Submicrometer period fused silica gratings were produced by two-beam interferometric laser-induced backside wet etching technique
(TWIN LIBWE). The fourth harmonic of a Nd:YAG laser beam was spatially filtered in two steps, and the smoothened beam was
split into two parts and interfered at incident angles of 60°, 30°, 14°, and 7.7°, respectively, on the backsides of fused
silica plates that were in contact with a liquid absorber. The periods of the produced fused silica gratings were, respectively,
154 nm, 266 nm, 550 nm, and 990 nm. In the next step, TWIN-LIBWE setup was completed by using a coupling rectangular prism
in order to reach immersion setup, which made possible to fabricate 104 nm period fused silica grating. This is the smallest
laser-generated grating constant in fused silica at present.
The morphology of the etched gratings was characterized by atomic force microscope. Important parameters (modulation depth,
low-pass filtered waviness, quality factor) of the produced gratings were determined. Evolution of the grating parameters
was also studied in the 990 nm case: the dependence of modulation depth, waviness, and quality factor on the number of laser
pulses was investigated. 相似文献
For a (simple) graph G, the signless Laplacian of G is the matrix A(G)+D(G), where A(G) is the adjacency matrix and D(G) is the diagonal matrix of vertex degrees of G; the reduced signless Laplacian of G is the matrix Δ(G)+B(G), where B(G) is the reduced adjacency matrix of G and Δ(G) is the diagonal matrix whose diagonal entries are the common degrees for vertices belonging to the same neighborhood equivalence class of G. A graph is said to be (degree) maximal if it is connected and its degree sequence is not majorized by the degree sequence of any other connected graph. For a maximal graph, we obtain a formula for the characteristic polynomial of its reduced signless Laplacian and use the formula to derive a localization result for its reduced signless Laplacian eigenvalues, and to compare the signless Laplacian spectral radii of two well-known maximal graphs. We also obtain a necessary condition for a maximal graph to have maximal signless Laplacian spectral radius among all connected graphs with given numbers of vertices and edges. 相似文献
The use of a double hydrophilic block copolymer (DHBC), poly(ethylene oxide)-block-poly(acrylic acid) (PEO-b-PAA) to prepare magnetic nanoparticle (MNP) clusters was investigated. In this one-pot synthesis method, the DHBC controlled the particle growth and served as both stabilizer and clustering agent. Depending on the iron-to-polymer ratio, the synthesized particles can be in the form of colonies of small iron oxide particles or clusters of these particles with size larger than 100 nm. Compared to the previous reported result using random copolymers, the clusters prepared with DHBC were more compact and homogeneous. The yield of clusters increased when the amount of polymer added was limiting. Insufficient amounts of polymer resulted in the formation of bare patches on the magnetite surface, and the strong van der Waals attraction induced cluster formation. 相似文献
Using light energy and O2 for the direct chemical oxidation of organic substrates is a major challenge. A limitation is the use of sacrificial electron donors to activate O2 by reductive quenching of the photosensitizer, generating undesirable side products. A reversible electron acceptor, methyl viologen, can act as electron shuttle to oxidatively quench the photosensitizer, [Ru(bpy)3]2+, generating the highly oxidized chromophore and the powerful reductant methyl‐viologen radical MV+.. MV+. can then reduce an iron(III) catalyst to the iron(II) form and concomitantly O2 to O2.? in an aqueous medium to generate an active iron(III)‐(hydro)peroxo species. The oxidized photosensitizer is reset to its ground state by oxidizing an alkene substrate to an alkenyl radical cation. Closing the loop, the reaction of the iron reactive intermediate with the substrate or its radical cation leads to the formation of two oxygenated compounds, the diol and the aldehyde following two different pathways. 相似文献
We consider a special iterated quantum protocol with measurement-induced nonlinearity for qubits, where all pure initial states on the Bloch sphere can be considered chaotic. The dynamics is ergodic with no attractive fixed cycles. We show that initial noise radically changes this behavior. The completely mixed state is an attractive fixed point of the dynamics induced by the protocol. Our numerical simulations strongly indicate that initially mixed states all converge to the completely mixed state. The presented protocol is an example, where gaining information from measurements and employing it to control an ensemble of quantum systems enables us to create ergodicity which, in turn, is destroyed by any initial noise. 相似文献
Jones and Lawson have discovered in (Period Math Hungar 64(1):53–87 2012) that certain representations of the so-called polycyclic monoids are closely related to some permutative representations of the Cuntz algebras \({\mathcal {O}}_{n}\) studied by Bratteli and Jorgensen in (Mem Am Math Soc 139(663):x+89 1999). We investigate these representations of the polycyclic monoids, and we generalize some results from Jones and Lawson (2012). We give a (sharp) upper bound on the number of atoms in case one of the parameters tends to infinity and present an infinite family of representations having only one atom. Furthermore, by making use of a C++ program we present some observations regarding the number of atoms in the case \(n=3\). 相似文献
The efficacy of a sound localization training procedure that provided listeners with auditory, visual, and proprioceptive/vestibular feedback as to the correct sound-source position was evaluated using a virtual auditory display that used nonindividualized head-related transfer functions (HRTFs). Under these degraded stimulus conditions, in which the monaural spectral cues to sound-source direction were inappropriate, localization accuracy was initially poor with frequent front-back reversals (source localized to the incorrect front-back hemifield) for five of six listeners. Short periods of training (two 30-min sessions) were found to significantly reduce the rate of front-back reversal responses for four of five listeners that showed high initial reversal rates. Reversal rates remained unchanged for all listeners in a control group that did not participate in the training procedure. Because analyses of the HRTFs used in the display demonstrated a simple and robust front-back cue related to energy in the 3-7-kHz bandwidth, it is suggested that the reductions observed in reversal rates following the training procedure resulted from improved processing of this front-back cue, which is perhaps a form of rapid perceptual recalibration. Reversal rate reductions were found to generalize to untrained source locations, and persisted at least 4 months following the training procedure. 相似文献
We describe a novel nucleation mechanism of scroll rings in three-dimensional reaction-diffusion systems with anomalous dispersion. The vortices form after the collision of two spherical wave fronts from a third, trailing wave that only partially annihilates in the wake of its predecessor. Depending on the relative positions of the three relevant wave sources, one obtains untwisted or twisted scroll rings. The formation of both vortex structures is demonstrated for a modified Belousov-Zhabotinsky reaction. 相似文献
Polyurethane elastomers (PUR) based on polypropylene glycol and 4,4′-diphenylmethane diisocyanate were prepared with various monoethylene glycol (mEG) contents. The aim of this study is to find a reliable polymer matrix for composites of improved thermal conductivity and testing fully in order to collect knowledge about its structure. Thermal conductivity was improved from 0.255 to 0.329 W m?1 K?1 when increasing chain extender content. This attributed to a high appearance crystalline ordering level when adding high mEG content. Differential scanning calorimetry revealed a low transition temperature of soft segment at the same temperature around ??64 °C, due to constant polyol content. The enthalpy of melting increases with increasing mEG content. This is due to the increasing crystalline phase and hard segment phase separation within the PUR structure. Dynamic mechanical analysis results show the glass transition temperature of soft segment in the same temperature range between ??57 and ??52 °C and intensity peak of tanδ tends to decrease when mEG content was increased. On the other hand, the glass transition temperature of hard segment tends to increase from 10 to 93 °C and has high intensity peak of tanδ with increasing mEG content. Increasing the chain extender content can be enhancing the hard segment length in PUR structure and affecting both soft segment motion and hard segment motion. Increasing hard segment length might be obstructing soft segment motion and influence hard segment motion which is hard to move at low temperatures. Phase separation of soft and hard segment clearly observed using the DMA technique.