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101.
电催化还原氧是一种新兴的可持续生产过氧化氢(H2O2)的合成技术,寻找低成本、高活性和高选择性的电催化剂是该技术实际应用的关键.钴氮掺杂的碳材料因含有钴氮(Co-Nx)催化活性位,成为一类新兴的可促进H2O2电化学合成的材料.本文采用低能耗干式球磨外加控制热解的方法来制备包含许多Co-Nx结构的钴氮掺杂碳材料.该方法使用材料廉价,即将醋酸钴、2-甲基咪唑和Ketjenblack EC-600JD高纯度且导电的碳黑分别作为金属、氮和碳的前体.在酸性介质中的电化学测试结果表明,该材料的氧还原反应电流密度明显增加,同时起始电位向正方向移动.该催化剂在较大电位范围内对H2O2的选择性约为90%.H2O2整体电解实验表明,H2O2产率达到100mmol gcat?1 h?1,H2O2法拉第效率达到85%(0.3Vvs.RHE条件下2h).耐久性测试(在0.3Vvs.RHE条件下6h)表明,催化剂表现出相对稳定的性能,且在整个测试循环中,法拉第效率达到约85%,表明催化剂在实际应用中具有良好的耐久性.催化剂表现出较高的电催化合成H2O2活性和选择性可能是由于形成了Co-Nx活性位,以及酸性环境和应用电位等其它因素的影响. 相似文献
102.
The hydrothermal reaction of MoO3, V, Na2WO4· 2H2O, [N(CH2CH2)3N](1,4-diazabicyclo[2.2.2] octane), and H2O at 160°C for 90h gave dark-brown crystals of [HN(CH2CH2)3N]2[HMoVMoVI
5O19]·[N(CH2CH2)3N], (1), in 40% yield. Complex (1) is the first one-electron reduced mixed-valence hexamolybdate to be crystallized and structurally characterized. The crystal structure of (1) consists of discrete [HMoVMoVI
5O19]2– anions, [HN-(CH2CH2)3N]+ cations, and neutral [N(CH2CH2)3N] molecules of crystallization. 相似文献
103.
Investigation of Capparis spinosa of Jordanian origin lead to isolation of two new compounds beta-sitosterylglucoside-6'-octadecanoate (1) and 3-methyl-2-butenyl-beta-glucoside (2). Linked Scan MS measurements were used to propose a mass fragmentation pattern for the alkaloid Cadabicine isolated here for the second time from nature. 相似文献
104.
105.
Familial predictors of childhood shyness: a study of the United Arab Emirates population 总被引:1,自引:0,他引:1
OBJECTIVES: Phobic anxiety disorders generally breed true. In this regard, family studies have suggested an association between childhood shyness and maternal social phobia. In this study, the relationship between childhood shyness and maternal social anxiety was examined. SUBJECTS AND METHODS: 203 5-year-old children from an Arabian Gulf community and their mothers were evaluated. The children were assessed in stage 1 using the shyness scale of Stevenson-Hinde and Glover and the Preschool Behavior Checklist (PBCL), while mothers completed the Liebowitz Social Anxiety Scale. In the second stage, blind clinical interviews were carried out to ascertain the diagnosis of psychiatric diagnoses, if any, using DSM-IV criteria. RESULTS: 27% of the children were identified as shy using the shyness scale of Stevenson-Hinde and Glover and 19% scored above the cutoff for behavioral disturbance on the PBCL. Child shyness was associated with female gender and maternal social anxiety as indicated by scores on the Liebowitz Social Anxiety Scale, while an inverse relationship was noted with behavioral disturbance. The odds of the child having a high shyness score was increased if the mother had social anxiety (odds ratio = 2.14) and the child lived in a family that was 'not socially active' (odds ratio = 1.42). CONCLUSION: Our initial findings suggest that there may be a complex interaction between maternal social anxiety and family sociability in childhood shyness. Prospective longitudinal work is indicated. 相似文献
106.
Temel Ozturk Sevil Savaskan Yilmaz Baki Hazer Yusuf Z. Menceloglu 《Journal of polymer science. Part A, Polymer chemistry》2010,48(6):1364-1373
This article reports the synthesis of the block and graft copolymers using peroxygen‐containing poly(methyl methacrylate) (poly‐MMA) as a macroinitiator that was prepared from the atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) in the presence of bis(4,4′‐bromomethyl benzoyl peroxide) (BBP). The effects of reaction temperatures on the ATRP system were studied in detail. Kinetic studies were carried out to investigate controlled ATRP for BBP/CuBr/bpy initiating system with MMA at 40 °C and free radical polymerization of styrene (S) at 80 °C. The plots of ln ([Mo]/[Mt]) versus reaction time are linear, corresponding to first‐order kinetics. Poly‐MMA initiators were used in the bulk polymerization of S to obtain poly (MMA‐b‐S) block copolymers. Poly‐MMA initiators containing undecomposed peroygen groups were used for the graft copolymerization of polybutadiene (PBd) and natural rubber (RSS‐3) to obtain crosslinked poly (MMA‐g‐PBd) and poly(MMA‐g‐RSS‐3) graft copolymers. Swelling ratio values (qv) of the graft copolymers in CHCl3 were calculated. The characterizations of the polymers were achieved by Fourier‐transform infrared spectroscopy (FTIR), 1H‐nuclear magnetic resonance (1H NMR), gel‐permeation chromatography (GPC), differential scanning calorimetry (DSC), thermogravimetric analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), and the fractional precipitation (γ) techniques. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1364–1373, 2010 相似文献
107.
E. Tellechea O. Sabri M.P. Ariza 《Revista Internacional de Métodos Numéricos para Cálculo y Dise?o en Ingeniería》2013,29(3):135-145
Motion of screw dislocations in BCC materials at low temperature is believed to be related to the formation of mobile kinks on the dislocation line. Therefore, the accurate prediction of kink nucleation energies is required to fully describe mobility of screw dislocations in these materials. Studies of fundamental dislocation processes at atomic length scale are numerically and computationally intensive problems. This work studies the calculation of zero-stress formation energies of kink-pair configurations for BCC crystals. Our model for stored energy associated to a dislocation line configuration is based on the theory of discrete dislocations of Ariza and Ortiz. Its value is computed efficiently using an algorithm developed on the NVIDIA Compute Unified Device Architecture (CUDA). Results confirm those obtained using atomistic potentials and first principles calculations, and those based on the continuum theory of dislocations. 相似文献
108.
This paper presents an easily verifiable delay independent sufficient condition for the global robust asymptotic stability of the equilibrium point for bidirectional associative memory (BAM) neural networks with time delays by employing a class of Lyapunov functionals. The obtained results are applicable to all bounded continuous non-monotonic neuron activation functions. Some numerical examples are given to compare our results with the previous robust stability results derived in the literature. 相似文献
109.
Properties of 114–134Xe isotopes are studied in the U(5)?SO(6) transitional region of Interacting Boson Model (IBM-1). The energy levels and B(E2) transition rates are calculated via the affine SU(1,1) Lie Algebra. The agreement with the most recent experimental is acceptable. The evaluated Hamiltonian control parameters suggest a spherical to γ-soft shape transition and propose the 130Xe nucleus as the best candidate for the E(5) symmetry. 相似文献
110.
Altu? Mert Sevim Rustam Hojiyev Ahmet Gül Mehmet Sabri ?elik 《Monatshefte für Chemie / Chemical Monthly》2012,102(1):385-400