全文获取类型
收费全文 | 17322篇 |
免费 | 3447篇 |
国内免费 | 5856篇 |
专业分类
化学 | 13026篇 |
晶体学 | 721篇 |
力学 | 1265篇 |
综合类 | 454篇 |
数学 | 2296篇 |
物理学 | 8863篇 |
出版年
2024年 | 56篇 |
2023年 | 228篇 |
2022年 | 593篇 |
2021年 | 645篇 |
2020年 | 656篇 |
2019年 | 677篇 |
2018年 | 567篇 |
2017年 | 801篇 |
2016年 | 732篇 |
2015年 | 879篇 |
2014年 | 1077篇 |
2013年 | 1446篇 |
2012年 | 1442篇 |
2011年 | 1565篇 |
2010年 | 1498篇 |
2009年 | 1572篇 |
2008年 | 1667篇 |
2007年 | 1535篇 |
2006年 | 1499篇 |
2005年 | 1212篇 |
2004年 | 978篇 |
2003年 | 710篇 |
2002年 | 711篇 |
2001年 | 680篇 |
2000年 | 791篇 |
1999年 | 425篇 |
1998年 | 251篇 |
1997年 | 197篇 |
1996年 | 222篇 |
1995年 | 145篇 |
1994年 | 161篇 |
1993年 | 159篇 |
1992年 | 135篇 |
1991年 | 90篇 |
1990年 | 114篇 |
1989年 | 108篇 |
1988年 | 83篇 |
1987年 | 63篇 |
1986年 | 52篇 |
1985年 | 26篇 |
1984年 | 31篇 |
1983年 | 23篇 |
1982年 | 24篇 |
1981年 | 24篇 |
1980年 | 12篇 |
1979年 | 8篇 |
1978年 | 7篇 |
1971年 | 7篇 |
1965年 | 11篇 |
1959年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
131.
A GPI-anchored dipeptide of sperm CD52 antigen was prepared through a convergent synthesis. First, the dipeptide with its C-terminus free and the GPI with its nonreducing end phosphoethanolamine bearing a free amino group were synthesized separately. Then, the two building blocks were coupled with use of EDC/HOBt as the condensation reagent. Finally, the GPI-anchored peptide was deprotected to give the target molecule 1. 相似文献
132.
郭黎平 《高等学校化学学报》1993,14(1):29-32
本文将自制Y式玻碳电极拉上两性接枝星形聚合物(GPSMA)的LB膜,用循环伏安法研究谈膜的屏蔽效应,讨论了接枝量、成膜条件等对膜缺陷的影响,并提出了减少缺陷的办法。 相似文献
133.
The covalent binding of pyrazine on Si(100) have been investigated using high-resolution electron energy loss spectroscopy (HREELS) and x-ray photoelectron spectroscopy. Experimental results clearly suggest that the attachment occurs exclusively through the bonding of the two para-nitrogen atoms with the surface without the involvement of the carbon atoms, as evidenced from the retention of the (sp2) C-H stretching mode in HREELS and a significant down shift of 1.6 eV in the binding energy of N 1s. The binding mechanism for pyrazine on Si(100) demonstrates that reaction channels for heteroatomic aromatic molecules are strongly dependent on the electronic properties of the constituent atoms. 相似文献
134.
In this paper, calculating the molecular internal rotating steric factor of polymers by the radiation crosslinking method is studied and a relationship between the molecular internal rotating steric factor (σ) and crosslinking parameter βis established~([1]) by taking account of the effect of polymer chain flexibility on βvalue, σvalue of polymer obtained by this method is in agreement with that given with other method. 相似文献
135.
136.
ShaoNongCHEN ShaoYuanCHEN HanDongSUN WenZhongLIN YaoZuCHEN 《中国化学快报》2004,15(5):539-542
Two novel ent-kauranoids with new sub-skeleton types, gesneroidins G and H were isolated as white powder from the ether extract of the leaves of Isodon gesneroides through normal phase column chromatography. Their structures were elucidated as 3β,6α,7β-triacetoxyl-15-hydroxyl-14-oxo-ent- 15,16-seco-kaur-11,17-olide and Iα-hydroxyl-3β,6α,7β,11 β-tetraacetoxyl-ent-nor-15,17-kaur-8,16-olide on the basis of the spectral evidences including ID and 2D NMR spectra. 相似文献
137.
The novel applications of molybdenum disulfide in recent research were reviewed, such as in lubricant, catalyst and photoelectrochemical solar cells. Recently, we found that LiMoS2 is a good candidate for new anode materials for lithium ion batteries with high lithium storage capacity.Here, the anode material LiMoS2 was synthesized by a hydrothermal method at 150℃ and the electrochemical characterization as an anode material for lithium ion batteries was examined.put in Teflon-lined stainless steel autoclaves of capacity 40 mL. Distilled water was used to fill the autoclaves to 70 % of the total volume. The autoclaves were maintained at 150℃ for 24 h and then cooled naturally. The resulting dark-gray powders were filled and washed with distilled water,diluted hydrochloric acid and ethanol, successively. The final products were dried at 80℃ for 24 h.The powder X-ray diffraction pattern showed the prepared LiMoS2 was amorphous structure. A test cell using LiMoS2 as the active material was discharged and charged between 3 and 0.01 V with respect to Li metal at a constant current density of C/5 (that is, one lithium per formula unit in 5 hours). During the first discharge, the potential rapidly drops to reach a large plateau at 2.2 V, then slowly drops to the other plateau at 0.8 V, and then continuously decreases down to 0.01V. There is only a plateau at 1.35 V in the subsequent discharge curves. The plateaus of charge potential appear at about 1.9 V.The irreversible loss was 41% in the first cycle. The ratio of discharge and charge is more than 99%in the subsequent cycles. Moreover, the ratio of discharge and charge almost reaches 100% after thedemonstrated that LiMoS2 has a very high capacity and a good cycle-ability as an anode material forlithium ion batteries. 相似文献
138.
Here, we report a new method based on the combination of membrane separation technology and nanomaterial to rapid detection of peptides and protein with MALDI-TOF MS. This method shows advantages as it can inhibit the heterogeneous of sample spot and enhance the target molecular signal intensity. 相似文献
139.
The potential-dependent surface-enhanced Raman spectrum of adsorbed p-nitrobenzoic acid (PNBA) on the roughened Au electrode has been obtained by using ultraviolet (UV) excitation at 325 nm. The surface-enhanced Raman spectra of PNBA intensely changed when the voltage was in the rang of negative value, and the electrode potential at which the resonance (potential of maximum intensity) occurs varied when the vibrational mode changes, indicating that the PNBA molecules were chemisorbed on the roughened Au surface. The charge transfer (CT) mechanism could probably explain the experiment results in the present work. 相似文献
140.
变温红外光谱研究多嵌段聚氨脂脲的微相分离行为 总被引:7,自引:0,他引:7
用傅里叶变换红外光谱方法研究了热处理对由聚环氧丙烷聚醚多元醇、3.5-二乙基甲苯二胺和4,4-二苯基甲烷二异氰酸酯组成的多嵌段聚氨酯脲(SPUU)的微相分离行为的影响.从室温逐步升温到310℃的过程中,氨基甲酸酯键(UT)之间形成的氢键大量解离,而脲键(UA)之间形成的、具有平面状双分叉结构的氢键在130~200℃范围却大量生成;从310℃缓慢冷却到室温后,部分游离的UT重新形成氢键,而硬段之间形成的UA氢键的含量又有所增加.结果表明:高温热处理可以有效地提高SPUU的微相分离程度. 相似文献