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51.
Synthesis and properties of optically active 1,3-diols and their derivatives as chiral dopants for ferroelectric liquid crystals 总被引:1,自引:0,他引:1
Tetsuo Kusumoto Ken-Ichi Sato Kumiko Ogino Tamejiro Hiyama Sadao Takehara Masashi Osawa Kayoko Nakamura 《Liquid crystals》1993,14(3):727-732
New chiral dopants β-hydroxy ketones 1, 1,3-diols 2, 1,3-dioxanes 3 and 1,3-dioxan-2-ones 4 were designed and synthesized. Reaction of (R)-1,2-epoxyoctane with carbanions derived from 2-(4-substituted phenyl)-1,3-dithianes followed by hydrolysis of the resulting hydroxy dithianes afforded 1. Reduction of 1 gave the diols 2, which yielded 3 upon acetalization and 4 upon carbonation. The syn isomers of 2, 3, and 4 exhibited larger spontaneous polarizations, when applied as chiral dopants, than the anti isomers or hydroxy ketones 1. 相似文献
52.
Yoshio Hamashima Sadao Yamamoto Tadatoshi Kubota Katsuya Tokura Koji Ishikura Kyogi Minami Fumihiko Matsubara Masaaki Yamaguchi Ikuo Kikkawa Wataru Nagata 《Tetrahedron letters》1979,20(51):4947-4950
Synthesis of optically active 3′-nor-type 1-oxacephems from 6-APA was described. -Nitrobenzyl 7β-amino-3-chloro-7α-methoxy-1-oxa-3-cephem-4-carboxylate was also prepared. 相似文献
53.
Nobumasa Hojo Hirofusa Shirai Yoshiki Chujo Sadao Hayashi 《Journal of polymer science. Part A, Polymer chemistry》1978,16(2):447-455
Decomposition of hydrogen peroxide was examined was examined by using Cu(II)–poly(vinyl alcohol) (PVA) as catalyst. The rates of decomposition were measured. Electronic spectra and infrared spectra of Cu(II)–PVA complex systems were determined at various stages of decomposition. Effect of addition of various amines to the Cu(II)–PVA system on catalytic action was considered. The relation between the initial rate and the initial concentration of hydrogen peroxide varied in accordance with the rate expression of Michaelis-Menten type. Cu(II)–PVA complex was found to have a large catalytic activity, while the polymeric PVA ligand and copper(II) ion exhibited less activity than Cu(II)–PVA complex. For hydrogen peroxide decomposition, Cu(II)–PVA complex showed catalytic activity when a stable complex of planar structure formed, while many other polymer complexes reported by other authors showed the catalytic activity when they were in unstable complex forms. An amine substituent has a critical influence on the rate of hydrogen peroxide decomposition. The mechanism in the first step of reaction for hydrogen peroxide decomposition is discussed. 相似文献
54.
Kiyoshi Sato Sadao Arai Takamichi Yamagishi Tomoaki Tanase 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(3):o162-o164
In 8a‐azonia[6]helicene hexafluorophosphate or 8a‐azoniaphenanthro[3,4‐c]phenanthrene hexafluorophosphate, C25H16N+·PF6−, replacement of an outer bridgehead carbon of hexahelicene by a quaternary Nsp2 atom results in a geometrical change in the helical structure. The racemic heterohelicene forms homochiral columnar stacks through intermolecular π–π donor–acceptor interactions in the crystalline state. 相似文献
55.
Ranganathan Kandasamy Masanobu Yamanaka Yasukasu Izawa Sadao Nakai 《Optical Review》2000,7(2):149-151
Using Jones matrix formulation, the theoretical calculations of birefringence compensation technique for a quarter-wave plate scheme are presented. This scheme was proposed and experimentally demonstrated by W. A. Clarkson et al. (Opt. Lett. 24 (1999) 820). In the present paper we have theoretically confirmed that using this method, even in principle, complete compensation is not possible. However, it is shown quantitatively that this scheme does makes possible effective compensation for the birefringence in as few as several tens of watts of pumping power region, which is an attractive feature for laser-diode (LD) pumped solid-state laser systems. We also found good agreement between our theoretical calculations and experimental results obtained by W. A. Clarkson et al. For example, from the analysis we show that only < 0.1% loss will be generated by about 10 W of heat deposited in the rod. This corresponds to about 30 W of LD pump power, which may generate from 6 to 10 W output power depending upon the conversion efficiency of type lasers 相似文献
56.
New trialkoxyphosphorane-thiolesters 10, obtained by reaction of oxalimides 9 with trialkyl phosphite, were efficiently cyclized by an intramolecular Wittig reaction to give carbapenems 11. 相似文献
57.
A newly designed jet-type, water-cooled heat sink (the funryu heat sink, meaning fountain flow in Japanese) yielded 255-W cw laser output at 808 nm from a 1-cm bar made from InGaAsP/InGaP quantum-well active layers with a 67% fill factor [70 quantum-well laser diode (LD) array along the 1-cm bar]. A funryu heat sink measuring 1.1 mm in thickness gave the LD 0.25 degrees C/W thermal resistance, one of the lowest values achieved with a 1-cm LD bar. Over a short period of operation, the device reached a maximum cw power of 255 W. To the best of our knowledge, this is the highest power ever achieved in 808-nm LD operation. In the future, the funryu heat sink may be capable of 80-W cw operation over an extended lifetime of several thousand hours. 相似文献
58.
59.
Akitami Ichihara Noriki Nio Yoshihiko Terayama Ryoji Kimura Sadao Sakamura 《Tetrahedron letters》1979,20(39):3731-3734
Various 2-alkyl-2-butenolactones were simply prepared from cyclopentadiene-maleic anhydride adducts through the retro-Diels-Alder reaction. The procedure was applied for the synthesis of dehydrolappaol A dimethyl ether. 相似文献
60.