determined by the fibre elongation or intrusion method which should reflect the bulk properties. No difference in the decay rate was observed on both the surfaces of float glass of which only one side had been exposed to molten tin during the glass manufacturing process. 相似文献
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A. Dönni P. Fischer B. Roessli H. Kitazawa 《Zeitschrift für Physik B Condensed Matter》1994,93(4):449-454
Nuclear and magnetic structures of an annealed polycrystalline sample of the heavy-fermion compound CePd2Al3 prepared by arc-melting were investigated by neutron powder diffraction. The chemical structure corresponds well to the ordered hexagonal PrNi2Al3-type structure. The antiferromagnetic structure of CePd2Al3 with an ordered magnetic moment
Ce=0.47(2)
B at saturation is remarkably similar to that in the heavy fermion superconductor UPd2Al3. The additional incommensurate magnetic structures reported previously both for UPd2Al3 and CePd2Al3 are not observed in the present sample of CePd2Al3. At 1.4 K the magnetoresistivity of CePd2Al3 measured up to 14 T indicates only one field-induced phase transition at 3.0 T. 相似文献
10.
In order to determine the copper content x of copper Chevrel compound CuxMo6S8?y(0?y?0.4) as a function of copper activity aCu and sulfur deficit y, a solid state electrochemical cell, Cu/Rb4Cu16I7Cl13/CuxMo6S8?y/Pt, was constructed and coulometric titration studies were made at 400 K. For the evaluation of the coulometric titration data, measurements were made on the electronic conductivity of copper-ion conductor Rb4Cu16I7Cl13. Also, a brief investigation was made on the condition of formation of single phase Chevrel CuxMo6S8?y with varying x and y at 1000°C. The structural change of CuxMo6S8?y with a change in x and y was studied by the X-ray diffraction method. It was found that x for constant aCu decreases with increasing y. The maximum value xmax of x in CuxMo6S8?y in equilibrium with metallic copper was found to be expressed by . In the region of y<0.3, xmax exceeded 4, contrary to a presupposition that xmax is less than 4. X-ray analysis revealed that most of the copper Chevrel compounds denoted by CuxMo6S8 so far were sulfur deficient ones with y?0.4. The importance of sulfur deficit on the properties of the copper Chevrel compound was emphasized. 相似文献