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51.
R. Rodríguez-Ramos R. Guinovart-Díaz J. C. López-Realpozo J. Bravo-Castillero J. A. Otero F. J. Sabina H. Berger M. Würkner U. Gabbert 《Archive of Applied Mechanics (Ingenieur Archiv)》2014,84(9-11):1565-1582
In this work, two-phase parallel fiber-reinforced periodic piezoelectric composites are considered wherein the constituents exhibit transverse isotropy and the cells have different configurations. Mechanical imperfect contact at the interface of the piezoelectric composites is studied via linear spring model. The statement of the problem for two-phase piezoelectric composites with mechanical imperfect contact is given. The local problems are formulated by means of the asymptotic homogenization method, and their solutions are found using complex variable theory. Analytical formulae are obtained for the effective properties of the composites with spring imperfect type of contact and different rhombic cells. Using the concept of a representative volume element (RVE), a finite element model is created, which combines the angular distribution of fibers and imperfect contact conditions (spring type) between the phases. Periodic boundary conditions are applied to the RVE, so that effective material properties can be derived. The fibers are distributed in such a way that the microstructure is characterized by a rhombic cell. The presented numerical homogenization technique is validated by comparing results with theoretical approach reported in the literature. Some studies of particular cases, numerical examples, and comparisons between the two aforementioned methods with other theoretical results illustrate that the model is efficient for the analysis of composites with presence of rhombic cells and the aforementioned imperfect contact. 相似文献
52.
Rebe Raz S Leontaridou M Bremer MG Peters R Weigel S 《Analytical and bioanalytical chemistry》2012,403(10):2843-2850
Silver nanoparticles are recognized as effective antimicrobial agents and have been implemented in various consumer products including washing machines, refrigerators, clothing, medical devices, and food packaging. Alongside the silver nanoparticles benefits, their novel properties have raised concerns about possible adverse effects on biological systems. To protect consumer's health and the environment, efficient monitoring of silver nanoparticles needs to be established. Here, we present the development of human metallothionein (MT) based surface plasmon resonance (SPR) sensor for rapid detection of nanosilver. Incorporation of human metallothionein 1A to the sensor surface enables screening for potentially biologically active silver nanoparticles at parts per billion sensitivity. Other protein ligands were also tested for binding capacity of the nanosilver and were found to be inferior to the metallothionein. The biosensor has been characterized in terms of selectivity and sensitivity towards different types of silver nanoparticles and applied in measurements of real-life samples-such as fresh vegetables and river water. Our findings suggest that human MT1-based SPR sensor has the potential to be utilized as a routine screening method for silver nanoparticles, that can provide rapid and automated analysis dedicated to environmental and food safety monitoring. 相似文献
53.
Remote and automated detection of organic compounds in subsurface aquifers is crucial to superfund monitoring and environmental remediation. Current monitoring techniques use expensive laboratory instruments and trained personnel. The use of a filled tubular preconcentrator combined with a chemicapacitive detector array presents an attractive option for the unattended monitoring of these compounds. Five preconcentrator materials were exposed to common target compounds of subsurface remediation projects (1,1,2-trichloroethane, trichloroethylene, t-1,2-dichloroethylene, benzene, and perchloroethylene). Rapid heating of the tube caused the collected, concentrated effluent to pass over the surface of a chemicapacitive detector array coated with four different sorbent polymers. A system containing a porous ladder polymer and the sensor array was subsequently used to sample the analytes injected onto sand in a laboratory test, simulating a subsurface environment. With extended collection times, effective detection limits of 5 ± 3 ppbV for 1,1,2-trichloroethane and 145 ± 60 ppbV for benzene were achieved. Effects of the preconcentrator material structure, the collection time, and sensor material on the system performance were observed. The resultant system presents a solution for remote, periodic monitoring of chlorinated organic compounds and other volatile organic compounds in a soil matrix. 相似文献
54.
55.
56.
Qian Wu Myun-Ho Bang Dae-Young Lee Jin-Gyeong Cho Rak-Hun Jeong Sabina Shrestha Kyung-Tae Lee Hae-Gon Chung Eun-Mi Ahn Nam-In Baek 《Chemistry of Natural Compounds》2012,48(2):281-284
Two new indoles, 2-C-β-D-glucopyranosyl-1-methoxyindole-3-acetonitrile (1) and 6-hydroxy-1-methylindole3-acetonitrile (2), along with two known indoles [caulilexin C (3) and arvelexin (4)], were isolated from turnip roots (Brassica rapa ssp. campestris L.). The structures of the compounds were established on the basis of NMR, FAB-MS, and IR spectroscopic data. 相似文献
57.
A pore-scale analysis of nonaqueous phase liquid (NAPL) blob dissolution and mobilization in porous media was presented. Dissolution
kinetics of residual NAPLs in an otherwise water-saturated porous medium was investigated by conducting micromodel experiments.
Changes in residual NAPL volume were measured from recorded video images to calculate the mass transfer coefficient, K and the lumped mass transfer rate coefficient, k. The morphological characteristics of the blobs such as specific and intrinsic area were found to be independent of water
flow rate except at NAPL saturations below 2%. Dissolution process was also investigated by separating the mass transfer into
zones of mobile and immobile water. The fractions of total residual NAPL perimeters in contact with mobile water and immobile
water were measured and their relationship to the mass transfer coefficient was discussed. In general, residual NAPLs are
removed by dissolution and mobilization. Although these two mechanisms were studied individually by others, their simultaneous
occurrence was not considered. Therefore, in this study, mobilization of dissolving NAPL blobs was investigated by an analysis
of the forces acting on a trapped NAPL blob. A dimensional analysis was performed to quantify the residual blob mobilization
in terms of dimensionless Capillary number (Ca
I). If Ca
I is equal to or greater than the trapping number defined as , then blob mobilization is expected. 相似文献
58.
Reinaldo Rodríguez-Ramos Raúl Guinovart-Díaz Juan C. López-Realpozo Julián Bravo-Castillero Federico J. Sabina 《Archive of Applied Mechanics (Ingenieur Archiv)》2010,80(4):377-388
A fiber-reinforced periodic piezoelectric composite, where the constituents exhibit transverse isotropic properties, is considered. The fiber cross-section is circular and the periodicity is the same in two orthogonal directions. Imperfect mechanic contact conditions at the interphase between the matrix and fibers are represented in parametric form. In order to analyze the influence of the imperfect interface effect over the behavior of the composite, the effective axial piezoelectric moduli are obtained by means of the Asymptotic Homogenization Method. Some numerical examples are given. 相似文献
59.
H. Brito-Santana R. Rodríguez-Ramos R. Guinovart-Díaz J. Bravo-Castillero F. J. Sabina G. A. Maugin 《Archive of Applied Mechanics (Ingenieur Archiv)》2009,79(3):189-204
Using the spherical and deviator decomposition of the polarization and strain tensors, we present a general algorithm for
the calculation of variational bounds of dimension d for any type of anisotropic linear elastic composite as a function of the properties of the comparison body. This procedure
is applied in order to obtain analytical expressions of bounds for multiphase, linear elastic composites with cubic symmetry
where the geometric shapes of the inclusions are arbitrary. For the validation, it can be proved that for the isotropic particular
case, the bounds coincide with those recently reported by Gibiansky and Sigmund. On the other hand, based on this general
procedure some, classical bounds reported by Hashin for transversely isotropic composites, are reproduced. Numerical calculations
and some comparisons with other models and experimental data are shown. 相似文献
60.
Agnieszka Ciurzyska Paulina Popkowicz Sabina Galus Monika Janowicz 《Molecules (Basel, Switzerland)》2022,27(10)
The aim of the work has been to develop freeze-dried fruit snacks in the form of bars with the use of by-products derived from fruit processing. In effect 14 product designs of fruit gels based on: apple pulp, apple juice, water, sodium alginate and only apple or only chokeberry pomace were prepared. The snacks were freeze-dried. The dry matter content, water activity, structure, colour, mechanical properties, as well as organoleptic evaluation were determined. Freeze-dried bares were obtained according to sustainability production which in this case was relied on application of fruit pomace. The freeze-drying process ensures the microbiological safety of the product without the need to use chemical preservatives. Freeze-dried samples obtained low water activity in the range of 0.099–0.159. The increase in pomace concentration (3–9%) boosted the dry matter content to above 98%, and decreased the brightness of the freeze-dried bars about 6 to 10 units. Mechanical properties varied depending on the product design. With the increase in the amount of pomace, the shear force increased at 23% to 41%. Based on the results, the best variant, that has the most delicate structure and the best organoleptic properties, has proven to contain 1% sodium alginate and 2% pomace. 相似文献